Tris(4-bromophenyl)ammoniumyl hexachloroantimonate is the
organic compound
In chemistry, organic compounds are generally any chemical compounds that contain carbon- hydrogen or carbon-carbon bonds. Due to carbon's ability to catenate (form chains with other carbon atoms), millions of organic compounds are known. Th ...
with the formula
6H4)3N">4-BrC6H4)3NbCl
6. Commonly known as magic blue, it is the
hexachloroantimonate salt of an amine
radical cation. It is a blue solid that reacts with many solvents but is soluble in
acetonitrile. The compound is a popular oxidizing agent in organic and
organometallic chemistry, with a reduction potential of 0.67 V versus
ferrocene
Ferrocene is an organometallic compound with the formula . The molecule is a complex consisting of two cyclopentadienyl rings bound to a central iron atom. It is an orange solid with a camphor-like odor, that sublimes above room temperature, ...
/ferrocenium (
acetonitrile solution) or 0.70 V versus
ferrocene
Ferrocene is an organometallic compound with the formula . The molecule is a complex consisting of two cyclopentadienyl rings bound to a central iron atom. It is an orange solid with a camphor-like odor, that sublimes above room temperature, ...
/ferrocenium (
dichloromethane
Dichloromethane (DCM or methylene chloride, methylene bichloride) is an organochlorine compound with the formula . This colorless, volatile liquid with a chloroform-like, sweet odour is widely used as a solvent. Although it is not miscible wit ...
solution).
The structure of the cation consists of a three-bladed propeller structure with a planar amine. It is nearly identical to the parent
triphenylamine. The
weakly coordinating anion is , which is octahedral.
Related compounds
*Magic green, tris(2,4-dibromophenyl)ammoniumyl hexachloroantimonate,
References
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Amines
Free radicals
Bromoarenes
Antimony(V) compounds
Oxidizing agents
Chlorometallates