Nano Tape
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Nano tape, also called gecko tape (or commercially as Insanity Tape or Alien Tape) is a synthetic
adhesive tape Adhesive tape is one of many varieties of backing materials coated with an adhesive. Several types of adhesives can be used. Types Pressure-sensitive tape Pressure-sensitive tape, PSA tape, self-stick tape or sticky tape consists of a pre ...
consisting of arrays of
carbon nanotube A carbon nanotube (CNT) is a tube made of carbon with a diameter in the nanometre range ( nanoscale). They are one of the allotropes of carbon. Two broad classes of carbon nanotubes are recognized: * ''Single-walled carbon nanotubes'' (''S ...
s transferred onto a backing material of flexible polymer tape. These arrays are called
synthetic setae Synthetic setae emulate the setae found on the gecko feet, toes of a gecko and scientific research in this area is driven towards the development of Dry glue, dry adhesives. Geckos have no difficulty mastering vertical walls and are apparently cap ...
and mimic the
nanostructure A nanostructure is a structure of intermediate size between microscopic and molecular structures. Nanostructural detail is microstructure at nanoscale. In describing nanostructures, it is necessary to differentiate between the number of dimen ...
s found on the toes of a gecko; this is an example of
biomimicry Biomimetics or biomimicry is the emulation of the models, systems, and elements of nature for the purpose of solving complex human problems. The terms "biomimetics" and "biomimicry" are derived from (''bios''), life, and μίμησις ('' mīm ...
. The
adhesion Adhesion is the tendency of dissimilar particles or interface (matter), surfaces to cling to one another. (Cohesion (chemistry), Cohesion refers to the tendency of similar or identical particles and surfaces to cling to one another.) The ...
is achieved not with chemical
adhesive Adhesive, also known as glue, cement, mucilage, or paste, is any non-metallic substance applied to one or both surfaces of two separate items that binds them together and resists their separation. The use of adhesives offers certain advantage ...
s, but via
van der Waals force In molecular physics and chemistry, the van der Waals force (sometimes van der Waals' force) is a distance-dependent interaction between atoms or molecules. Unlike ionic or covalent bonds, these attractions do not result from a chemical elec ...
s, which are weak electric forces generated between two atoms or molecules that are very close to each other.


Explanation

Gecko Geckos are small, mostly carnivorous lizards that have a wide distribution, found on every continent except Antarctica. Belonging to the infraorder Gekkota, geckos are found in warm climates. They range from . Geckos are unique among lizards ...
s show a remarkable ability to climb smooth vertical surfaces at high speeds, exhibiting both strong attachment and easy rapid removal, or shear adhesion, of their feet. On a gecko's foot, micrometer-sized elastic hairs called
setae In biology, setae (; seta ; ) are any of a number of different bristle- or hair-like structures on living organisms. Animal setae Protostomes Depending partly on their form and function, protostome setae may be called macrotrichia, chaetae ...
are split into nanometer-sized structures called spatulas. The shear adhesion is achieved by forming and breaking van der Waals forces between these microscopic structures and the substrate. Nano tapes mimic these structures with carbon nanotube bundles, which simulate setae and individual nanotubes, which simulate spatulas, to achieve macroscopic shear adhesion and to translate the weak van der Waals interactions into high shear forces. The shear adhesion allows the tape to be easily peeled off in the manner a gecko lifts its foot. Since the carbon nanotube arrays leave no residue on the substrate, the tape can be reused many times.


History

Nano tape is one of the first developments of
synthetic setae Synthetic setae emulate the setae found on the gecko feet, toes of a gecko and scientific research in this area is driven towards the development of Dry glue, dry adhesives. Geckos have no difficulty mastering vertical walls and are apparently cap ...
, which arose from a collaboration between the Manchester Centre for Mesoscience and Nanotechnology, and the Institute for Microelectronics Technology in Russia. Work started in 2001 and two years later results were published in ''Nature Materials''. The group prepared flexible fibers of polyimide as the synthetic setae structures on the surface of a 5 
μm The micrometre (Commonwealth English as used by the International Bureau of Weights and Measures; SI symbol: μm) or micrometer (American English), also commonly known by the non-SI term micron, is a unit of length in the International System ...
thick film of the same material using electron beam lithography and dry etching in an oxygen plasma. The fibres were 2 μm long, with a diameter of around 500 nm and a periodicity of 1.6 μm, and covered an area of roughly 1 cm2 (see figure on the left). Initially, the team used a
silicon wafer In electronics, a wafer (also called a slice or substrate) is a thin slice of semiconductor, such as a crystalline silicon (c-Si, silicium), used for the fabrication of integrated circuits and, in photovoltaics, to manufacture solar cells. The ...
as a substrate, but found that the tape's adhesive power increased by almost 1,000 times if they used a soft bonding substrate such as Scotch tape. This is because the flexible substrate yields a much higher ratio of the number of setae in contact with the surface over the total number of setae. The result of this "gecko tape" was tested by attaching a sample to the hand of a 15 cm high plastic Spider-Man figure weighing 40 g, which enabled it to stick to a glass ceiling, as is shown in the figure. The tape, which had a contact area of around with the glass, was able to carry a load of more than . However, the adhesion coefficient was only 0.06, which is low compared with real geckos (8~16).


Commercial use

Commercial nano tape is usually sold as
double-sided tape Double-sided tape is any pressure-sensitive tape that is coated with adhesive on both sides. It is designed to stick two surfaces together, often in a way which is not visible in the end product, due to it being in between the objects rather tha ...
that is useful for hanging lightweight items, such as pictures and decorative items on smooth walls. Using superaligned carbon nanotubes, some nano tapes can stay sticky in extreme temperatures.


Gallery

Gecko Leaftail 1.jpg,
Gecko Geckos are small, mostly carnivorous lizards that have a wide distribution, found on every continent except Antarctica. Belonging to the infraorder Gekkota, geckos are found in warm climates. They range from . Geckos are unique among lizards ...
climbing a glass surface Gecko foot on glass.JPG, Close view of a gecko's foot Micro and nano view of gecko's toe.jpg, Micro and nano view of gecko's toe Micro view of Gecko Tape.jpg, Micro view of nano tape


References

{{Reflist Adhesive tape Biophysics Biomimetics Nanotechnology Carbon nanotubes