Much insight in
quantum mechanics
Quantum mechanics is the fundamental physical Scientific theory, theory that describes the behavior of matter and of light; its unusual characteristics typically occur at and below the scale of atoms. Reprinted, Addison-Wesley, 1989, It is ...
can be gained from understanding the
closed-form solutions to the time-dependent non-relativistic
Schrödinger equation
The Schrödinger equation is a partial differential equation that governs the wave function of a non-relativistic quantum-mechanical system. Its discovery was a significant landmark in the development of quantum mechanics. It is named after E ...
. It takes the form
where
is the
wave function
In quantum physics, a wave function (or wavefunction) is a mathematical description of the quantum state of an isolated quantum system. The most common symbols for a wave function are the Greek letters and (lower-case and capital psi (letter) ...
of the system,
is the
Hamiltonian operator, and
is time.
Stationary states of this equation are found by solving the time-independent Schrödinger equation,
which is an eigenvalue equation. Very often, only numerical solutions to the Schrödinger equation can be found for a given physical system and its associated potential energy. However, there exists a subset of physical systems for which the form of the eigenfunctions and their associated energies, or eigenvalues, can be found. These quantum-mechanical systems with analytical solutions are listed below.
Solvable systems
*The
two-state quantum system (the simplest possible quantum system)
*The
free particle
*The one-dimensional potentials
**The
particle in a ring or
ring wave guide
**The delta potential
***The
single delta potential
***The
double-well delta potential
**The steps potentials
***The
particle in a box /
infinite potential well
***The
finite potential well
***The
step potential
***The
rectangular potential barrier
**The
triangular potential
**The quadratic potentials
***The
quantum harmonic oscillator
The quantum harmonic oscillator is the quantum-mechanical analog of the classical harmonic oscillator. Because an arbitrary smooth potential can usually be approximated as a harmonic potential at the vicinity of a stable equilibrium point, ...
***The quantum harmonic oscillator with an applied uniform field
**The
Inverse square root potential
**The periodic potential
***The
particle in a lattice
***The
particle in a lattice of finite length
**The
Pöschl–Teller potential
**The
quantum pendulum
*The three-dimensional potentials
**The rotating system
***The
linear rigid rotor
***The
symmetric top
**The
particle in a spherically symmetric potential
***The
hydrogen atom or
hydrogen-like atom e.g.
positronium
Positronium (Ps) is a system consisting of an electron and its antimatter, anti-particle, a positron, bound together into an exotic atom, specifically an onium. Unlike hydrogen, the system has no protons. The system is unstable: the two part ...
***The
hydrogen atom in a spherical cavity with
Dirichlet boundary conditions
*** The Mie potential
***The
Hooke's atom
***The
Morse potential
***The
Spherium atom
*Zero range interaction in a harmonic trap
* Multistate Landau–Zener models
*The
Luttinger liquid (the only exact quantum mechanical solution to a model including interparticle interactions)
Solutions
See also
*
List of quantum-mechanical potentials – a list of physically relevant potentials without regard to analytic solubility
*
List of integrable models
*
WKB approximation
*
Quasi-exactly-solvable problems
References
Reading materials
* {{cite book
, last = Mattis
, first = Daniel C.
, authorlink = Daniel C. Mattis
, title = The Many-Body Problem: An Encyclopedia of Exactly Solved Models in One Dimension
, publisher =
World Scientific
World Scientific Publishing is an academic publisher of scientific, technical, and medical books and journals headquartered in Singapore. The company was founded in 1981. It publishes about 600 books annually, with more than 170 journals in var ...
, date = 1993
, isbn = 978-981-02-0975-9
Quantum models
Quantum-mechanical systems with analytical solutions
Exactly solvable models