Legrandite is a rare
zinc
Zinc is a chemical element with the symbol Zn and atomic number 30. Zinc is a slightly brittle metal at room temperature and has a shiny-greyish appearance when oxidation is removed. It is the first element in group 12 (IIB) of the periodic t ...
arsenate mineral
Arsenate minerals usually refer to the naturally occurring orthoarsenates, possessing the (AsO4)3− anion group and, more rarely, other arsenates with anions like AsO3(OH)2− (also written HAsO42−) (example: pharmacolite Ca(AsO3OH).2H2O) or ( ...
, Zn
2(AsO
4)(OH)·(H
2O).
It is an uncommon secondary mineral in the
oxidized
Redox (reduction–oxidation, , ) is a type of chemical reaction in which the oxidation states of substrate change. Oxidation is the loss of electrons or an increase in the oxidation state, while reduction is the gain of electrons or a de ...
zone of arsenic bearing zinc deposits and occurs rarely in
granite
Granite () is a coarse-grained ( phaneritic) intrusive igneous rock composed mostly of quartz, alkali feldspar, and plagioclase. It forms from magma with a high content of silica and alkali metal oxides that slowly cools and solidifies und ...
pegmatite
A pegmatite is an igneous rock showing a very coarse texture, with large interlocking crystals usually greater in size than and sometimes greater than . Most pegmatites are composed of quartz, feldspar, and mica, having a similar silicic co ...
. Associated minerals include:
adamite
Adamite is a zinc arsenate hydroxide mineral, Zn2 As O4O H. It is a mineral that typically occurs in the oxidized or weathered zone above zinc ore occurrences. Pure adamite is colorless, but usually it possess yellow color due to Fe compoun ...
,
paradamite,
köttigite,
scorodite
Scorodite is a common hydrated iron arsenate mineral, with the chemical formula FeAsO4·2H2O. It is found in hydrothermal deposits and as a secondary mineral in gossans worldwide. Scorodite weathers to limonite.
Scorodite was discovered in the S ...
,
smithsonite
Smithsonite, also known as zinc spar, is the mineral form of zinc carbonate ( Zn CO3). Historically, smithsonite was identified with hemimorphite before it was realized that they were two different minerals. The two minerals are very similar in a ...
,
leiteite,
renierite
Renierite is a rare copper zinc germanium bearing sulfide mineral with the chemical formula . It occurs at the Kipushi Mine, Democratic Republic of the Congo; and Namibia
Namibia (, ), officially the Republic of Namibia, is a country in S ...
,
pharmacosiderite,
aurichalcite
Aurichalcite is a carbonate mineral, usually found as a secondary mineral in copper and zinc deposits. Its chemical formula is . The zinc to copper ratio is about 5:4.
Occurrence
Aurichalcite typically occurs in the oxidized zone of copper and ...
,
siderite
Siderite is a mineral composed of iron(II) carbonate (FeCO3). It takes its name from the Greek word σίδηρος ''sideros,'' "iron". It is a valuable iron mineral, since it is 48% iron and contains no sulfur or phosphorus. Zinc, magnesium an ...
,
goethite
Goethite (, ) is a mineral of the diaspore group, consisting of iron(III) oxide-hydroxide, specifically the "α" polymorph. It is found in soil and other low-temperature environments such as sediment. Goethite has been well known since ancient ...
and
pyrite
The mineral pyrite (), or iron pyrite, also known as fool's gold, is an iron sulfide with the chemical formula Fe S2 (iron (II) disulfide). Pyrite is the most abundant sulfide mineral.
Pyrite's metallic luster and pale brass-yellow hue giv ...
.
[ It has been reported from ]Tsumeb
, nickname =
, settlement_type = City
, motto = ''Glück Auf'' (German for ''Good luck'')
, image_skyline = Welcome to tsumeb.jpg
, imagesize =
, image_caption =
, image_flag ...
, Namibia
Namibia (, ), officially the Republic of Namibia, is a country in Southern Africa. Its western border is the Atlantic Ocean. It shares land borders with Zambia and Angola to the north, Botswana to the east and South Africa to the south and e ...
; the Ojuela
Ojuela was a small mining town, settlement located northwest of the nearest town Mapimí, Durango, Mapimí, northwest. The settlement is now well known as a ghost town as a result of the ore being exhausted.
Ojuela was established after the di ...
mine in Durango
Durango (), officially named Estado Libre y Soberano de Durango ( en, Free and Sovereign State of Durango; Tepehuán: ''Korian''; Nahuatl: ''Tepēhuahcān''), is one of the 31 states which make up the 32 Federal Entities of Mexico, situated i ...
, Mexico and at Sterling Hill, New Jersey
New Jersey is a U.S. state, state in the Mid-Atlantic States, Mid-Atlantic and Northeastern United States, Northeastern regions of the United States. It is bordered on the north and east by the state of New York (state), New York; on the ea ...
, US.[
It was first described in 1934 for an occurrence in the Flor de Peña Mine, ]Nuevo León
Nuevo León () is a state in the northeast region of Mexico. The state was named after the New Kingdom of León, an administrative territory from the Viceroyalty of New Spain, itself was named after the historic Spanish Kingdom of León. With ...
, Mexico and named after M. Legrand, a Belgian mining engineer .[
]
References
Zinc minerals
Arsenate minerals
Monoclinic minerals
Minerals in space group 14
Minerals described in 1934
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