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Lithographic limestone is hard
limestone Limestone is a type of carbonate rock, carbonate sedimentary rock which is the main source of the material Lime (material), lime. It is composed mostly of the minerals calcite and aragonite, which are different Polymorphism (materials science) ...
that is sufficiently fine-grained, homogeneous and defect-free to be used for
lithography Lithography () is a planographic method of printing originally based on the miscibility, immiscibility of oil and water. The printing is from a stone (lithographic limestone) or a metal plate with a smooth surface. It was invented in 1796 by ...
.
Geologist A geologist is a scientist who studies the structure, composition, and History of Earth, history of Earth. Geologists incorporate techniques from physics, chemistry, biology, mathematics, and geography to perform research in the Field research, ...
s use the term "lithographic texture" to refer to a grain size under 1/250 mm. The term "sublithographic" is sometimes used for homogeneous fine-grained
limestone Limestone is a type of carbonate rock, carbonate sedimentary rock which is the main source of the material Lime (material), lime. It is composed mostly of the minerals calcite and aragonite, which are different Polymorphism (materials science) ...
with a somewhat coarser texture.


Origin

The generally accepted theory for the origin of lithographic and sublithographic limestones is that they were formed in shallow, stagnant, hypersaline, and anoxic lagoons. The combination of mild hypersalinity and low oxygen content is believed to have inhibited the formation of microbial mats and prevented the invasion of bottom dwelling organisms. Microbial mats and bottom dwelling organisms would have left fossils, and bottom dwelling organisms would have churned the accumulating sediment, producing a less homogeneous rock. Stagnancy was required to avoid churning or sculpting of the sediment by currents or wave action.Walter Etter, Solnhofen: Plattenkalk Preservation with Archaeopteryx, Chapter 18 o
Exceptional Fossil Preservation: A Unique View of the Evolution of Marine Life
Columbia University Press, 2002; pages 327–350.


Distribution


Europe

The original source for lithographic limestone was the Solnhofen Limestone, named after the quarries of Solnhofen where it was first found. This is a
late Jurassic The Late Jurassic is the third Epoch (geology), epoch of the Jurassic Period, and it spans the geologic time scale, geologic time from 161.5 ± 1.0 to 143.1 ± 0.8 million years ago (Ma), which is preserved in Upper Jurassic stratum, strata.Owen ...
deposit, part of a deposit of plattenkalk (a very fine-grained limestone that splits into thin plates, usually micrite) that extends through the Swabian Alb and Franconian Alb in Southern Germany. Only a small fraction of plattenkalk is suitable for lithography. For many years, the Solnhofen deposits were the only source of lithographic limestone. French lithographic limestone from quarries near Montdardier, about south of le Vigan, Gard was exhibited at the Great Exhibition of 1851, where it earned an honorable mention. This stone is from the upper Lias Group, from the
early Jurassic The Early Jurassic Epoch (geology), Epoch (in chronostratigraphy corresponding to the Lower Jurassic series (stratigraphy), Series) is the earliest of three epochs of the Jurassic Period. The Early Jurassic starts immediately after the Triassic� ...
. The largest lithographic printing stone ever quarried came from Le Vigan, 230 x 150cm (90 x 59 in). Théophile Steinlen used a comparable stone for some of his posters. Several quarries are visible today on the chalky plateau above Montdardier, between north (), and 2 km west () of the town. Shortly before 1867, a second lithographic limestone quarry was opened in France near Cerin and Crey,
Isère Isère ( , ; ; , ) is a landlocked Departments of France, department in the southeastern French Regions of France, region of Auvergne-Rhône-Alpes. Named after the river Isère (river), Isère, it had a population of 1,271,166 in 2019.
(). The lithographic limestones of Cerin are from the Kimmeridgian stage of the Upper Jurassic, and as with the Solnhofen deposits, they preserve numerous interesting
fossils A fossil (from Classical Latin , ) is any preserved remains, impression, or trace of any once-living thing from a past geological age. Examples include bones, shells, exoskeletons, stone imprints of animals or microbes, objects preserved ...
. Lithographic limestone from the Lower Cretaceous has been quarried near Santa Maria de Meià on the south flank of the Serra del Montsec in Spain. In 1902, L. M. Vidal, a mining engineer, recognized the importance of the fossils found there.


The Americas

The American Lithographic Stone Company was organized in
Louisville, Kentucky Louisville is the List of cities in Kentucky, most populous city in the Commonwealth of Kentucky, sixth-most populous city in the Southeastern United States, Southeast, and the list of United States cities by population, 27th-most-populous city ...
in late 1868. It initially focused its operation on quarries in
Overton County, Tennessee Overton County is a County (United States), county located in the U.S. state of Tennessee. As of the 2020 United States census, 2020 census, the population was 22,511. Its county seat is Livingston, Tennessee, Livingston. Overton County is part ...
, but shortly before 1900, it opened a quarry at Brandenburg, Kentucky. This quarry was the only commercial source of lithographic stone in the United States at the turn of the 20th century. Unlike the Solnhofen stone, Kentucky lithographic limestone was slightly dolomitic, and it was judged to be competitive with Solnhofen stone for some purposes, but not for the highest quality work. This stone source was sub-Carboniferous ( Mississippian). In 1917, the Brandenburg quarry was judged the most important source of lithographic stone in the United States. Prior to 1916, the output of the Brandenburg quarry was small, but in 1916, as
World War I World War I or the First World War (28 July 1914 – 11 November 1918), also known as the Great War, was a World war, global conflict between two coalitions: the Allies of World War I, Allies (or Entente) and the Central Powers. Fighting to ...
cut off access to Solnhofen stone, the quarry produced 20 tons of finished lithographic stone. The Remains of the Brandenburg Lithograph Quarry are located along the Buttermilk Falls Historic Walking Trail (). In 1903, Clement L. Webster discovered a bed of lithographic limestone about southwest of Orchard, Iowa. His company, the Interstate Investment & Development Company platted a town named Lithograph City nearby and opened a quarry (). The Lithograph City Formation of the Cedar Valley Group straddles the border between the Middle and Late
Devonian The Devonian ( ) is a period (geology), geologic period and system (stratigraphy), system of the Paleozoic era (geology), era during the Phanerozoic eon (geology), eon, spanning 60.3 million years from the end of the preceding Silurian per ...
and was named for its exposure in this quarry. Outcrops of this formation extend from near Cedar Falls, Iowa north into
Minnesota Minnesota ( ) is a U.S. state, state in the Upper Midwestern region of the United States. It is bordered by the Canadian provinces of Manitoba and Ontario to the north and east and by the U.S. states of Wisconsin to the east, Iowa to the so ...
. The suitability of Lithograph City limestone for lithography was tested by A. B. Hoen who reported that stone from two layers in the Lithograph City quarry was excellent for lithography and finer grained than the finest Solnhofen stone. Lithograph City was an important source of lithographic stone in the United States during World War I, but the quarries closed as metal printing plates replaced stone. In 1918, the Devonian Products Company took over the operation, focusing on the production of crushed rock and renaming the town Devonia. By 1938, the town had disappeared.Bill J. Bunker
Lithograph City
web page of th

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See-also

* Ichnofabric index * List of dinosaur-bearing rock formations * List of types of limestone


References

{{reflist Limestone industry
Limestone Limestone is a type of carbonate rock, carbonate sedimentary rock which is the main source of the material Lime (material), lime. It is composed mostly of the minerals calcite and aragonite, which are different Polymorphism (materials science) ...