Napoleonite is a variety of

diorite Diorite ( ) is an intrusive rock, intrusive igneous rock formed by the slow cooling underground of magma (molten rock) that has a moderate content of silica and a relatively low content of alkali metals. It is Intermediate composition, inter ...

(also called corsite because the stone is found in the

island An island or isle is a piece of land, distinct from a continent, completely surrounded by water. There are continental islands, which were formed by being split from a continent by plate tectonics, and oceanic islands, which have never been ...

Corsica Corsica ( , , ; ; ) is an island in the Mediterranean Sea and one of the Regions of France, 18 regions of France. It is the List of islands in the Mediterranean#By area, fourth-largest island in the Mediterranean and lies southeast of the Metro ...

Description

Napoleonite is a variety of

which is characterized by orbicular structure. The grey matrix of the stone has the normal appearance of a diorite, but contains many rounded lumps 1 or 2 inches in diameter, which show

concentric In geometry, two or more objects are said to be ''concentric'' when they share the same center. Any pair of (possibly unalike) objects with well-defined centers can be concentric, including circles, spheres, regular polygons, regular polyh ...

zones of light and dark colors. In these

spheroid A spheroid, also known as an ellipsoid of revolution or rotational ellipsoid, is a quadric surface (mathematics), surface obtained by Surface of revolution, rotating an ellipse about one of its principal axes; in other words, an ellipsoid with t ...

s also a distinct and well-marked radial arrangement of the

crystal A crystal or crystalline solid is a solid material whose constituents (such as atoms, molecules, or ions) are arranged in a highly ordered microscopic structure, forming a crystal lattice that extends in all directions. In addition, macros ...

s is apparent. The center of the spheroid is usually white or pale grey and consists mainly of

feldspar Feldspar ( ; sometimes spelled felspar) is a group of rock-forming aluminium tectosilicate minerals, also containing other cations such as sodium, calcium, potassium, or barium. The most common members of the feldspar group are the ''plagiocl ...

; the same

mineral In geology and mineralogy, a mineral or mineral species is, broadly speaking, a solid substance with a fairly well-defined chemical composition and a specific crystal structure that occurs naturally in pure form.John P. Rafferty, ed. (2011): Mi ...

makes the pale zones while the dark ones are rich in

hornblende Hornblende is a complex silicate minerals#Inosilicates, inosilicate series of minerals. It is not a recognized mineral in its own right, but the name is used as a general or field term, to refer to a dark amphibole. Hornblende minerals are common ...

and

pyroxene The pyroxenes (commonly abbreviated Px) are a group of important rock-forming inosilicate minerals found in many igneous and metamorphic rocks. Pyroxenes have the general formula , where X represents ions of calcium (Ca), sodium (Na), iron ( ...

. The feldspar is a basic variety of

plagioclase Plagioclase ( ) is a series of Silicate minerals#Tectosilicates, tectosilicate (framework silicate) minerals within the feldspar group. Rather than referring to a particular mineral with a specific chemical composition, plagioclase is a continu ...

(

anorthite Anorthite (< ''an'' 'not' + ''ortho'' 'straight') is the

calcium

bytownite Bytownite is a calcium rich member of the plagioclase solid solution series of feldspar minerals with composition between anorthite and labradorite. It is usually defined as having between 70 and 90% An (formula: ). Like others of the series, byt ...

). Though mostly rounded, the spheroids may be elliptical or subangular; sometimes they are in contact with one another but usually they are separated by small areas of massive diorite.

Uses

When cut and polished the rock makes a beautiful and striking ornamental stone. It has been used for making

paperweight A paperweight is a small solid object heavy enough, when placed on top of papers, to keep them from blowing away in a breeze or from moving under the strokes of a painting brush (as with Chinese calligraphy). While any object, such as a stone, ...

s and other small ornamental articles.

Spheroidal structure

Spheroidal structure is found in other diorites and in quite a number of

granite Granite ( ) is a coarse-grained (phanerite, phaneritic) intrusive rock, intrusive igneous rock composed mostly of quartz, alkali feldspar, and plagioclase. It forms from magma with a high content of silica and alkali metal oxides that slowly coo ...

s in various places, such as

Sweden Sweden, formally the Kingdom of Sweden, is a Nordic countries, Nordic country located on the Scandinavian Peninsula in Northern Europe. It borders Norway to the west and north, and Finland to the east. At , Sweden is the largest Nordic count ...

Russia Russia, or the Russian Federation, is a country spanning Eastern Europe and North Asia. It is the list of countries and dependencies by area, largest country in the world, and extends across Time in Russia, eleven time zones, sharing Borders ...

America The United States of America (USA), also known as the United States (U.S.) or America, is a country primarily located in North America. It is a federal republic of 50 U.S. state, states and a federal capital district, Washington, D.C. The 48 ...

Sardinia Sardinia ( ; ; ) is the Mediterranean islands#By area, second-largest island in the Mediterranean Sea, after Sicily, and one of the Regions of Italy, twenty regions of Italy. It is located west of the Italian Peninsula, north of Tunisia an ...

and

Ireland Ireland (, ; ; Ulster Scots dialect, Ulster-Scots: ) is an island in the North Atlantic Ocean, in Northwestern Europe. Geopolitically, the island is divided between the Republic of Ireland (officially Names of the Irish state, named Irelan ...

