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Whitewash, calcimine, kalsomine, calsomine, asbestis or lime paint is a type of
paint Paint is a material or mixture that, when applied to a solid material and allowed to dry, adds a film-like layer. As art, this is used to create an image or images known as a painting. Paint can be made in many colors and types. Most paints are ...
made from
slaked lime Calcium hydroxide (traditionally called slaked lime) is an inorganic compound with the chemical formula Ca( OH)2. It is a colorless crystal or white powder and is produced when quicklime ( calcium oxide) is mixed with water. Annually, approxim ...
(
calcium hydroxide Calcium hydroxide (traditionally called slaked lime) is an inorganic compound with the chemical formula Ca( OH)2. It is a colorless crystal or white powder and is produced when quicklime ( calcium oxide) is mixed with water. Annually, approxim ...
, Ca(OH)2) or
chalk Chalk is a soft, white, porous, sedimentary carbonate rock. It is a form of limestone composed of the mineral calcite and originally formed deep under the sea by the compression of microscopic plankton that had settled to the sea floor. Ch ...
(
calcium carbonate Calcium carbonate is a chemical compound with the chemical formula . It is a common substance found in Rock (geology), rocks as the minerals calcite and aragonite, most notably in chalk and limestone, eggshells, gastropod shells, shellfish skel ...
, CaCO3), sometimes known as "whiting". Various other additives are sometimes used.


Use as paint

Whitewash cures through a reaction with
carbon dioxide Carbon dioxide is a chemical compound with the chemical formula . It is made up of molecules that each have one carbon atom covalent bond, covalently double bonded to two oxygen atoms. It is found in a gas state at room temperature and at norma ...
in the atmosphere to form
calcium carbonate Calcium carbonate is a chemical compound with the chemical formula . It is a common substance found in Rock (geology), rocks as the minerals calcite and aragonite, most notably in chalk and limestone, eggshells, gastropod shells, shellfish skel ...
in the form of
calcite Calcite is a Carbonate minerals, carbonate mineral and the most stable Polymorphism (materials science), polymorph of calcium carbonate (CaCO3). It is a very common mineral, particularly as a component of limestone. Calcite defines hardness 3 on ...
, a type of reaction generally known as
carbonation Carbonation is the chemical reaction of carbon dioxide to give carbonates, bicarbonates, and carbonic acid. In chemistry, the term is sometimes used in place of carboxylation, which refers to the formation of carboxylic acids. In inorganic che ...
or by the more specific term,
carbonatation Carbonatation is a chemical reaction in which calcium hydroxide reacts with carbon dioxide and forms insoluble calcium carbonate: :Ca(OH)2CO2->CaCO3H_2O The process of forming a carbonate is sometimes referred to as "carbonation", although thi ...
. It is usually applied to exteriors, or interiors of rural
dairies A dairy is a place where milk is stored and where butter, cheese, and other dairy products are made, or a place where those products are sold. It may be a room, a building, or a larger establishment. In the United States, the word may also des ...
because of its mildly antibacterial properties. Whitewash can be tinted for decorative use and is sometimes painted inside structures such as the hallways of apartment buildings. A small amount can rub off onto
clothing Clothing (also known as clothes, garments, dress, apparel, or attire) is any item worn on a human human body, body. Typically, clothing is made of fabrics or textiles, but over time it has included garments made from animal skin and other thin s ...
. In Britain and Ireland, whitewash was used historically in interiors and exteriors of workers' cottages and still retains something of this association with
rural poverty Rural poverty refers to situations where people living in rural area, non-urban regions are in a poverty, state or condition of lacking the financial resources and essentials for living. It takes account of factors of Rural sociology, rural so ...
. In the United States, a similar attitude is expressed in the old saying "Too proud to whitewash and too poor to paint." The historic
California Missions The Spanish missions in California () formed a series of 21 religious outposts or missions established between 1769 and 1833 in what is now the U.S. state of California. The missions were established by Catholic priests of the Franciscan ord ...
were commonly whitewashed, giving them their distinctive bright white appearance. Whitewash is especially compatible with
masonry Masonry is the craft of building a structure with brick, stone, or similar material, including mortar plastering which are often laid in, bound, and pasted together by mortar (masonry), mortar. The term ''masonry'' can also refer to the buildin ...
because it is absorbed easily and the resultant chemical reaction hardens the medium. Lime wash is pure slaked lime in water. It produces a unique surface glow due to the
double refraction Birefringence, also called double refraction, is the optical property of a material having a refractive index that depends on the polarization and propagation direction of light. These optically anisotropic materials are described as birefring ...
of
calcite Calcite is a Carbonate minerals, carbonate mineral and the most stable Polymorphism (materials science), polymorph of calcium carbonate (CaCO3). It is a very common mineral, particularly as a component of limestone. Calcite defines hardness 3 on ...
crystals. Limewash and whitewash both cure to become the same material. When whitewash or limewash is initially applied, it has very low opacity, which can lead novices to overthicken the paint. Drying increases opacity and subsequent curing increases opacity even further. Limewash relies on being drawn into a substrate unlike a modern paint that adheres to the surface. The process of being drawn in needs to be controlled by damping down. If a wall is not damped, it can leave the lime and pigments on the surface powdery; if the wall is saturated, then there is no surface tension and this can result in failure of the limewash. Damping down is not difficult but it does need to be considered before application of the limewash.


