
Marine clay is a type of
clay
Clay is a type of fine-grained natural soil material containing clay minerals (hydrous aluminium phyllosilicates, e.g. kaolinite, ). Most pure clay minerals are white or light-coloured, but natural clays show a variety of colours from impuriti ...
found in coastal regions around the world. In the northern, deglaciated regions, it can sometimes be
quick clay, which is notorious for being involved in landslides.
Marine clay is a particle of soil that is dedicated to a particle size class, this is usually associated with USDA's classification with
sand
Sand is a granular material composed of finely divided mineral particles. Sand has various compositions but is usually defined by its grain size. Sand grains are smaller than gravel and coarser than silt. Sand can also refer to a textural ...
at 0.05mm,
silt
Silt is granular material of a size between sand and clay and composed mostly of broken grains of quartz. Silt may occur as a soil (often mixed with sand or clay) or as sediment mixed in suspension (chemistry), suspension with water. Silt usually ...
at 0.05-.002mm and clay being less than 0.002 mm in diameter. Paired with the fact this size of particle was deposited within a marine system involving the
erosion
Erosion is the action of surface processes (such as Surface runoff, water flow or wind) that removes soil, Rock (geology), rock, or dissolved material from one location on the Earth's crust#Crust, Earth's crust and then sediment transport, tran ...
and
transportation
Transport (in British English) or transportation (in American English) is the intentional Motion, movement of humans, animals, and cargo, goods from one location to another. Mode of transport, Modes of transport include aviation, air, land tr ...
of the clay into the ocean.
Soil particles become suspended when in a
solution
Solution may refer to:
* Solution (chemistry), a mixture where one substance is dissolved in another
* Solution (equation), in mathematics
** Numerical solution, in numerical analysis, approximate solutions within specified error bounds
* Solu ...
with water, with sand being affected by the force of gravity first with suspended silt and clay still floating in solution. This is also known as
turbidity
Turbidity is the cloudiness or haziness of a fluid caused by large numbers of individual particles that are generally invisible to the naked eye, similar to smoke in air. The measurement of turbidity is a key test of both water clarity and wa ...
, in which floating soil particles create a murky brown color to a water solution. These clay particles are then transferred to the
abyssal plain
An abyssal plain is an underwater plain on the deep ocean floor, usually found at depths between . Lying generally between the foot of a continental rise and a mid-ocean ridge, abyssal plains cover more than 50% of the Earth's surface. They ...
in which they are deposited in high percentages of clay.
Once the clay is deposited on the ocean floor it can change its structure through a process known as
flocculation
In colloidal chemistry, flocculation is a process by which colloidal particles come out of Suspension (chemistry), suspension to sediment in the form of floc or flake, either spontaneously or due to the addition of a clarifying agent. The actio ...
, process by which fine particulates are caused to clump together or floc. These can be either edge to edge flocculation or edge to face flocculation. Relating to individual clay particles interacting with each other. Clays can also be aggregated or shifted in their structure besides being flocculated.
Particles configurations
Clay particles can self-assemble into various configurations, each with totally different properties.
This change in structure to the clay particles is due to a swap in
cations
An ion () is an atom or molecule with a net electrical charge. The charge of an electron is considered to be negative by convention and this charge is equal and opposite to the charge of a proton, which is considered to be positive by convent ...
with the basic structure of a clay particle. This basic structure of the clay particle is known as a silica
tetrahedral
In geometry, a tetrahedron (: tetrahedra or tetrahedrons), also known as a triangular pyramid, is a polyhedron composed of four triangular Face (geometry), faces, six straight Edge (geometry), edges, and four vertex (geometry), vertices. The tet ...
or aluminum
octahedral
In geometry, an octahedron (: octahedra or octahedrons) is any polyhedron with eight faces. One special case is the regular octahedron, a Platonic solid composed of eight equilateral triangles, four of which meet at each vertex. Many types of i ...
. They are the basic structure of clay particles composing of one
cation
An ion () is an atom or molecule with a net electrical charge. The charge of an electron is considered to be negative by convention and this charge is equal and opposite to the charge of a proton, which is considered to be positive by convent ...
, usually
silica
Silicon dioxide, also known as silica, is an oxide of silicon with the chemical formula , commonly found in nature as quartz. In many parts of the world, silica is the major constituent of sand. Silica is one of the most complex and abundant f ...
or
aluminum
Aluminium (or aluminum in North American English) is a chemical element; it has chemical symbol, symbol Al and atomic number 13. It has a density lower than that of other common metals, about one-third that of steel. Aluminium has ...
surrounded by
hydroxide
Hydroxide is a diatomic anion with chemical formula OH−. It consists of an oxygen and hydrogen atom held together by a single covalent bond, and carries a negative electric charge. It is an important but usually minor constituent of water. It ...
anions
An ion () is an atom or molecule with a net electrical charge. The charge of an electron is considered to be negative by convention and this charge is equal and opposite to the charge of a proton, which is considered to be positive by convent ...