. It is by no means common, however, and usually occurs in only a small part of a

granitic A granitoid is a broad term referring to a diverse group of coarse-grained igneous rocks that are widely distributed across the globe, covering a significant portion of the Earth's exposed surface and constituting a large part of the continental ...

or dioritic mass, being sometimes restricted to an area of a few square yards. In most cases it is found near the center of the outcrop, though exceptionally it has been found quite close to the margin. It arises evidently from intermittent and repeated crystallization of the rock-forming minerals in successive stages.

Formation

Such a process would be favored by complete rest, which would allow of

supersaturation In physical chemistry, supersaturation occurs with a solution (chemistry), solution when the concentration of a solute exceeds the concentration specified by the value of solubility at Solubility equilibrium, equilibrium. Most commonly the term ...

of the

magma Magma () is the molten or semi-molten natural material from which all igneous rocks are formed. Magma (sometimes colloquially but incorrectly referred to as ''lava'') is found beneath the surface of the Earth, and evidence of magmatism has also ...

by one of the components. Rapid crystallization would follow, producing deposits on any suitable nuclei, and the

s then formed might have a radial disposition on the surfaces on which they grew. The magma might then be greatly impoverished in this particular substance, and another deposit of a different kind would follow, producing a zone of different color. The nucleus for the spheroidal growth is sometimes an early

porphyritic Porphyritic is an adjective used in geology to describe igneous rocks with a distinct difference in the size of mineral crystals, with the larger crystals known as phenocrysts. Both extrusive and intrusive rocks can be porphyritic, meaning ...

crystal, sometimes an enclosure of

gneiss Gneiss (pronounced ) is a common and widely distributed type of metamorphic rock. It is formed by high-temperature and high-pressure metamorphic processes acting on formations composed of igneous or sedimentary rocks. This rock is formed under p ...

, et cetera, and often does not differ essentially in composition from the surrounding rock. When spheroids are in contact their inner zones may be distinct while the outer ones are common to both individuals having the outlines of a figure of eight. This proves that growth was

centrifugal Centrifugal (a key concept in rotating systems) may refer to: *Centrifugal casting (industrial), Centrifugal casting (silversmithing), and Spin casting (centrifugal rubber mold casting), forms of centrifigual casting *Centrifugal clutch *Centrifug ...

, not centripetal. Many varieties of spheroids are described presenting great differences in composition and in structure. Some are merely rounded balls consisting of the earliest minerals of the rock, such as

apatite Apatite is a group of phosphate minerals, usually hydroxyapatite, fluorapatite and chlorapatite, with high concentrations of Hydroxide, OH−, Fluoride, F− and Chloride, Cl− ion, respectively, in the crystal. The formula of the admixture of ...

zircon Zircon () is a mineral belonging to the group of nesosilicates and is a source of the metal zirconium. Its chemical name is zirconium(IV) silicate, and its corresponding chemical formula is Zr SiO4. An empirical formula showing some of th ...

biotite Biotite is a common group of phyllosilicate minerals within the mica group, with the approximate chemical formula . It is primarily a solid-solution series between the iron- endmember annite, and the magnesium-endmember phlogopite; more al ...

and

, and possessing no regular arrangement. Others have as centers a foreign fragment such as

hornfel Hornfels is the group name for a set of contact metamorphic rocks that have been baked and hardened by the heat of intrusive igneous masses and have been rendered massive, hard, splintery, and in some cases exceedingly tough and durable. These p ...

s, with one or more zones, pale or dark, around this. Radial arrangement of the crystals, though often very perfect, is by no means universal. The spheroids are sometimes flattened or

egg-shaped An oval () is a closed curve in a plane (geometry), plane which resembles the outline of an egg. The term is not very specific, but in some areas of mathematics (projective geometry, technical drawing, etc.), it is given a more precise definitio ...

, apparently by the flow of magma at a time when they were semi-solid or plastic. As a general rule the spheroids are more

basic Basic or BASIC may refer to: Science and technology * BASIC, a computer programming language * Basic (chemistry), having the properties of a base * Basic access authentication, in HTTP Entertainment * Basic (film), ''Basic'' (film), a 2003 film ...

and richer in the iron-magnesium minerals than the surrounding rock, though some of the zones are often very rich in

quartz Quartz is a hard, crystalline mineral composed of silica (silicon dioxide). The Atom, atoms are linked in a continuous framework of SiO4 silicon–oxygen Tetrahedral molecular geometry, tetrahedra, with each oxygen being shared between two tet ...

and

. Graphic or

perthitic Perthite or perthitic texture is used to describe an intergrowth of two feldspars: a host grain of potassium-rich alkali feldspar (near K-feldspar, KAlSi3O8, in composition) includes exsolved lamellae or irregular intergrowths of sodic alkali f ...

intergrowths between the minerals of a zone are frequent. The spheroids vary in width up to 1 or 2 ft. In some cases they contain abnormal constituents such as

calcite Calcite is a Carbonate minerals, carbonate mineral and the most stable Polymorphism (materials science), polymorph of calcium carbonate (CaCO3). It is a very common mineral, particularly as a component of limestone. Calcite defines hardness 3 on ...

sillimanite Sillimanite or fibrolite is an aluminosilicate mineral with the chemical formula Al2SiO5. Sillimanite is named after the American chemist Benjamin Silliman (1779–1864). It was first described in 1824 for an occurrence in Chester, Connecticut ...

corundum Corundum is a crystalline form of aluminium oxide () typically containing traces of iron, titanium, vanadium, and chromium. It is a rock (geology), rock-forming mineral. It is a naturally transparency and translucency, transparent material, but ...

Notes

References