Additives

Additives traditionally used include water glass,
glue Adhesive, also known as glue, cement, mucilage, or paste, is any non-metallic substance applied to one or both surfaces of two separate items that binds them together and resists their separation. The use of adhesives offers certain advantage ...
,
egg white Egg white is the clear liquid (also called the albumen or the glair/glaire) contained within an egg. In chickens, it is formed from the layers of secretions of the anterior section of the hen's oviduct during the passage of the egg. It forms a ...
,
Portland cement Portland cement is the most common type of cement in general use around the world as a basic ingredient of concrete, mortar (masonry), mortar, stucco, and non-specialty grout. It was developed from other types of hydraulic lime in England in th ...
,
salt In common usage, salt is a mineral composed primarily of sodium chloride (NaCl). When used in food, especially in granulated form, it is more formally called table salt. In the form of a natural crystalline mineral, salt is also known as r ...
,
soap Soap is a salt (chemistry), salt of a fatty acid (sometimes other carboxylic acids) used for cleaning and lubricating products as well as other applications. In a domestic setting, soaps, specifically "toilet soaps", are surfactants usually u ...
,
milk Milk is a white liquid food produced by the mammary glands of lactating mammals. It is the primary source of nutrition for young mammals (including breastfeeding, breastfed human infants) before they are able to digestion, digest solid food. ...
,
flour Flour is a powder made by Mill (grinding), grinding raw grains, List of root vegetables, roots, beans, Nut (fruit), nuts, or seeds. Flours are used to make many different foods. Cereal flour, particularly wheat flour, is the main ingredie ...
, molasses, alum, and
soil Soil, also commonly referred to as earth, is a mixture of organic matter, minerals, gases, water, and organisms that together support the life of plants and soil organisms. Some scientific definitions distinguish dirt from ''soil'' by re ...
. Whitewash is sometimes coloured with
earth Earth is the third planet from the Sun and the only astronomical object known to Planetary habitability, harbor life. This is enabled by Earth being an ocean world, the only one in the Solar System sustaining liquid surface water. Almost all ...
s to achieve colours spanning the range of broken white,
cream Cream is a dairy product composed of the higher-fat layer skimmed from the top of milk before homogenization. In un-homogenized milk, the fat, which is less dense, eventually rises to the top. In the industrial production of cream, this proces ...
,
yellow Yellow is the color between green and orange on the spectrum of light. It is evoked by light with a dominant wavelength of roughly 575585 nm. It is a primary color in subtractive color systems, used in painting or color printing. In t ...
and a range of
brown Brown is a color. It can be considered a composite color, but it is mainly a darker shade of orange. In the CMYK color model used in printing and painting, brown is usually made by combining the colors Orange (colour), orange and black. In the ...
s. The blue laundry dye (such as Reckitt's "Dolly Blue" in the UK, Ireland and Australia, Loulaki in Greece, or Mrs. Stewart's Bluing in North America), formerly widely used to give a bright tinge to boiled white textiles, was a common 19th century addition. Historically, pig's
blood Blood is a body fluid in the circulatory system of humans and other vertebrates that delivers necessary substances such as nutrients and oxygen to the cells, and transports metabolic waste products away from those same cells. Blood is com ...
was added to give the colour Suffolk pink, a colour still widely used on house exteriors in some areas of the UK. If animal blood is applied excessively, its iron oxide can compromise the lime binder's strength.
Pozzolan Pozzolans are a broad class of siliceous and aluminous materials which, in themselves, possess little or no cementitious value but which will, in finely divided form and in the presence of water, react chemically with calcium hydroxide (Ca(OH)2 ...
ic materials are occasionally added to give a much harder wearing paint finish. This addition creates a short open time and therefore requires timely application of the altered paint.
Linseed oil Linseed oil, also known as flaxseed oil or flax oil (in its edible form), is a colorless to yellowish oil obtained from the dried, ripened seeds of the flax plant (''Linum usitatissimum''). The oil is obtained by pressing, sometimes followed by ...
is sometimes added (typically 0.5-2%) to improve adhesion on difficult surfaces.
Cement A cement is a binder, a chemical substance used for construction that sets, hardens, and adheres to other materials to bind them together. Cement is seldom used on its own, but rather to bind sand and gravel ( aggregate) together. Cement mi ...
addition makes a harder wearing paint in
white White is the lightest color and is achromatic (having no chroma). It is the color of objects such as snow, chalk, and milk, and is the opposite of black. White objects fully (or almost fully) reflect and scatter all the visible wa ...
or
grey Grey (more frequent in British English) or gray (more frequent in American English) is an intermediate color between black and white. It is a neutral or achromatic color, meaning that it has no chroma. It is the color of a cloud-covered s ...
. Open time is short, so this is added at point of use. Cement restricts the breathable aspects of the limewash and is inadvisable for preserved historic buildings. Dilute
glue Adhesive, also known as glue, cement, mucilage, or paste, is any non-metallic substance applied to one or both surfaces of two separate items that binds them together and resists their separation. The use of adhesives offers certain advantage ...
s improve paint toughness.
Wheat flour Wheat flour is a powder made from the grinding of common wheat used for human consumption. Wheat varieties are called "soft" or "weak" if gluten content is low, and are called "hard" or "strong" if they have high gluten content. Hard flour, or ...
has been used as a strength enhancing binder.
Salt In common usage, salt is a mineral composed primarily of sodium chloride (NaCl). When used in food, especially in granulated form, it is more formally called table salt. In the form of a natural crystalline mineral, salt is also known as r ...
is often added to prevent
mold A mold () or mould () is one of the structures that certain fungus, fungi can form. The dust-like, colored appearance of molds is due to the formation of Spore#Fungi, spores containing Secondary metabolite#Fungal secondary metabolites, fungal ...
.