, these particles form in sheets forming what we know as clay particles and have very specific properties to them including micro
porosity
Porosity or void fraction is a measure of the void (i.e. "empty") spaces in a material, and is a fraction of the volume of voids over the total volume, between 0 and 1, or as a percentage between 0% and 100%. Strictly speaking, some tests measure ...
which is the ability of clay to hold water against the force of gravity,
shrink swell capacity and
absorption capabilities.
When clay is deposited in the
ocean
The ocean is the body of salt water that covers approximately 70.8% of Earth. The ocean is conventionally divided into large bodies of water, which are also referred to as ''oceans'' (the Pacific, Atlantic, Indian Ocean, Indian, Southern Ocean ...
, the presence of excess ions in seawater causes a loose, open structure of the clay particles to form, a process known as
flocculation
In colloidal chemistry, flocculation is a process by which colloidal particles come out of Suspension (chemistry), suspension to sediment in the form of floc or flake, either spontaneously or due to the addition of a clarifying agent. The actio ...
. Once stranded and dried by ancient changing ocean levels, this open framework means that such clay is open to water infiltration. Construction in marine clays thus presents a
geotechnical engineering
Geotechnical engineering, also known as geotechnics, is the branch of civil engineering concerned with the engineering behavior of earth materials. It uses the principles of soil mechanics and rock mechanics to solve its engineering problems. I ...
challenge.
"Overcoming Problems with Marine Clays", Fairfax County, Virginia
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Where clay overlies peat, a lateral movement of the coastline is indicated and shows a rise in relative sea level
Effect on building foundations
Swelling of marine clay has the potential to destroy building foundations in only a few years. Due to the changes in climatic conditions on the construction site, the pavement constructed on the marine clay (as subgrade) will have less durability and requires lot of maintenance cost. Some simple precautions, however, can reduce the hazard significantly .
The swapping of this positive cation
An ion () is an atom or molecule with a net electrical charge. The charge of an electron is considered to be negative by convention and this charge is equal and opposite to the charge of a proton, which is considered to be positive by convent ...
with another is what makes different types of clays including Kaolinite
Kaolinite ( ; also called kaolin) is a clay mineral, with the chemical composition Al2 Si2 O5( OH)4. It is a layered silicate mineral, with one tetrahedral sheet of silica () linked through oxygen atoms to one octahedral sheet of alumina () ...
, montmorillonite
Montmorillonite is a very soft phyllosilicate group of minerals that form when they precipitate from water solution as microscopic crystals, known as clay. It is named after Montmorillon in France. Montmorillonite, a member of the smectite grou ...
, smectite
A smectite (; ; ) is a mineral mixture of various swelling sheet silicates (phyllosilicates), which have a three-layer 2:1 (TOT) structure and belong to the clay minerals. Smectites mainly consist of montmorillonite, but can often contain secon ...
and illite
Illite, also called hydromica or hydromuscovite, is a group of closely related non-expanding clay minerals. Illite is a secondary mineral precipitate, and an example of a phyllosilicate, or layered alumino-silicate. Its structure is a 2:1 sandw ...
. This happens in marine clays because the ocean's water is high in solution with cations making it very easy to overcome the clays negative net charge and swap the clays cation with a less positive one. These marine clays can be what are known as quick clays, which are notorious for its erosive properties. A great example of these quick clays is in the Pacific Northwest
The Pacific Northwest (PNW; ) is a geographic region in Western North America bounded by its coastal waters of the Pacific Ocean to the west and, loosely, by the Rocky Mountains to the east. Though no official boundary exists, the most common ...
. They are known as blue goo
Blue goo is a sticky, plasticky, blueish-grey, clay-textured soil derived from a highly weathered serpentinite mélange. The name derives from the soil's color; a result of undergoing anaerobic conditions and becoming gleyed. A greyer variation ...
which is a mix of clay and mélange
In geology, a mélange is a large-scale breccia, a mappable body of rock characterized by a lack of continuous bedding and the inclusion of fragments of rock of all sizes, contained in a fine-grained deformed matrix. The mélange typically con ...
( greenstone, basalt
Basalt (; ) is an aphanite, aphanitic (fine-grained) extrusive igneous rock formed from the rapid cooling of low-viscosity lava rich in magnesium and iron (mafic lava) exposed at or very near the planetary surface, surface of a terrestrial ...
, chert
Chert () is a hard, fine-grained sedimentary rock composed of microcrystalline or cryptocrystalline quartz, the mineral form of silicon dioxide (SiO2). Chert is characteristically of biological origin, but may also occur inorganically as a prec ...
