Lurgi–Ruhrgas Process
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The Lurgi–Ruhrgas process is an above-ground
coal Coal is a combustible black or brownish-black sedimentary rock, formed as rock strata called coal seams. Coal is mostly carbon with variable amounts of other Chemical element, elements, chiefly hydrogen, sulfur, oxygen, and nitrogen. Coal i ...
liquefaction and
shale oil extraction Shale oil extraction is an industrial process for unconventional oil production. This process converts kerogen in oil shale into shale oil by pyrolysis, hydrogenation, or thermal dissolution. The resultant shale oil is used as fuel oil or ...
technology. It is classified as a hot recycled solids technology.


History

The Lurgi–Ruhrgas process was originally invented in the 1940s and further developed in the 1950s for a low-temperature liquefaction of
lignite Lignite (derived from Latin ''lignum'' meaning 'wood'), often referred to as brown coal, is a soft, brown, combustible sedimentary rock formed from naturally compressed peat. It has a carbon content around 25–35% and is considered the lowest ...
(brown coal). The technology is named after its developers Lurgi Gesellschaft für Wärmetechnik G.m.b.H. and Ruhrgas AG. Over a time, the process was used for coal processing in Japan, Germany, the United Kingdom, Argentina, and former Yugoslavia. The plant in Japan processed also cracking petroleum oils to
olefins In organic chemistry, an alkene, or olefin, is a hydrocarbon containing a carbon–carbon double bond. The double bond may be internal or at the terminal position. Terminal alkenes are also known as α-olefins. The International Union of P ...
. In 1947–1949, the Lurgi–Ruhrgas process was used in Germany for
shale oil Shale oil is an unconventional oil produced from oil shale rock fragments by pyrolysis, hydrogenation, or thermal dissolution. These processes convert the organic matter within the rock (kerogen) into synthetic oil and gas. The resulting oil c ...
production. In
Lukavac Lukavac ( cyrl, Лукавац) is a city located in the Tuzla Canton of the Federation of Bosnia and Herzegovina, an entity of Bosnia and Herzegovina. According to the 2013 census, the urban centre has a population of 12,061 inhabitants, with 44 ...
,
Bosnia and Herzegovina Bosnia and Herzegovina, sometimes known as Bosnia-Herzegovina and informally as Bosnia, is a country in Southeast Europe. Situated on the Balkans, Balkan Peninsula, it borders Serbia to the east, Montenegro to the southeast, and Croatia to th ...
, two retorts for liquefaction of lignite were in operation from 1963 to 1968. The capacity of the plant was 850 tons of lignite per day. Initially, two Lurgi-Ruhrgas plants were built and operated in the U.K.: the first to be opened (by Queen Elizabeth II in 1963) was the Westfield plant in Fife, Scotland which was operated by the Scottish Gas Board. The second plant, also opened in 1963, was sited near Coleshill in the West Midlands and was operated by the West Midlands Gas Board. A third, smaller plant, was sited in
Lincolnshire Lincolnshire (), abbreviated ''Lincs'', is a Ceremonial counties of England, ceremonial county in the East Midlands and Yorkshire and the Humber regions of England. It is bordered by the East Riding of Yorkshire across the Humber estuary to th ...
, United Kingdom, but only operated during 1978–1979 with a maximum capacity of 900 tons of coal per day. In the late 1960s and early 1970s,
oil shale Oil shale is an organic-rich Granularity, fine-grained sedimentary rock containing kerogen (a solid mixture of Organic compound, organic chemical compounds) from which liquid hydrocarbons can be produced. In addition to kerogen, general compos ...
s from different European countries and from the
Green River Formation The Green River Formation is an Eocene geologic formation that records the sedimentation in a group of intermountain lakes in three basins along the present-day Green River (Colorado River), Green River in Colorado, Wyoming, and Utah. The sedimen ...
of
Colorado Colorado is a U.S. state, state in the Western United States. It is one of the Mountain states, sharing the Four Corners region with Arizona, New Mexico, and Utah. It is also bordered by Wyoming to the north, Nebraska to the northeast, Kansas ...
, the United States, were tested at the Lurgi's pilot plant in
Frankfurt Frankfurt am Main () is the most populous city in the States of Germany, German state of Hesse. Its 773,068 inhabitants as of 2022 make it the List of cities in Germany by population, fifth-most populous city in Germany. Located in the forela ...
. In the United States, the technology was promoted in cooperation with
Dravo Corporation Dravo Corporation was an American shipbuilding company with shipyards in Pittsburgh, Pennsylvania, Pittsburgh and Wilmington, Delaware. It was founded by Frank and Ralph Dravo in Pittsburgh in 1891. The corporation Initial public offering, went pub ...
. In the 1970s, the technology was licensed to the Rio Blanco Shale Oil Project for construction of a modular retort in combination with the modified ''in situ'' process. However, this plan was terminated. In 1974, the Westfield plant in Scotland was converted to a new Lurgi 'slagging gasifier' system developed jointly by British Gas and the Lurgi company. Whilst this British Gas-Lurgi process was never used commercially in the U.K., similar designs are now being built and operated in China. This converted plant finally ceased gas production in early 1998, with the site lying dormant until a demolition order was given in 2014. In 1980, the Natural Resources Authority of Jordan commissioned from the Klöckner- Lurgi consortium a pre-feasibility study of construction of an oil shale retorting complex in
Jordan Jordan, officially the Hashemite Kingdom of Jordan, is a country in the Southern Levant region of West Asia. Jordan is bordered by Syria to the north, Iraq to the east, Saudi Arabia to the south, and Israel and the occupied Palestinian ter ...
using the Lurgi–Ruhrgas process. However, although the study found the technology feasible, it was never implemented.


