Lamprophyllite
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Lamprophyllite (named for its lustrous cleavage) is a rare, but widespread mineral Ti-silicate mineral usually found in intrusive agpasitic
igneous Igneous rock ( ), or magmatic rock, is one of the three main rock types, the others being sedimentary and metamorphic. Igneous rocks are formed through the cooling and solidification of magma or lava. The magma can be derived from partial ...
rocks. Yellow, reddish brown, Vitreous, Pearly. Lamprophyllite formula is (Sr,Ba,K,Na)2Na(Na,Fe,Mn)2Ti[Ti2O2(Si2O7)2[(O, OH,F)2 . Full isomorphic range between lampropyllite and baritollalpropyllite exist. The general crystal-chemical formula for lampropyllite-related minerals can be written as A2[(M1)(M2)2(M3)X2] 5] L2(Si2O7)2O2], where the contents of the O and H sheets are given in square brackets in this order and A = Sr, Ba,K, Na; M1 = Na, Mn2+; M2 = Na, Mn2+, Fe2+, Ca; M3 = Ti, Mn2+, Mg, Fe3+, Fe2+; L = Ti, Fe3+; X = OH, O, F. Lamprophyllite is
monoclinic In crystallography, the monoclinic crystal system is one of the seven crystal systems. A crystal system is described by three Vector (geometric), vectors. In the monoclinic system, the crystal is described by vectors of unequal lengths, as in t ...
, The mineral also has an
orthorhombic In crystallography, the orthorhombic crystal system is one of the 7 crystal systems. Orthorhombic Lattice (group), lattices result from stretching a cubic crystal system, cubic lattice along two of its orthogonal pairs by two different factors, res ...
polytype In crystallography, polymorphism is the phenomenon where a compound or element can crystallize into more than one crystal structure. The preceding definition has evolved over many years and is still under discussion today. Discussion of the defi ...
Unit-cell parameters mainly depend from the cationic composition in the interlayer position A The crystal structures of the lamprophyllite-related minerals are based upon HOH modules consisting of a central octahedral O sheet sandwiched between two heteropolyhedral H sheets. Lamprophyllite melts incongruently (880 °C) with formation of titanium oxides: rutile, tausonite, freudenbergite. Syntetic lamprophyllite synthesis was crystallized from melt. Tewly formed lamprophyllite show higher Sr/Ba ratioi than in equilibrium melt.


References

Silicate minerals {{Silicate-mineral-stub