Khomyakovite is an exceedingly rare mineral of the eudialyte group, with formula .Mindat, Khomyakovite, http://www.mindat.org/min-7137.htmlJohnsen, O., Gault, R.A., Grice, J.D., and Ercit, T.S., 1999: Khomyakovite and manganokhomyakovite, two new members of the eudialyte group from Mont Saint-Hilaire, Quebec, Canada. The Canadian Mineralogist 37, 893–899 The original formula was extended to show the presence of both the cyclic silicate groups and M4-site silicon, according to the nomenclature of the eudialyte group.Johnsen, O., Ferraris, G., Gault, R.A., Grice, D.G., Kampf, A.R., and Pekov, I.V., 2003. The nomenclature of eudialyte-group minerals. The Canadian Mineralogist 41, 785–794 Some niobium substitutes for tungsten in khomyakovite. Khomyakovite is an iron-analogue of manganokhomyakovite, the second mineral being a bit more common. The two minerals are the only group representatives, beside taseqite, with species-defining

strontium Strontium is a chemical element; it has symbol Sr and atomic number 38. An alkaline earth metal, it is a soft silver-white yellowish metallic element that is highly chemically reactive. The metal forms a dark oxide layer when it is exposed to ...

, although many other members display strontium diadochy. Khomyakovite is the third eudialyte-group mineral with essential

tungsten Tungsten (also called wolfram) is a chemical element; it has symbol W and atomic number 74. It is a metal found naturally on Earth almost exclusively in compounds with other elements. It was identified as a distinct element in 1781 and first ...

(after johnsenite-(Ce) and manganokhomyakovite).

Occurrence and association

Khomyakovite, manganokhomyakovite, johnsenite-(Ce) and oneillite are four eudialyte-group minerals with type locality in

Mont Saint-Hilaire Mont Saint-Hilaire (; English: Mount Saint-Hilaire; ;, ; see for other names) is a mountain, high, in the Montérégie region of southern Quebec. It is about thirty kilometres east of Montreal, and immediately east of the Richelieu River. It ...

, Quebec, Canada. Khomyakovite itself is associated with analcime, annite, natrolite,

titanite Titanite, or sphene (), is a calcium titanium nesosilicate mineral, Ca Ti Si O5. Trace impurities of iron and aluminium are typically present. Also commonly present are rare earth metals including cerium and yttrium; calcium may be partly rep ...

, calcite, and

pyrite The mineral pyrite ( ), or iron pyrite, also known as fool's gold, is an iron sulfide with the chemical formula Fe S2 (iron (II) disulfide). Pyrite is the most abundant sulfide mineral. Pyrite's metallic luster and pale brass-yellow hue ...

Notes on chemistry

Impurities in khomyakovite include

niobium Niobium is a chemical element; it has chemical symbol, symbol Nb (formerly columbium, Cb) and atomic number 41. It is a light grey, crystalline, and Ductility, ductile transition metal. Pure niobium has a Mohs scale of mineral hardness, Mohs h ...

potassium Potassium is a chemical element; it has Symbol (chemistry), symbol K (from Neo-Latin ) and atomic number19. It is a silvery white metal that is soft enough to easily cut with a knife. Potassium metal reacts rapidly with atmospheric oxygen to ...

and

manganese Manganese is a chemical element; it has Symbol (chemistry), symbol Mn and atomic number 25. It is a hard, brittle, silvery metal, often found in minerals in combination with iron. Manganese was first isolated in the 1770s. It is a transition m ...

, with minor

rare earth elements The rare-earth elements (REE), also called the rare-earth metals or rare earths, and sometimes the lanthanides or lanthanoids (although scandium and yttrium, which do not belong to this series, are usually included as rare earths), are a set of ...

magnesium Magnesium is a chemical element; it has Symbol (chemistry), symbol Mg and atomic number 12. It is a shiny gray metal having a low density, low melting point and high chemical reactivity. Like the other alkaline earth metals (group 2 ...

titanium Titanium is a chemical element; it has symbol Ti and atomic number 22. Found in nature only as an oxide, it can be reduced to produce a lustrous transition metal with a silver color, low density, and high strength, resistant to corrosion in ...

hafnium Hafnium is a chemical element; it has symbol Hf and atomic number 72. A lustrous, silvery gray, tetravalent transition metal, hafnium chemically resembles zirconium and is found in many zirconium minerals. Its existence was predicted by Dm ...

and

aluminium Aluminium (or aluminum in North American English) is a chemical element; it has chemical symbol, symbol Al and atomic number 13. It has a density lower than that of other common metals, about one-third that of steel. Aluminium has ...

References

Cyclosilicates Sodium minerals Strontium minerals Calcium minerals Iron minerals Zirconium minerals Tungsten minerals Trigonal minerals Minerals in space group 160 {{silicate-mineral-stub