Technology

The Lurgi–Ruhrgas process is a hot recycled solids technology, which processes fine particles of coal or oil shale sized . As a heat carrier, it uses spent char or
spent oil shale Spent shale or spent oil shale (also known as retorted shale) is a solid residue from the shale oil extraction process of producing synthetic shale oil from oil shale. It consists of inorganic compounds (minerals) and remaining organic matter kno ...
(oil shale ash), mixed with sand or other more durable materials. In this process, crushed coal or oil shale is fed into the top of the retort. In retort, coal or oil shale is mixed with the heated char or spent oil shale particles in the mechanical mixer (
screw conveyor A screw conveyor or auger conveyor is a mechanism that uses a rotating helical screw (simple machine), screw blade, called a "''flighting''", usually within a tube, to move liquid or granular materials. They are used in many bulk handling in ...
). The heat is transferred from the heated char or spent oil shale to the coal or raw oil shale causing pyrolysis. As a result, oil shale decomposes to shale oil vapors,
oil shale gas Oil shale gas (also: retort gas or retorting gas) is a synthetic non-condensable gas mixture (syngas) produced by oil shale thermal processing (pyrolysis). Although often referred to as shale gas, it differs from the natural gas produced from shal ...
and spent oil shale. The oil vapor and product gases pass through a hot cyclone for cleaning before sending to a condenser. In the condenser, shale oil is separated from product gases. The spent oil shale, still including residual carbon ( char), is burnt at a lift pipe
combustor A combustor is a component or area of a gas turbine, ramjet, or scramjet engine where combustion takes place. It is also known as a burner, burner can, combustion chamber or flame holder. In a gas turbine engine, the ''combustor'' or combustion ...
to heat the process. If necessary, additional fuel oil is used for combustion. During the combustion process, heated solid particles in the pipe are moved to the surge bin by pre-heated air that is introduced from the bottom of the pipe. At the surge bin, solids and gases are separated, and solid particles are transferred to the mixer unit to conduct the pyrolysis of the raw oil shale. One of the disadvantages of this technology is the fact that produced shale oil vapors are mixed with shale ash causing impurities in shale oil. Ensuring the quality of produced shale oil is complicated as compared with other mineral dusts the shale ash is more difficult to collect.


See also

*
Galoter process The Galoter process (also known as TSK, UTT, or SHC; its newest modifications are called Enefit and Petroter) is a shale oil extraction technology for the production of shale oil, a type of synthetic crude oil. In this process, the oil shale is ...
*
Alberta Taciuk process The Alberta Taciuk process (ATP; known also as the AOSTRA Taciuk process) is an above-ground dry thermal retorting technology for extracting oil from oil sands, oil shale and other organics-bearing materials, including oil contaminated soils, slud ...
* Petrosix process *
Kiviter process The Kiviter process is an above ground retorting technology for shale oil extraction. History The Kiviter process is based on the earlier vertical retort technology (Pintsch's generator). This technology underwent a long process of development. ...
*
TOSCO II process The TOSCO II process is an above ground retorting technology for shale oil extraction, which uses fine particles of oil shale that are heated in a rotating kiln. The particularity of this process is that it use hot ceramic balls for the heat tran ...
*
Fushun process The Fushun process is an above-ground retorting technology for shale oil extraction. It is named after the main production site of Fushun, Liaoning province in northeastern China. History The Fushun process was developed and utilized for the extra ...
*
Paraho process The Paraho process is an above ground retorting technology for shale oil extraction. The name "Paraho" is delivered from the words "''para homem''", which means in Portuguese "for mankind". History The Paraho process was invented by John B. Jones, ...
*
KENTORT II KENTORT II is an above-ground shale oil extraction process developed by the Center for Applied Energy Research of the University of Kentucky. It is a hot recycled solids fluidized bed retorting process developed since 1982 for processing the easter ...
* Union process


References

{{DEFAULTSORT:Lurgi-Ruhrgas process Oil shale technology Coal Thermal treatment