
Luminescence is a
spontaneous emission
Spontaneous emission is the process in which a Quantum mechanics, quantum mechanical system (such as a molecule, an atom or a subatomic particle) transits from an excited state, excited energy state to a lower energy state (e.g., its ground state ...
of
radiation
In physics, radiation is the emission or transmission of energy in the form of waves or particles through space or a material medium. This includes:
* ''electromagnetic radiation'' consisting of photons, such as radio waves, microwaves, infr ...
from an electronically or vibrationally excited species not in
thermal equilibrium
Two physical systems are in thermal equilibrium if there is no net flow of thermal energy between them when they are connected by a path permeable to heat. Thermal equilibrium obeys the zeroth law of thermodynamics. A system is said to be in t ...
with its environment. A luminescent object emits ''cold light'' in contrast to
incandescence
Thermal radiation is electromagnetic radiation emitted by the thermal motion of particles in matter. All matter with a temperature greater than absolute zero emits thermal radiation. The emission of energy arises from a combination of electron ...
, where an object only emits light after heating.
Generally, the emission of light is due to the movement of electrons between different energy levels within an atom after excitation by external factors. However, the exact mechanism of light emission in vibrationally excited species is unknown.
The dials, hands, scales, and signs of aviation and navigational instruments and markings are often coated with luminescent materials in a process known as ''luminising''.
Types
* Ionoluminescence, a result of bombardment by fast ions
*
Radioluminescence, a result of bombardment by ionizing radiation
*
Electroluminescence
Electroluminescence (EL) is an optical phenomenon, optical and electrical phenomenon, in which a material emits light in response to the passage of an electric current or to a strong electric field. This is distinct from black body light emission ...
, a result of an electric current passed through a substance
**
Cathodoluminescence
Cathodoluminescence is an optical and electromagnetic phenomenon in which electrons impacting on a luminescent material such as a phosphor, cause the emission of photons which may have wavelengths in the visible spectrum. A familiar example i ...
, a result of a luminescent material being struck by electrons
*
Chemiluminescence
Chemiluminescence (also chemoluminescence) is the emission of light (luminescence) as the result of a chemical reaction, i.e. a chemical reaction results in a flash or glow of light. A standard example of chemiluminescence in the laboratory se ...
, the emission of light as a result of a
chemical reaction
A chemical reaction is a process that leads to the chemistry, chemical transformation of one set of chemical substances to another. When chemical reactions occur, the atoms are rearranged and the reaction is accompanied by an Gibbs free energy, ...
**
Bioluminescence
Bioluminescence is the emission of light during a chemiluminescence reaction by living organisms. Bioluminescence occurs in multifarious organisms ranging from marine vertebrates and invertebrates, as well as in some Fungus, fungi, microorgani ...
, a result of biochemical reactions in a living organism
**
Electrochemiluminescence
Electrochemiluminescence or electrogenerated chemiluminescence (ECL) is a kind of luminescence produced during electrochemical reactions in solutions. In electrogenerated chemiluminescence, electrochemically generated intermediates undergo a highl ...
, a result of an
electrochemical reaction
Electrochemistry is the branch of physical chemistry concerned with the relationship between electrical potential difference and identifiable chemical change. These reactions involve electrons moving via an electronically conducting phase (typica ...
**
Lyoluminescence, a result of dissolving a solid (usually heavily irradiated) in a liquid solvent
**
Candoluminescence
Candoluminescence is the light given off by certain materials at elevated temperatures (usually when exposed to a flame) that has an intensity at some wavelengths which can, through chemical action in flames, be higher than the blackbody emission ...
, is light emitted by certain materials at elevated temperatures, which differs from the
blackbody
A black body or blackbody is an idealized physical body that absorbs all incident electromagnetic radiation, regardless of frequency or angle of incidence. The radiation emitted by a black body in thermal equilibrium with its environment is ...
emission expected at the temperature in question.
*
Mechanoluminescence, a result of a mechanical action on a solid
**
Triboluminescence
Triboluminescence is a phenomenon in which light is generated when a material is mechanically pulled apart, ripped, scratched, crushed, or rubbed (see tribology). The phenomenon is not fully understood but appears in most cases to be caused by the ...
, generated when bonds in a material are broken when that material is scratched, crushed, or rubbed
**
Fractoluminescence, generated when bonds in certain crystals are broken by fractures
**
Piezoluminescence, produced by the action of pressure on certain solids
**
Sonoluminescence
Sonoluminescence is the emission of light from imploding bubbles in a liquid when excited by sound.
Sonoluminescence was first discovered in 1934 at the University of Cologne. It occurs when a sound wave of sufficient intensity induces a gaseo ...
, a result of imploding bubbles in a liquid when excited by sound
*
Crystalloluminescence, produced during
crystallization
Crystallization is a process that leads to solids with highly organized Atom, atoms or Molecule, molecules, i.e. a crystal. The ordered nature of a crystalline solid can be contrasted with amorphous solids in which atoms or molecules lack regu ...
*
Thermoluminescence, the re-emission of absorbed energy when a substance is heated
** Cryoluminescence, the emission of light when an object is cooled
(an example of this is
wulfenite
Wulfenite is a lead molybdate mineral with the formula Pb Mo O4. It often occurs as thin tabular crystals with a bright orange-red to yellow-orange color, sometimes brown, although the color can be highly variable. In its yellow form it is some ...
)
*
Photoluminescence
Photoluminescence (abbreviated as PL) is light emission from any form of matter after the absorption of photons (electromagnetic radiation). It is one of many forms of luminescence (light emission) and is initiated by photoexcitation (i.e. phot ...
