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Liming is the application of
calcium Calcium is a chemical element; it has symbol Ca and atomic number 20. As an alkaline earth metal, calcium is a reactive metal that forms a dark oxide-nitride layer when exposed to air. Its physical and chemical properties are most similar to it ...
- (Ca) and
magnesium Magnesium is a chemical element; it has Symbol (chemistry), symbol Mg and atomic number 12. It is a shiny gray metal having a low density, low melting point and high chemical reactivity. Like the other alkaline earth metals (group 2 ...
(Mg)-rich materials in various forms, including marl,
chalk Chalk is a soft, white, porous, sedimentary carbonate rock. It is a form of limestone composed of the mineral calcite and originally formed deep under the sea by the compression of microscopic plankton that had settled to the sea floor. Ch ...
,
limestone Limestone is a type of carbonate rock, carbonate sedimentary rock which is the main source of the material Lime (material), lime. It is composed mostly of the minerals calcite and aragonite, which are different Polymorphism (materials science) ...
, burnt lime or
hydrated lime Calcium hydroxide (traditionally called slaked lime) is an inorganic compound with the chemical formula calcium, Ca(Hydroxide, OH)2. It is a colorless crystal or white powder and is produced when quicklime (calcium oxide) is mixed with water. A ...
to
soil Soil, also commonly referred to as earth, is a mixture of organic matter, minerals, gases, water, and organisms that together support the life of plants and soil organisms. Some scientific definitions distinguish dirt from ''soil'' by re ...
. In acid soils, these materials react as a base and neutralize soil acidity. This often improves plant growth and increases the activity of soil
bacteria Bacteria (; : bacterium) are ubiquitous, mostly free-living organisms often consisting of one Cell (biology), biological cell. They constitute a large domain (biology), domain of Prokaryote, prokaryotic microorganisms. Typically a few micr ...
, but oversupply may result in harm to plant life. Modern liming was preceded by marling, a process of spreading raw chalk and lime debris across soil, in an attempt to modify pH or aggregate size. Evidence of these practices dates to the 1200's and the earliest examples are taken from the modern British Isles.


Impact on soil properties

Liming can also improve aggregate stability on clay soils. For this purpose structure lime, products containing calcium oxide (CaO) or hydroxide (Ca(OH)2) in mixes with calcium carbonate (CaCO3), are often used. Structure liming can reduce losses of clay and nutrients from soil aggregates. The degree to which a given amount of lime per unit of soil volume will increase soil pH depends on the buffer capacity of the soil (this is generally related to soil cation exchange capacity or CEC). Most acid soils are saturated with
aluminum Aluminium (or aluminum in North American English) is a chemical element; it has chemical symbol, symbol Al and atomic number 13. It has a density lower than that of other common metals, about one-third that of steel. Aluminium has ...
rather than hydrogen ions. Soil acidity generally results from
hydrolysis Hydrolysis (; ) is any chemical reaction in which a molecule of water breaks one or more chemical bonds. The term is used broadly for substitution reaction, substitution, elimination reaction, elimination, and solvation reactions in which water ...
of aluminum. This concept of "corrected lime potential" to define the degree of base saturation in soils became the basis for procedures now used in soil testing laboratories to determine the "lime requirement" of soils. Soils with low CEC will usually show a more marked pH increase than soils with high CEC. But the low-CEC soils will witness more rapid leaching of the added bases, and so will see a quicker return to original acidity unless additional liming is done. Over-liming is most likely to occur on soil that has low CEC, such as sand which is deficient in buffering agents such as organic matter and
clay Clay is a type of fine-grained natural soil material containing clay minerals (hydrous aluminium phyllosilicates, e.g. kaolinite, ). Most pure clay minerals are white or light-coloured, but natural clays show a variety of colours from impuriti ...
.


Effect on soil organic carbon

The net effect of soil liming on soil organic carbon is primarily the result of three processes. # Increased plant productivity resulting in larger organic matter inputs. As soil liming ameliorates soil conditions that inhibit plant growth, an increase in plant productivity is expected. The higher yields resulting from lime applications will produce increased returns of organic matter to the soil in the form of dying roots and decaying crop residue. # Increased organic matter mineralization due to a more favorable pH. Lime applications are known to have short-term stimulating effects on soil biological activity, thus favoring organic matter mineralization and very likely accelerating organic matter turnover rates in soil. # Amelioration of soil structure leading to a reduction of mineralization by means of protecting soil organic carbon. Liming is known to ameliorate soil structure, as high Ca2+ concentrations and high ionic strength in the soil solution enhance the flocculation of clay minerals and, in turn, form more stable soil aggregates. An agricultural study at the Faculty of Forestry in Freising, Germany, that compared tree stocks two and twenty years after liming found that liming promotes nitrate leaching and decreases the phosphorus content of some leaves.Huber C, Baier R, Gottlein A, Weis W. Changes in soil, seepage water and needle chemistry between 1984 and 2004 after liming an N-saturated Norway spruce stand at the Höglwald, Germany. Forest Ecology and Management, 2006; 233; 11-20.


See also

* Alkali soils * Soil conservation * Soil pH * Agricultural lime *
Aluminum Aluminium (or aluminum in North American English) is a chemical element; it has chemical symbol, symbol Al and atomic number 13. It has a density lower than that of other common metals, about one-third that of steel. Aluminium has ...


References


Further reading

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Further reading


"A Study of the Lime Potential, R.C. Turner, Research Branch, Department Of Agriculture, 1965"
{{Authority control Edaphology Soil chemistry Agricultural practices