Metam sodium is an

organosulfur compound Organosulfur compounds are organic compounds that contain sulfur. They are often associated with foul odors, but many of the sweetest compounds known are organosulfur derivatives, e.g., saccharin. Nature abounds with organosulfur compounds—sulf ...

with the formula . The compound is a sodium salt of a

dithiocarbamate In organic chemistry, a dithiocarbamate is a functional group with the general formula and structure . It is the analog of a carbamate in which both oxygen atoms are replaced by sulfur atoms (when only 1 oxygen is replaced the result is thio ...

. The compound exists as a colorless dihydrate, but most commonly it is encountered as an aqueous solution. It is used as a soil

fumigant Fumigation is a method of pest control or the removal of harmful micro-organisms by completely filling an area with gaseous pesticides—or fumigants—to suffocate or poison the pests within. It is used to control pests in buildings ( ...

, pesticide, herbicide, and fungicide. It is one of the most widely used pesticides in the United States, with approximately 60 million pounds used in 2001.

Preparation and properties

Metam sodium is prepared by combining

methylamine Methylamine is an organic compound with a formula of . This colorless gas is a derivative of ammonia, but with one hydrogen atom being replaced by a methyl group. It is the simplest primary amine. Methylamine is sold as a solution in methanol, ...

carbon disulfide Carbon disulfide (also spelled as carbon disulphide) is a neurotoxic, colorless, volatile liquid with the formula and structure . The compound is used frequently as a building block in organic chemistry as well as an industrial and chemical ...

, and

sodium hydroxide Sodium hydroxide, also known as lye and caustic soda, is an inorganic compound with the formula NaOH. It is a white solid ionic compound consisting of sodium cations and hydroxide anions . Sodium hydroxide is a highly caustic base and alkal ...

: : It also arises from the reaction of

methyl isothiocyanate Methyl isothiocyanate is the organosulfur compound with the formula CH3N=C=S. This low melting colorless solid is a powerful lachrymator. As a precursor to a variety of valuable bioactive compounds, it is the most important organic isothiocyan ...

and

sodium thiolate Sodium hydrosulfide is the chemical compound with the formula NaHS. This compound is the product of the half-neutralization of hydrogen sulfide () with sodium hydroxide (NaOH). NaSH and sodium sulfide are used industrially, often for similar purpos ...

. Upon exposure to the environment, metam sodium decomposes to

Safety and environmental considerations

Metam sodium is nonpersistent in the environment since it is prone to hydrolysis. The degradation products, carbon disulfide and methyl amine are however toxic. In 1991 a tank car with 19,000 gallons of metam sodium spilled into

Sacramento River The Sacramento River ( es, Río Sacramento) is the principal river of Northern California in the United States and is the largest river in California. Rising in the Klamath Mountains, the river flows south for before reaching the Sacramento–S ...

above

Lake Shasta Shasta Lake, also popularly known as Lake Shasta, is a reservoir in Shasta County, California, United States. It began to store water in 1944 due to the impounding of the Sacramento River by Shasta Dam, the ninth tallest dam in the United ...

. This killed all fish in a 41-mile stretch of the river. By 20 years later the

rainbow trout The rainbow trout (''Oncorhynchus mykiss'') is a species of trout native to cold-water tributaries of the Pacific Ocean in Asia and North America. The steelhead (sometimes called "steelhead trout") is an anadromous (sea-run) form of the coast ...

population had recovered.

References

External links

* {{DEFAULTSORT:Metham Sodium Pesticides Herbicides Fungicides Dithiocarbamates Organic sodium salts

Preparation and properties

Safety and environmental considerations

See also

References

External links