, a result of the absorption of photons
**
Fluorescence
Fluorescence is one of two kinds of photoluminescence, the emission of light by a substance that has absorbed light or other electromagnetic radiation. When exposed to ultraviolet radiation, many substances will glow (fluoresce) with colore ...
, traditionally defined as the emission of light that ends immediately after the source of excitation is removed. As the definition does not fully describe the phenomenon, quantum mechanics is employed where it is defined as there is no change in spin multiplicity from the state of excitation to emission of light.
**
Phosphorescence
Phosphorescence is a type of photoluminescence related to fluorescence. When exposed to light (radiation) of a shorter wavelength, a phosphorescent substance will glow, absorbing the light and reemitting it at a longer wavelength. Unlike fluor ...
, traditionally defined as persistent emission of light after the end of excitation. As the definition does not fully describe the phenomenon, quantum mechanics is employed where it is defined as there is a change in spin multiplicity from the state of excitation to the emission of light.
Applications
*
Light-emitting diode
A light-emitting diode (LED) is a semiconductor device that emits light when current flows through it. Electrons in the semiconductor recombine with electron holes, releasing energy in the form of photons. The color of the light (corre ...
s (LEDs) emit light via electro-luminescence.
*
Phosphor
A phosphor is a substance that exhibits the phenomenon of luminescence; it emits light when exposed to some type of radiant energy. The term is used both for fluorescent or phosphorescent substances which glow on exposure to ultraviolet or ...
s, materials that emit light when irradiated by higher-energy
electromagnetic radiation
In physics, electromagnetic radiation (EMR) is a self-propagating wave of the electromagnetic field that carries momentum and radiant energy through space. It encompasses a broad spectrum, classified by frequency or its inverse, wavelength ...
or
particle radiation
Particle radiation is the radiation of energy by means of fast-moving subatomic particles. Particle radiation is referred to as a particle beam if the particles are all moving in the same direction, similar to a light beam.
Due to the wave–p ...
*
Laser
A laser is a device that emits light through a process of optical amplification based on the stimulated emission of electromagnetic radiation. The word ''laser'' originated as an acronym for light amplification by stimulated emission of radi ...
, and
lamp industry
*
Phosphor thermometry, measuring temperature using
phosphorescence
Phosphorescence is a type of photoluminescence related to fluorescence. When exposed to light (radiation) of a shorter wavelength, a phosphorescent substance will glow, absorbing the light and reemitting it at a longer wavelength. Unlike fluor ...
*
Thermoluminescence dating
Thermoluminescence dating (TL) is the determination, by means of measuring the accumulated radiation dose, of the time elapsed since material containing crystalline minerals was either heated (lava, ceramics) or exposed to sunlight (sediment ...
*
Thermoluminescent dosimeter
*
Non-disruptive observation of processes within a
cell.
Luminescence occurs in some
mineral
In geology and mineralogy, a mineral or mineral species is, broadly speaking, a solid substance with a fairly well-defined chemical composition and a specific crystal structure that occurs naturally in pure form.John P. Rafferty, ed. (2011): Mi ...
s when they are exposed to low-powered sources of
ultraviolet
Ultraviolet radiation, also known as simply UV, is electromagnetic radiation of wavelengths of 10–400 nanometers, shorter than that of visible light, but longer than X-rays. UV radiation is present in sunlight and constitutes about 10% of ...
or
infrared
Infrared (IR; sometimes called infrared light) is electromagnetic radiation (EMR) with wavelengths longer than that of visible light but shorter than microwaves. The infrared spectral band begins with the waves that are just longer than those ...
electromagnetic radiation
In physics, electromagnetic radiation (EMR) is a self-propagating wave of the electromagnetic field that carries momentum and radiant energy through space. It encompasses a broad spectrum, classified by frequency or its inverse, wavelength ...
(for example,
portable UV lamps) at
atmospheric pressure
Atmospheric pressure, also known as air pressure or barometric pressure (after the barometer), is the pressure within the atmosphere of Earth. The standard atmosphere (symbol: atm) is a unit of pressure defined as , which is equivalent to 1,013. ...
and atmospheric temperatures. This property of these minerals can be used during the process of mineral identification at rock
outcrop
An outcrop or rocky outcrop is a visible exposure of bedrock or ancient superficial deposits on the surface of the Earth and other terrestrial planets.
Features
Outcrops do not cover the majority of the Earth's land surface because in most p ...
s in the
field or in the laboratory.
History
The term ''luminescence'' was first introduced in 1888 by German physicist
Eilhard Wiedemann.
["Über Fluorescenz und Phosphorescenz, I. Abhandlung"]
(On fluorescence and phosphorescence, first paper), ''Annalen der Physik und Chemie'', 34: 446–463. From page 447: "Ich möchte für diese zweite Art der Lichterregung, für die uns eine einheitliche Benennung fehlt, den Namen Luminescenz vorschlagen, und Körper, die in dieser Weise leuchten, luminescirende nennen." or this second type of light excitation, for which we lack a consistent name, I would like to suggest the name of "luminescence", and call "luminescing" [anybodies that glow in this way.">ny">or this second type of light excitation, for which we lack a consistent name, I would like to suggest the name of "luminescence", and call "luminescing" [anybodies that glow in this way./ref>
See also
* List of light sources
* Scientific American,
Luminous Paint
(historical aspects), 10-Dec-1881, pp.368
* High-visibility clothing
High-visibility clothing, sometimes shortened to hi vis or hi viz, is any clothing worn that is highly luminescent in its natural matt property or a color that is easily discernible from any background. It is most commonly worn on the torso an ...
References
External links
Fluorophores.org A database of luminescent dyes
{{Authority control
Light sources
1880s neologisms