Nernst Effect
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In physics and chemistry, the Nernst effect (also termed the first Nernst–Ettingshausen effect, after
Walther Nernst Walther Hermann Nernst (; 25 June 1864 – 18 November 1941) was a German physical chemist known for his work in thermodynamics, physical chemistry, electrochemistry, and solid-state physics. His formulation of the Nernst heat theorem helped ...
and Albert von Ettingshausen) is a thermoelectric (or thermomagnetic) phenomenon observed when a sample allowing
electrical conduction Electrical resistivity (also called volume resistivity or specific electrical resistance) is a fundamental specific property of a material that measures its electrical resistance or how strongly it resists electric current. A low resistivity i ...
is subjected to a
magnetic field A magnetic field (sometimes called B-field) is a physical field that describes the magnetic influence on moving electric charges, electric currents, and magnetic materials. A moving charge in a magnetic field experiences a force perpendicular ...
and a temperature gradient normal (perpendicular) to each other. An
electric field An electric field (sometimes called E-field) is a field (physics), physical field that surrounds electrically charged particles such as electrons. In classical electromagnetism, the electric field of a single charge (or group of charges) descri ...
will be induced normal to both. This effect is quantified by the Nernst coefficient \nu, which is defined to be ::\nu=\frac\frac where E_y is the y-component of the electric field that results from the magnetic field's z-component B_z and the x-component of the temperature gradient \partial_x T. The reverse process is known as the Ettingshausen effect and also as the second Nernst–Ettingshausen effect.


Physical picture

Mobile energy carriers (for example conduction-band
electron The electron (, or in nuclear reactions) is a subatomic particle with a negative one elementary charge, elementary electric charge. It is a fundamental particle that comprises the ordinary matter that makes up the universe, along with up qua ...
s in a
semiconductor A semiconductor is a material with electrical conductivity between that of a conductor and an insulator. Its conductivity can be modified by adding impurities (" doping") to its crystal structure. When two regions with different doping level ...
) will move along
temperature Temperature is a physical quantity that quantitatively expresses the attribute of hotness or coldness. Temperature is measurement, measured with a thermometer. It reflects the average kinetic energy of the vibrating and colliding atoms making ...
gradients due to statistics and the relationship between temperature and kinetic energy. If there is a
magnetic field A magnetic field (sometimes called B-field) is a physical field that describes the magnetic influence on moving electric charges, electric currents, and magnetic materials. A moving charge in a magnetic field experiences a force perpendicular ...
transversal to the temperature gradient and the carriers are electrically charged, they experience a
force In physics, a force is an influence that can cause an Physical object, object to change its velocity unless counterbalanced by other forces. In mechanics, force makes ideas like 'pushing' or 'pulling' mathematically precise. Because the Magnitu ...
perpendicular to their direction of motion (also the direction of the temperature gradient) and to the magnetic field. Thus, a perpendicular electric field is induced.


Sample types

The semiconductors exhibit the Nernst effect, as first observed by T. V. Krylova and Mochan in the Soviet Union in 1955. In
metal A metal () is a material that, when polished or fractured, shows a lustrous appearance, and conducts electrical resistivity and conductivity, electricity and thermal conductivity, heat relatively well. These properties are all associated wit ...
s however, it is almost non-existent.


Superconductors

Nernst effect appears in the vortex phase of type-II superconductors due to vortex motion.
High-temperature superconductors High-temperature superconductivity (high-c or HTS) is superconductivity in materials with a critical temperature (the temperature below which the material behaves as a superconductor) above , the boiling point of liquid nitrogen. They are "high ...
exhibit the Nernst effect both in the superconducting and in the pseudogap phase. Heavy fermion superconductors can show a strong Nernst signal which is likely not due to the vortices.


See also

* Spin Nernst effect * Seebeck effect * Peltier effect *
Hall effect The Hall effect is the production of a voltage, potential difference (the Hall voltage) across an electrical conductor that is wikt:transverse, transverse to an electric current in the conductor and to an applied magnetic field wikt:perpendicul ...
* Righi–Leduc effect


References

{{Authority control Walther Nernst Electrodynamics Thermoelectricity