Dr. Joseph Cecil Patrick (August 28, 1892 – April 12, 1965) invented
Thiokol
Thiokol (variously Thiokol Chemical Corporation(/Company), Morton Thiokol Inc., Cordant Technologies Inc., Thiokol Propulsion, AIC Group, ATK Thiokol, ATK Launch Systems Group; finally Orbital ATK before becoming part of Northrop Grumman) was a ...
, America's first
synthetic rubber
A synthetic rubber is an artificial elastomer. They are polymers synthesized from petroleum byproducts. About 32-million metric tons of rubbers are produced annually in the United States, and of that amount two thirds are synthetic. Synthetic rubbe ...
in the early 1920s. While seeking a formulation for automotive antifreeze, he attempted to
hydrolyze
Hydrolysis (; ) is any chemical reaction in which a molecule of water breaks one or more chemical bonds. The term is used broadly for substitution, elimination, and solvation reactions in which water is the nucleophile.
Biological hydrolysis ...
ethylene dichloride
The chemical compound 1,2-dichloroethane, commonly known as ethylene dichloride (EDC), is a chlorinated hydrocarbon. It is a colourless liquid with a chloroform-like odour. The most common use of 1,2-dichloroethane is in the production of vinyl ...
with
sodium polysulfide
Sodium polysulfide is a general term for salts with the formula Na2 Sx, where ''x'' = 2 to 5. The species Sx2−, called polysulfide anions, include disulfide (S22−), trisulfide (S32−), tetrasulfide (S42−), and pentasulfide (S52−). In pr ...
. In doing so, he produced a brown, insoluble gum that later became known as
Thiokol
Thiokol (variously Thiokol Chemical Corporation(/Company), Morton Thiokol Inc., Cordant Technologies Inc., Thiokol Propulsion, AIC Group, ATK Thiokol, ATK Launch Systems Group; finally Orbital ATK before becoming part of Northrop Grumman) was a ...
.
He solved commercial production problems by inventing the
suspension polymerization
Suspension polymerization is a heterogeneous radical polymerization process that uses mechanical agitation to mix a monomer or mixture of monomers in a liquid phase, such as water, while the monomers polymerize, forming spheres of polymer. The m ...
process, and solved compounding problems by degrading high molecular weight polymer to a low molecular weight liquid polymer. This material is one of the principal binders for
rocket propellant
Rocket propellant is the reaction mass of a rocket. This reaction mass is ejected at the highest achievable velocity from a rocket engine to produce thrust. The energy required can either come from the propellants themselves, as with a chemical ...
.
Patrick was the 1958 recipient of the
Charles Goodyear Medal
The Charles Goodyear Medal is the highest honor conferred by the American Chemical Society, Rubber Division. Established in 1941, the award is named after Charles Goodyear, the discoverer of vulcanization, and consists of a gold medal, a framed c ...
.
References
Polymer scientists and engineers
1892 births
1965 deaths
20th-century American chemists
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