Mendozite is a
sulfate
The sulfate or sulphate ion is a polyatomic anion with the empirical formula . Salts, acid derivatives, and peroxides of sulfate are widely used in industry. Sulfates occur widely in everyday life. Sulfates are salts of sulfuric acid and many ...
mineral, one of the
alum
An alum () is a type of chemical compound, usually a hydrated double salt, double sulfate salt (chemistry), salt of aluminium with the general chemical formula, formula , such that is a valence (chemistry), monovalent cation such as potassium ...
series, with formula NaAl(SO
4)
2·11H
2O. It is a hydrated form of
sodium aluminium sulfate (soda alum).
It was discovered in western
Argentina
Argentina, officially the Argentine Republic, is a country in the southern half of South America. It covers an area of , making it the List of South American countries by area, second-largest country in South America after Brazil, the fourt ...
in 1868, probably near
San Juan San Juan, Spanish for Saint John (disambiguation), Saint John, most commonly refers to:
* San Juan, Puerto Rico
* San Juan, Argentina
* San Juan, Metro Manila, a highly urbanized city in the Philippines
San Juan may also refer to:
Places Arge ...
. The exact location has been lost, but was described as "San Juan, near
Mendoza", and it is the latter city that give the mineral its name.
It occurs in
evaporites
An evaporite () is a water-soluble sedimentary mineral deposit that results from concentration and crystallization by evaporation from an aqueous solution. There are two types of evaporite deposits: marine, which can also be described as ocean ...
, presumably from the
oxidation
Redox ( , , reduction–oxidation or oxidation–reduction) is a type of chemical reaction in which the oxidation states of the reactants change. Oxidation is the loss of electrons or an increase in the oxidation state, while reduction is ...
of
sulfide mineral
The sulfide minerals are a class of minerals containing sulfide (S2−) or disulfide () as the major anion. Some sulfide minerals are economically important as metal ores. The sulfide class also includes the selenide mineral, selenides, the tell ...
s in the presence of
clay
Clay is a type of fine-grained natural soil material containing clay minerals (hydrous aluminium phyllosilicates, e.g. kaolinite, ). Most pure clay minerals are white or light-coloured, but natural clays show a variety of colours from impuriti ...
s.
It is very soluble in water, and so can only be found in dry regions: however, in can still
effloresce (lose
water of crystallisation) in extremely arid climates,
altering to
tamarugite (the hexahydrate).
Bibliography
*
Palache, P.; Berman H.; Frondel, C. (1960). "''Dana's System of Mineralogy, Volume II: Halides, Nitrates, Borates, Carbonates, Sulfates, Phosphates, Arsenates, Tungstates, Molybdates, Etc. (Seventh Edition)"'' John Wiley and Sons, Inc., New York, pp. 469-471.
References
Sodium minerals
Aluminium minerals
Sulfate minerals
Monoclinic minerals
Minerals in space group 15
{{sulfate-mineral-stub