Mogovidite is a very rare mineral of the
eudialyte group
Eudialyte group is a group of complex trigonal zircono- and, more rarely, titanosilicate minerals with general formula (1)N(2)N(3)N(4)N(5)sub>3 (1a)M(1b)sub>3M(2)3M(4)Z3 i24O72'4X2, where N(1) and N(2) and N(3) and N(5) = Na+ and more rarely H3 ...
,
It is similar to feklichevite, differing from it in the presence of essential vacancies (at the M3 site) and
carbonate
A carbonate is a salt of carbonic acid, (), characterized by the presence of the carbonate ion, a polyatomic ion with the formula . The word "carbonate" may also refer to a carbonate ester, an organic compound containing the carbonate group ...
group.
Another specific feature is the dominance of ferric iron – a feature shared with other eudialyte-group members, including
feklichevite
Feklichevite is a rare mineral of the eudialyte group with the formula Na11Ca9(Fe3+,Fe2+)2Zr3NbSi(Si3O9)2(Si9O27)2.Pekov, I.V., Ekimenkova, I.A., Chukanov, N.V., Rastsvetaeva, R.K., Kononkova, N.N., Pekova, N.A., and Zadov, A.E., 2001. Feklichevit ...
,
fengchengite,
golyshevite and
ikranite. Similarly to
golyshevite, it is
calcium
Calcium is a chemical element; it has symbol Ca and atomic number 20. As an alkaline earth metal, calcium is a reactive metal that forms a dark oxide-nitride layer when exposed to air. Its physical and chemical properties are most similar to it ...
-dominant, however on three (not two) sites: M(1), N(3) and N(4).
[Mindat, Mogovidite, http://www.mindat.org/min-27487.html] It has a
molecular mass
The molecular mass () is the mass of a given molecule, often expressed in units of daltons (Da). Different molecules of the same compound may have different molecular masses because they contain different isotopes of an element. The derived quan ...
of 3,066.24 gm.
Mogovidite's formula given as .
[Chukanov, N.V., Moiseyev, M.M., Rastsvetayeva, R.K., Rozenberg, K.A., and Zadov, A.E., 2005. Golyshevite (Na,Ca)10Ca9(Fe3+,Fe2+)2Zr3NbSi25O72(CO3)(OH)3·H2O, and Mogovidite, Na9(Ca,Na)6Ca6(Fe3+,Fe2+)2Zr3[]Si25O72(CO3)(OH,H2O)4, new eudialyte-group minerals from calcium-rich agpaitic pegmatites of the Kovdor massif, Kola Peninsula. Zapiski Rossiyskogo Mineralogicheskogo Obshchestva 134(6), 36–47 (in Russian, with English abstract)] The formula given is based on the original one but extended to show the presence of cyclic silicate groups.
Occurrence and association
As
golyshevite, mogovidite was discovered in
calcium
Calcium is a chemical element; it has symbol Ca and atomic number 20. As an alkaline earth metal, calcium is a reactive metal that forms a dark oxide-nitride layer when exposed to air. Its physical and chemical properties are most similar to it ...
-bearing peralkaline
pegmatite
A pegmatite is an igneous rock showing a very coarse texture, with large interlocking crystals usually greater in size than and sometimes greater than . Most pegmatites are composed of quartz, feldspar, and mica, having a similar silicic c ...
s of the
Kovdor
Kovdor (, ) is a types of inhabited localities in Russia, town and the administrative center of Kovdorsky District of Murmansk Oblast, Russia, mostly known for its mining industry. Population:
History
By 1965, Kovdor was a urban-type settlemen ...
massif, Kola Peninsula, Russia. The mineral name is of geographical origin – mogovidite is named after Mt. Mogo-Vid located in the vicinity of type locality. Association of mogovidite:
aegirine
Aegirine is a member of the clinopyroxene group of inosilicate minerals. It is the sodium endmember of the aegirine– augite series. It has the chemical formula NaFeSi2O6, in which the iron is present as the ion Fe3+. In the aegirine–augite se ...
