
Nanoarchitectonics is a technology allowing to arrange nano-sized structural units, usually a group of
atom
Every atom is composed of a nucleus and one or more electrons bound to the nucleus. The nucleus is made of one or more protons and a number of neutrons. Only the most common variety of hydrogen has no neutrons.
Every solid, liquid, gas, and ...
s or
molecule
A molecule is a group of two or more atoms held together by attractive forces known as chemical bonds; depending on context, the term may or may not include ions which satisfy this criterion. In quantum physics, organic chemistry, and bioch ...
s, in an intended configuration. It employs two major processes: nano-creation and nano-organization. Nano-organization involves re-arrangement of the structural units in a desired pattern, while nano-creation is synthesis of new materials that do not exist in nature. For example, by peeling atomic sheets off
graphite
Graphite () is a crystalline form of the element carbon. It consists of stacked layers of graphene. Graphite occurs naturally and is the most stable form of carbon under standard conditions. Synthetic and natural graphite are consumed on large ...
slab, a novel nano-material
graphene
Graphene () is an allotrope of carbon consisting of a single layer of atoms arranged in a hexagonal lattice nanostructure. can be obtained, which has very different properties from graphite.
Nanoarchitectonics is not limited to nano-creation and nano-organization, but rather employs those techniques to understand and use the ultimate functions of materials. The important technologies to achieve this goal involve manipulation of single atoms and molecules through physical interactions,
chemical reactions
A chemical reaction is a process that leads to the chemical transformation of one set of chemical substances to another. Classically, chemical reactions encompass changes that only involve the positions of electrons in the forming and breaking ...
, applied fields, or
self-assembly.
Examples
A typical example of nano-organization is the development of a
nanoelectronics circuit. Challenging electronic devices are produced experimentally, using previously discovered materials, such as
carbon nanotubes
A scanning tunneling microscopy image of a single-walled carbon nanotube
Rotating single-walled zigzag carbon nanotube
A carbon nanotube (CNT) is a tube made of carbon with diameters typically measured in nanometers.
''Single-wall carbon nan ...
,
fullerenes,
graphene
Graphene () is an allotrope of carbon consisting of a single layer of atoms arranged in a hexagonal lattice nanostructure. , single molecules having
functional groups, etc. However, their practical use is impossible without a technology (nano-organization) to integrate and link these devices into a system.
Examples of those technologies are:
[
*Physical manipulation of atoms and molecules has already been achieved using, e.g., atomically sharp needles of a scanning tunneling microscope or an ]atomic force microscope
Atomic force microscopy (AFM) or scanning force microscopy (SFM) is a very-high-resolution type of scanning probe microscopy (SPM), with demonstrated resolution on the order of fractions of a nanometer, more than 1000 times better than the diffr ...
.
*Chemical manipulation can be realized through, e.g., electrochemical reactions induced by localized electric field in a nanoelectronic device or through local polymerization
In polymer chemistry, polymerization (American English), or polymerisation (British English), is a process of reacting monomer, monomer molecules together in a chemical reaction to form polymer chains or three-dimensional networks. There are ...
.
*Field-induced manipulation is a widely explored direction where control over atoms or molecules is achieved using various combinations of electric, magnetic, elastic and other fields. A well-known example is manipulation of individual atoms by laser
A laser is a device that emits light through a process of optical amplification based on the stimulated emission of electromagnetic radiation. The word "laser" is an acronym for "light amplification by stimulated emission of radiation". The fir ...
beams ("optical tweezers
Optical tweezers (originally called single-beam gradient force trap) are scientific instruments that use a highly focused laser beam to hold and move microscopic and sub-microscopic objects like atoms, nanoparticles and droplets, in a manner simila ...
").
* Self-assembly usually involves weaker interactions, such as van der Waals forces. Common self-assembly examples are growth of a molecular crystal
A molecular solid is a solid consisting of discrete molecules. The cohesive forces that bind the molecules together are van der Waals forces, Dipole-Dipole Forces, dipole-dipole interactions, Quadrupole, quadrupole interactions, Pi interaction, � ...
, e.g., snow
Snow comprises individual ice crystals that grow while suspended in the atmosphere—usually within clouds—and then fall, accumulating on the ground where they undergo further changes.
It consists of frozen crystalline water throughout ...
.
History
The importance of architectonics in nanoscience and nanotechnology was first accentuated in 1999 at the University of California, Los Angeles
The University of California, Los Angeles (UCLA) is a public land-grant research university in Los Angeles, California. UCLA's academic roots were established in 1881 as a teachers college then known as the southern branch of the California St ...
(UCLA).[ Next year, the first International Symposium on Nanoarchitectonics has been held in ]Tsukuba
is a city located in Ibaraki Prefecture, Japan. , the city had an estimated population of 244,528 in 108,669 households and a population density of 862 persons per km². The percentage of the population aged over 65 was 20.3%. The total ar ...
, Japan. In 2003, the term ''nanoarchitectonics'' was first mentioned in a peer-reviewed article, by a German group from the Freie Universität Berlin, and the same year a dedicated research center, Functional Engineered Nano Architectonics, has been opened at UCLA. In 2007, similar centers have been established in Tsukuba: the International Center for Materials Nanoarchitectonics
International Center for Materials Nanoarchitectonics (MANA from ''MAterials NanoArchitectonics'') is a special research unit established in 2007 at the National Institute for Materials Science (NIMS) within thWorld Premier International (WPI)Rese ...
at NIMS and Interfacial Nanoarchitectonics at AIST.[
]
References
External links
{{Commons category, Nanoarchitectonics
What is Nanoarchitectonics ?
Nanotechnology