Langer Correction
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The Langer correction, named after the mathematician Rudolf Ernest Langer, is a correction to the
WKB approximation In mathematical physics, the WKB approximation or WKB method is a technique for finding approximate solutions to Linear differential equation, linear differential equations with spatially varying coefficients. It is typically used for a Semiclass ...
for problems with radial symmetry.


Description


In 3D systems

When applying WKB approximation method to the radial
Schrödinger equation The Schrödinger equation is a partial differential equation that governs the wave function of a non-relativistic quantum-mechanical system. Its discovery was a significant landmark in the development of quantum mechanics. It is named after E ...
, -\frac \frac + -V_\textrm(r)R(r) = 0 , where the
effective potential The effective potential (also known as effective potential energy) combines multiple, perhaps opposing, effects into a single potential. In its basic form, it is the sum of the "opposing" centrifugal potential energy with the potential energy of a ...
is given by V_\textrm(r) = V(r) - \frac ( \ell the
azimuthal quantum number In quantum mechanics, the azimuthal quantum number is a quantum number for an atomic orbital that determines its angular momentum operator, orbital angular momentum and describes aspects of the angular shape of the orbital. The azimuthal quantum ...
related to the
angular momentum operator In quantum mechanics, the angular momentum operator is one of several related operators analogous to classical angular momentum. The angular momentum operator plays a central role in the theory of atomic and molecular physics and other quantum pro ...
), the eigenenergies and the wave function behaviour obtained are different from the real solution. In 1937, Rudolf E. Langer suggested a correction \ell(\ell+1) \rightarrow \left(\ell+\frac\right)^2 which is known as Langer correction or Langer replacement. This manipulation is equivalent to inserting a 1/4 constant factor whenever \ell(\ell+1) appears. Heuristically, it is said that this factor arises because the range of the radial Schrödinger equation is restricted from 0 to infinity, as opposed to the entire real line. By such a changing of constant term in the effective potential, the results obtained by WKB approximation reproduces the exact spectrum for many potentials. That the Langer replacement is correct follows from the WKB calculation of the Coulomb eigenvalues with the replacement which reproduces the well known result.


In 2D systems

Note that for 2D systems, as the effective potential takes the form V_\textrm(r) = V(r) - \frac, so Langer correction goes: \left(\ell^2-\frac\right) \rightarrow \ell^2. This manipulation is also equivalent to insert a 1/4 constant factor whenever \ell^2 appears.


Justification

An even more convincing calculation is the derivation of
Regge trajectories In quantum physics, Regge theory ( , ) is the study of the analytic properties of scattering as a function of angular momentum, where the angular momentum is not restricted to be an integer multiple of '' ħ'' but is allowed to take any complex val ...
(and hence eigenvalues) of the radial Schrödinger equation with
Yukawa potential Yukawa (written: 湯川) is a Japanese surname, but is also applied to proper nouns. People * Diana Yukawa (born 1985), Anglo-Japanese solo violinist. She has had two solo albums with BMG Japan, one of which opened to #1 * Hideki Yukawa (1907–1 ...
by both a perturbation method (with the old \ell(\ell+1) factor) and independently the derivation by the WKB method (with Langer replacement)-- in both cases even to higher orders. For the perturbation calculation see Müller-Kirsten book and for the WKB calculation Boukema.


See also

*
Einstein–Brillouin–Keller method The Einstein–Brillouin–Keller (EBK) method is a semiclassical technique (named after Albert Einstein, Léon Brillouin, and Joseph B. Keller) used to compute eigenvalues in quantum-mechanical systems. EBK quantization is an improvement from ...


References

{{DEFAULTSORT:Langer Correction Theoretical physics