Limitations

Basic limewash can be inadequate in its ability to prevent rain-driven water ingress. Additives are being developed but these have the potential for affecting free vapor permeability. For this reason silicate paints, more common in Germany, are gaining popularity in the UK over limewash.


Applications


Orchards

Whitewash is applied to trees, especially fruit trees, to prevent sun scald. Most often only the lower trunk is painted. In Poland painting the whole trunk is also said to help keep the body of the tree cool in late winter and early spring months and hence help prevent fruit trees from blooming too soon, i.e. when warm sunny days could promote rapid tree warming, rising sap and bloom and intermittent frosty nights could damage outer tree rings and destroy the young buds and blossoms.


Dairy barns

In the middle of the 20th century, when
family farm A family farm is generally understood to be a farm owned and/or operated by a family. It is sometimes considered to be an Estate (land), estate passed down by inheritance. Although a recurring conceptual model, conceptual and archetype, archet ...
s with
dairy A dairy is a place where milk is stored and where butter, cheese, and other dairy products are made, or a place where those products are sold. It may be a room, a building, or a larger establishment. In the United States, the word may also des ...
barns were common in the
Upper Midwest The Upper Midwest is a northern subregion of the U.S. Census Bureau's Midwestern United States. Although the exact boundaries are not uniformly agreed upon, the region is usually defined to include the states of Iowa, Michigan, Minnesota and Wi ...
of the
United States The United States of America (USA), also known as the United States (U.S.) or America, is a country primarily located in North America. It is a federal republic of 50 U.S. state, states and a federal capital district, Washington, D.C. The 48 ...
, whitewash was a necessary part of routine barn
maintenance The technical meaning of maintenance involves functional checks, servicing, repairing or replacing of necessary devices, equipment, machinery, building infrastructure and supporting utilities in industrial, business, and residential installa ...
. A traditional animal barn contains a variety of extremely rough surfaces that are difficult to wash and keep clean, such as stone and brick masonry, and also rough-cut lumber for the ceiling. If left alone, these surfaces collect dust, dirt, insect debris and wastes, and can become very dirty. Whitewash aids in sanitation by coating and smoothing over the rough surfaces. Successive applications of whitewash build up layers of scale that flake off and, in the process, remove surface debris. The coating also has antimicrobial properties that provide hygienic and sanitary benefits for animal
barn A barn is an agricultural building usually on farms and used for various purposes. In North America, a barn refers to structures that house livestock, including cattle and horses, as well as equipment and fodder, and often grain.Allen G ...
s.


