
Muonium () is an
exotic atom made up of an
antimuon and an
electron
The electron (, or in nuclear reactions) is a subatomic particle with a negative one elementary charge, elementary electric charge. It is a fundamental particle that comprises the ordinary matter that makes up the universe, along with up qua ...
,
[
] which was discovered in 1960 by
Vernon W. Hughes[
] and is given the chemical symbol Mu. During the muon's lifetime, muonium can undergo chemical reactions.
Description
Because, like a proton, the antimuon's mass is vastly larger than that of the electron, muonium () is more similar to
atomic hydrogen () than
positronium
Positronium (Ps) is a system consisting of an electron and its antimatter, anti-particle, a positron, bound together into an exotic atom, specifically an onium. Unlike hydrogen, the system has no protons. The system is unstable: the two part ...
(). Its
Bohr radius and ionization energy are within 0.5% of
hydrogen
Hydrogen is a chemical element; it has chemical symbol, symbol H and atomic number 1. It is the lightest and abundance of the chemical elements, most abundant chemical element in the universe, constituting about 75% of all baryon, normal matter ...
,
deuterium
Deuterium (hydrogen-2, symbol H or D, also known as heavy hydrogen) is one of two stable isotopes of hydrogen; the other is protium, or hydrogen-1, H. The deuterium nucleus (deuteron) contains one proton and one neutron, whereas the far more c ...
, and
tritium
Tritium () or hydrogen-3 (symbol T or H) is a rare and radioactive isotope of hydrogen with a half-life of ~12.33 years. The tritium nucleus (t, sometimes called a ''triton'') contains one proton and two neutrons, whereas the nucleus of the ...
, and thus it can usefully be considered as an exotic light isotope of hydrogen.
Properties
Although muonium is short-lived, physical chemists study it using
muon spin spectroscopy (μSR),
[
] a magnetic resonance technique analogous to
nuclear magnetic resonance
Nuclear magnetic resonance (NMR) is a physical phenomenon in which nuclei in a strong constant magnetic field are disturbed by a weak oscillating magnetic field (in the near field) and respond by producing an electromagnetic signal with a ...
(NMR) or
electron spin resonance (ESR)
spectroscopy
Spectroscopy is the field of study that measures and interprets electromagnetic spectra. In narrower contexts, spectroscopy is the precise study of color as generalized from visible light to all bands of the electromagnetic spectrum.
Spectro ...
. Like ESR, μSR is useful for the analysis of chemical transformations and the structure of compounds with novel or potentially valuable electronic properties. Muonium is usually studied by
muon spin rotation, in which the muonium atom's spin precesses in a
magnetic field
A magnetic field (sometimes called B-field) is a physical field that describes the magnetic influence on moving electric charges, electric currents, and magnetic materials. A moving charge in a magnetic field experiences a force perpendicular ...
applied transverse to the muon spin direction (since muons are typically produced in a
spin-polarized state from the decay of
pion
In particle physics, a pion (, ) or pi meson, denoted with the Greek alphabet, Greek letter pi (letter), pi (), is any of three subatomic particles: , , and . Each pion consists of a quark and an antiquark and is therefore a meson. Pions are the ...
s), and by
avoided level crossing (ALC), which is also called
level crossing resonance (LCR).
The latter employs a magnetic field applied longitudinally to the polarization direction, and monitors the relaxation of muon spins caused by "flip/flop" transitions with other magnetic nuclei.
Because the muon is a
lepton
In particle physics, a lepton is an elementary particle of half-integer spin (Spin (physics), spin ) that does not undergo strong interactions. Two main classes of leptons exist: electric charge, charged leptons (also known as the electron-li ...
, the atomic energy levels of muonium can be calculated with great precision from
quantum electrodynamics
In particle physics, quantum electrodynamics (QED) is the Theory of relativity, relativistic quantum field theory of electrodynamics. In essence, it describes how light and matter interact and is the first theory where full agreement between quant ...
(QED), unlike in the case of hydrogen, where the precision is limited by uncertainties related to the internal structure of the
proton
A proton is a stable subatomic particle, symbol , Hydron (chemistry), H+, or 1H+ with a positive electric charge of +1 ''e'' (elementary charge). Its mass is slightly less than the mass of a neutron and approximately times the mass of an e ...
. For this reason, muonium is an ideal system for studying bound-state QED and also for searching for physics beyond the
Standard Model
The Standard Model of particle physics is the Scientific theory, theory describing three of the four known fundamental forces (electromagnetism, electromagnetic, weak interaction, weak and strong interactions – excluding gravity) in the unive ...
.
[
]
Nomenclature
Normally in the nomenclature of particle physics, an atom composed of a positively charged particle bound to an electron is named after the positive particle with "-ium" replacing an "-on" suffix, in this case "muium". Replacing "-on" with (or otherwise appending) "-
onium" is mostly used for
bound state
A bound state is a composite of two or more fundamental building blocks, such as particles, atoms, or bodies, that behaves as a single object and in which energy is required to split them.
In quantum physics, a bound state is a quantum state of a ...
s of a particle with its own antiparticle. The exotic atom consisting of a muon and an antimuon (which is yet to be observed) is known as
true muonium.
See also
*
Muonic hydrogen
*
Muon-catalyzed fusion
References
Exotic atoms
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Atomic physics
Particle physics
Spectroscopy
Quantum electrodynamics