-
augite
Augite, also known as Augurite, is a common rock-forming pyroxene mineral with formula . The crystals are monoclinic and prismatic. Augite has two prominent cleavages, meeting at angles near 90 degrees.
Characteristics
Augite is a solid soluti ...
,
andradite
Andradite is a Mineralogy, mineral species of the Garnet, garnet group. It is a Silicate minerals#Nesosilicates, nesosilicate, with chemical formula Ca3Fe2Si3O12.
Andradite includes three varieties:
* ''Colophonite'': a historical variety found ...
,
calcite
Calcite is a Carbonate minerals, carbonate mineral and the most stable Polymorphism (materials science), polymorph of calcium carbonate (CaCO3). It is a very common mineral, particularly as a component of limestone. Calcite defines hardness 3 on ...
,
humite
Humite is a mineral found in the volcanically ejected masses of Vesuvius
Mount Vesuvius ( ) is a Somma volcano, somma–stratovolcano located on the Gulf of Naples in Campania, Italy, about east of Naples and a short distance from the sho ...
,
nepheline
Nepheline, also called nephelite (), is a rock-forming mineral in the feldspathoid groupa silica-undersaturated aluminosilicate, Na3 K Al4 Si4 O16, that occurs in intrusive and volcanic rocks with low silica, and in their associated pegmatit ...
,
pectolite,
scolecite
Scolecite is a tectosilicate mineral belonging to the zeolite group; it is a hydrated calcium silicate, Ca Al2 Si3 O10· 3H2O. Only minor amounts of sodium and traces of potassium substitute for calcium. There is an absence of barium, strontium, ...
,
titanite
Titanite, or sphene (), is a calcium titanium nesosilicate mineral, Ca Ti Si O5. Trace impurities of iron and aluminium are typically present. Also commonly present are rare earth metals including cerium and yttrium; calcium may be partly rep ...
,
zircon
Zircon () is a mineral belonging to the group of nesosilicates and is a source of the metal zirconium. Its chemical name is zirconium(IV) silicate, and its corresponding chemical formula is Zr SiO4. An empirical formula showing some of th ...
.
Notes on chemistry
Chemical impurities in mogovidite include
chlorine
Chlorine is a chemical element; it has Symbol (chemistry), symbol Cl and atomic number 17. The second-lightest of the halogens, it appears between fluorine and bromine in the periodic table and its properties are mostly intermediate between ...
,
potassium
Potassium is a chemical element; it has Symbol (chemistry), symbol K (from Neo-Latin ) and atomic number19. It is a silvery white metal that is soft enough to easily cut with a knife. Potassium metal reacts rapidly with atmospheric oxygen to ...
, and
manganese
Manganese is a chemical element; it has Symbol (chemistry), symbol Mn and atomic number 25. It is a hard, brittle, silvery metal, often found in minerals in combination with iron. Manganese was first isolated in the 1770s. It is a transition m ...
, with trace
titanium
Titanium is a chemical element; it has symbol Ti and atomic number 22. Found in nature only as an oxide, it can be reduced to produce a lustrous transition metal with a silver color, low density, and high strength, resistant to corrosion in ...
,
cerium
Cerium is a chemical element; it has Chemical symbol, symbol Ce and atomic number 58. It is a hardness, soft, ductile, and silvery-white metal that tarnishes when exposed to air. Cerium is the second element in the lanthanide series, and while it ...
, and
lanthanum
Lanthanum is a chemical element; it has symbol La and atomic number 57. It is a soft, ductile, silvery-white metal that tarnishes slowly when exposed to air. It is the eponym of the lanthanide series, a group of 15 similar elements bet ...
.
References
Cyclosilicates
Sodium minerals
Calcium minerals
Iron(II,III) minerals
Zirconium minerals
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