Other uses

Whitewash was painted on the internal walls of
Royal Navy The Royal Navy (RN) is the naval warfare force of the United Kingdom. It is a component of His Majesty's Naval Service, and its officers hold their commissions from the King of the United Kingdom, King. Although warships were used by Kingdom ...
vessels during the
Age of Sail The Age of Sail is a period in European history that lasted at the latest from the mid-16th (or mid-15th) to the mid-19th centuries, in which the dominance of sailing ships in global trade and warfare culminated, particularly marked by the int ...
to improve light levels inside a vessel's
gundeck The term gun deck used to refer to a deck aboard a ship that was primarily used for the mounting of cannon to be fired in broadsides. The term is generally applied to decks enclosed under a roof; smaller and unrated vessels carried their guns ...
, reduce bacteria and prevent wear and tear on hull timbers. It was also used during the
Second World War World War II or the Second World War (1 September 1939 – 2 September 1945) was a World war, global conflict between two coalitions: the Allies of World War II, Allies and the Axis powers. World War II by country, Nearly all of the wo ...
by the German armed forces as an easy-to-apply winter
camouflage Camouflage is the use of any combination of materials, coloration, or illumination for concealment, either by making animals or objects hard to see, or by disguising them as something else. Examples include the leopard's spotted coat, the b ...
for soft- and hard-skinned vehicles, aircraft and helmets.


In popular culture

The incident of
Tom Sawyer Thomas "Tom" Sawyer () is the title character of the Mark Twain novel '' The Adventures of Tom Sawyer'' (1876). He appears in three other novels by Twain: '' Adventures of Huckleberry Finn'' (1884), '' Tom Sawyer Abroad'' (1894), and '' Tom Sawy ...
whitewashing a fence as punishment is a famous image in American literature. It appears in ''
The Adventures of Tom Sawyer ''The Adventures of Tom Sawyer'' (also simply known as ''Tom Sawyer'') is a novel by Mark Twain published on June 9, 1876, about a boy, Tom Sawyer, growing up along the Mississippi River. It is set in the 1830s-1840s in the town of St. Petersbu ...
'' written in 1876 by
Mark Twain Samuel Langhorne Clemens (November 30, 1835 – April 21, 1910), known by the pen name Mark Twain, was an American writer, humorist, and essayist. He was praised as the "greatest humorist the United States has produced," with William Fau ...
. In the 1934 film, ''
Fugitive Lovers ''Fugitive Lovers'' is a 1934 American pre-Code comedy drama film directed by Richard Boleslavsky. Released by Metro-Goldwyn-Mayer, it stars Madge Evans and Robert Montgomery with a supporting cast of Nat Pendleton, C. Henry Gordon, Ruth ...
'', Madge Evans drops a bottle of cosmetics that she calls her "Calcimine". Metaphorically,
whitewashing Whitewash is a paint-like covering of hydrated lime or a cheap white paint. Whitewash or whitewashing may also refer to: Racist practices * Whitewashing (beauty), modifying the skin tones of photographs of nonwhite people in mass media * Whitew ...
refers to suppression or "glossing over" (possibly a close parallel construction) of potentially damaging or unwelcome information. In many Commonwealth areas, a
whitewash Whitewash, calcimine, kalsomine, calsomine, asbestis or lime paint is a type of paint made from slaked lime ( calcium hydroxide, Ca(OH)2) or chalk (calcium carbonate, CaCO3), sometimes known as "whiting". Various other additives are sometimes ...
refers to a game in which one side fails to score at all; the usage is especially found in
cricket Cricket is a Bat-and-ball games, bat-and-ball game played between two Sports team, teams of eleven players on a cricket field, field, at the centre of which is a cricket pitch, pitch with a wicket at each end, each comprising two Bail (cr ...
.“Whitewash”
Merriam-Webster.com Dictionary, Merriam-Webster. Accessed 21 Mar. 2020.


See also

*
Lime plaster Lime plaster is a type of plaster composed of sand, water, and lime, usually non-hydraulic hydrated lime (also known as slaked lime, high calcium lime or air lime). Ancient lime plaster often contained horse hair for reinforcement and pozzolan ...
*
Lime mortar Lime mortar or torching is a masonry mortar (masonry), mortar composed of lime (material), lime and an construction aggregate, aggregate such as sand, mixed with water. It is one of the oldest known types of mortar, used in ancient Rome and anci ...
* Silicate paint


References


External links

*
Lighthouse keeper A lighthouse keeper or lightkeeper is a person responsible for tending and caring for a lighthouse, particularly the light and lens in the days when oil lamps and clockwork mechanisms were used. Lighthouse keepers were sometimes referred to as ...
'
formula for White Wash
at Crisp Point Light.
Paper on Whitewashing including mixes etc by Peter Mold & Richard Godbey

Application guide on Limewishing by Cornish Lime
{{Authority control Coatings Painting materials