, shale
Shale is a fine-grained, clastic sedimentary rock formed from mud that is a mix of flakes of Clay mineral, clay minerals (hydrous aluminium phyllosilicates, e.g., Kaolinite, kaolin, aluminium, Al2Silicon, Si2Oxygen, O5(hydroxide, OH)4) and tiny f ...
, sandstone
Sandstone is a Clastic rock#Sedimentary clastic rocks, clastic sedimentary rock composed mainly of grain size, sand-sized (0.0625 to 2 mm) silicate mineral, silicate grains, Cementation (geology), cemented together by another mineral. Sand ...
, schists
Schist ( ) is a medium-grained metamorphic rock generally derived from fine-grained sedimentary rock, like shale. It shows pronounced ''schistosity'' (named for the rock). This means that the rock is composed of mineral grains easily seen with a ...
. uplifted through the accretionary wedge
An accretionary wedge or accretionary prism forms from sediments accreted onto the non- subducting tectonic plate at a convergent plate boundary. Most of the material in the accretionary wedge consists of marine sediments scraped off from the ...
). These quick clays have a very high-risk factor associated with them if they are built upon, as they are very unstable due to the fact that liquefaction
In materials science, liquefaction is a process that generates a liquid from a solid or a gas or that generates a non-liquid phase which behaves in accordance with fluid dynamics.
It occurs both naturally and artificially. As an example of t ...
happens when it becomes saturated and literally flows, causing mass wasting events to happen. Other marine clays are used all around the world for many different uses, such as ceramics
A ceramic is any of the various hard, brittle, heat-resistant, and corrosion-resistant materials made by shaping and then firing an inorganic, nonmetallic material, such as clay, at a high temperature. Common examples are earthenware, porce ...
, building material, including adobe
Adobe (from arabic: الطوب Attub ; ) is a building material made from earth and organic materials. is Spanish for mudbrick. In some English-speaking regions of Spanish heritage, such as the Southwestern United States, the term is use ...
. Clay layers in soils which can be used as an impermeable layer are very important for dumps or chemical spills as they have a very high absorption capacity for heavy metals. For these clays to be available for human use they must have been eroded, deposited on the ocean floor and then uplifted through means of tectonic
Tectonics ( via Latin ) are the processes that result in the structure and properties of the Earth's crust and its evolution through time. The field of ''planetary tectonics'' extends the concept to other planets and moons.
These processes ...
activity to bring it to land.
During the construction of Marina Barrage in Singapore
Singapore, officially the Republic of Singapore, is an island country and city-state in Southeast Asia. The country's territory comprises one main island, 63 satellite islands and islets, and one outlying islet. It is about one degree ...
, marine clay was found at the site. Since marine clay was the cause of the Nicoll Highway collapse years previous, the construction team removed all the marine clay to ensure the stability of Marina Barrage. Later on, they found marine clay mixed with seawater even in the deeper underground.
Geotechnical problems posed by marine clay can be handled by various ground improvement techniques. Marine clay can be densified by mixing it with cement or similar binding material in specific proportions. Marine clay can be stabilised using wastes of various industries like porcelain industry and tree-cutting industries. This method is usually adopted in highways where marine clay is used as a subgrade soil.
References
{{reflist
Bibliography
* ̈Effect of pore water chemistry on the hydro-mechanical behaviour of Lianyungang soft marine clay- Deng, Y.F.; Yue, X.B.; Cui, Y.J.; Shao, G.H.; Liu, S.Y.; Zhang, D.W. Applied Clay Science, June 2014, Vol.95, pp. 167–175
* ̈Strength of High Water Content Marine Clay Stabilized by Low Amount of Cement; Zhang, R; Santoso, A; Tan, T; Phoon, Kː Journal of Geotechnical and Geoenvironmental Engineering, April 23, 2013
* Structuration and Destructuration Behavior of Cement-Treated Singapore Marine Clay; Kamruzzaman, A; Chew, S; Lee, F; Journal of Geotechnical Engineering, Apr. 2009, Issue 4, pp. 573–589
* Sulfidization of lacustrine glacial clay upon Holocene marine transgression (Arkona Basin, Baltic Sea); Holmkvist, Lars; Kamyshny, Alexey; Brüchert, Volker; Ferdelman, Timothy G.; Jørgensen, Bo Barker; Geochimica et Cosmochimica Acta, 1 October 2014, Vol.142, pp. 75–94
* Linear and Nonlinear Dynamic Response of Piles in Soft Marine Clay; Dezi, Francesca; Gara, Fabrizio; Roia, Davide; Journal of Geotechnical and Geoenvironmental Engineering, July 29, 2016, Vol.143(1)
Oceanography
Sediments