
A molozonide (or "molecular ozonide") is a 1,2,3-trioxolane, which can also be considered a cyclic disubstituted
trioxidane derivative. Molozonides are formed by
cycloaddition
In organic chemistry, a cycloaddition is a chemical reaction in which "two or more Unsaturated hydrocarbon, unsaturated molecules (or parts of the same molecule) combine with the formation of a cyclic adduct in which there is a net reduction of th ...
of
ozone
Ozone () (or trioxygen) is an Inorganic compound, inorganic molecule with the chemical formula . It is a pale blue gas with a distinctively pungent smell. It is an allotrope of oxygen that is much less stable than the diatomic allotrope , break ...
and an
alkene
In organic chemistry, an alkene, or olefin, is a hydrocarbon containing a carbon–carbon double bond. The double bond may be internal or at the terminal position. Terminal alkenes are also known as Alpha-olefin, α-olefins.
The Internationa ...
during
ozonolysis
In organic chemistry, ozonolysis is an organic reaction where the Saturated and unsaturated compounds, unsaturated bonds are Bond cleavage, cleaved with ozone (). Multiple carbon–carbon bond are replaced by carbonyl () groups, such as aldehydes ...
, as a transient intermediate which quickly rearranges to give the
ozonide
Ozonide is the polyatomic anion . Cyclic organic compounds formed by the addition of ozone () to an alkene are also called ozonides.
Ionic ozonides
Inorganic ozonides are dark red salts. The anion has the bent shape of the ozone molecule.
In ...
(1,2,4-trioxolane), the relatively stable product generated immediately prior to reductive or oxidative cleavage to form alcohols, carbonyl compounds, or derivatives thereof.
References
Oxygen heterocycles
Polyoxides
Heterocyclic compounds with 1 ring
{{Heterocyclic-stub