Josef Mattauch
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Josef Mattauch (21 November 1895 – 10 August 1976) was a nuclear physicist and chemist. He was known for the development of the Mattauch-Herzog double-focusing mass spectrometer, for his work on the investigation of isotopic abundances using
mass spectrometry Mass spectrometry (MS) is an analytical technique that is used to measure the mass-to-charge ratio of ions. The results are presented as a ''mass spectrum'', a plot of intensity as a function of the mass-to-charge ratio. Mass spectrometry is used ...
, and the determination of atomic weights. Much of his career was spent at the
Kaiser Wilhelm Institute for Chemistry The Kaiser Wilhelm Society for the Advancement of Science () was a German scientific institution established in the German Empire in 1911. Its functions were taken over by the Max Planck Society. The Kaiser Wilhelm Society was an umbrella organi ...
(later the
Max Planck Institute The Max Planck Society for the Advancement of Science (; abbreviated MPG) is a formally independent non-governmental and non-profit association of German research institutes. Founded in 1911 as the Kaiser Wilhelm Society, it was renamed to the M ...
). He developed the Mattauch isobar rule ("Isobarenregel") in 1934. He correctly predicted that the last of the
rare earth elements The rare-earth elements (REE), also called the rare-earth metals or rare earths, and sometimes the lanthanides or lanthanoids (although scandium and yttrium, which do not belong to this series, are usually included as rare earths), are a set of ...
, element 61 (later named
promethium Promethium is a chemical element; it has Symbol (chemistry), symbol Pm and atomic number 61. All of its isotopes are Radioactive decay, radioactive; it is extremely rare, with only about 500–600 grams naturally occurring in the Earth's crust a ...
), would not have stable isotopes.


Early life

Josef Heinrich Elisabeth Mattauch was born 21 November 1895 in Ostrau,
Moravia Moravia ( ; ) is a historical region in the eastern Czech Republic, roughly encompassing its territory within the Danube River's drainage basin. It is one of three historical Czech lands, with Bohemia and Czech Silesia. The medieval and early ...
. Mattauch was educated at the
University of Vienna The University of Vienna (, ) is a public university, public research university in Vienna, Austria. Founded by Rudolf IV, Duke of Austria, Duke Rudolph IV in 1365, it is the oldest university in the German-speaking world and among the largest ...
, where he worked with
Felix Ehrenhaft Felix Ehrenhaft (24 April 1879 – 4 March 1952) was an Austrian physicist who contributed to atomic physics, to the measurement of electrical charges and to the optical properties of metal colloids. He was known for his maverick and controversial ...
. Ehrenhaft believed he had discovered a "sub-electron", smaller than anything measured by
Robert Andrews Millikan Robert Andrews Millikan ( ; March 22, 1868 – December 19, 1953) was an American physicist who received the Nobel Prize in Physics in 1923 "for his work on the elementary charge of electricity and on the photoelectric effect". Millikan gradua ...
. Mattauch's results, however, were in agreement with Millikan and not Ehrenhaft. Mattauch completed his PhD degree in Vienna as of 1920. Through the help of another professor, Mattauch spent 1927–1928 on a
Rockefeller Fellowship The Rockefeller Foundation is an American private foundation and philanthropic medical research and arts funding organization based at 420 Fifth Avenue, New York City. The foundation was created by Standard Oil magnate John D. Rockefeller ("Seni ...
at
Caltech The California Institute of Technology (branded as Caltech) is a private university, private research university in Pasadena, California, United States. The university is responsible for many modern scientific advancements and is among a small g ...
. There he worked with William Smythe on the development of early mass spectrometers.


Career

Mattauch returned to Vienna in 1928 as an unpaid lecturer. There he worked with student Richard F. K. Herzog to develop the Mattauch-Herzog double-focusing mass spectrometer. The first of a new type, it was announced in 1934. His work significantly improved the sharpness and sensitivity of mass spectroscopes. The double-focusing mechanism allowed for the separation and measurement of
isotopes Isotopes are distinct nuclear species (or ''nuclides'') of the same chemical element. They have the same atomic number (number of protons in their nuclei) and position in the periodic table (and hence belong to the same chemical element), but ...
that could not be isolated by chemical means, and as such was a major contribution to
nuclear physics Nuclear physics is the field of physics that studies atomic nuclei and their constituents and interactions, in addition to the study of other forms of nuclear matter. Nuclear physics should not be confused with atomic physics, which studies th ...
. Mattauch became an associate professor at the University of Vienna in 1937. In 1938 Lise Meitner fled Germany after the Nazi occupation of Austria changed her citizenship from Austrian to German, making her subject to the
antisemitic Antisemitism or Jew-hatred is hostility to, prejudice towards, or discrimination against Jews. A person who harbours it is called an antisemite. Whether antisemitism is considered a form of racism depends on the school of thought. Antisemi ...
Nuremberg Laws The Nuremberg Laws (, ) were antisemitic and racist laws that were enacted in Nazi Germany on 15 September 1935, at a special meeting of the Reichstag convened during the annual Nuremberg Rally of the Nazi Party. The two laws were the Law ...
of 1935. Otto Hahn invited Mattauch to join the Institute. In 1939, Mattauch succeeded
Lise Meitner Elise Lise Meitner ( ; ; 7 November 1878 – 27 October 1968) was an Austrian-Swedish nuclear physicist who was instrumental in the discovery of nuclear fission. After completing her doctoral research in 1906, Meitner became the second woman ...
as head of the department for mass spectroscopy, within the physics department at
Kaiser Wilhelm Institute for Chemistry The Kaiser Wilhelm Society for the Advancement of Science () was a German scientific institution established in the German Empire in 1911. Its functions were taken over by the Max Planck Society. The Kaiser Wilhelm Society was an umbrella organi ...
(KWI). A new Mattauch-Herzog mass spectrograph was installed. On 31 July 1941, Mattauch succeeded
Lise Meitner Elise Lise Meitner ( ; ; 7 November 1878 – 27 October 1968) was an Austrian-Swedish nuclear physicist who was instrumental in the discovery of nuclear fission. After completing her doctoral research in 1906, Meitner became the second woman ...
as head of the physics department. Josef Mattauch was appointed an associate professor of nuclear chemistry at the
University of Berlin The Humboldt University of Berlin (, abbreviated HU Berlin) is a public research university in the central borough of Mitte in Berlin, Germany. The university was established by Frederick William III on the initiative of Wilhelm von Humbol ...
in 1940. Hahn and Mattauch successfully sought funds for a major expansion for fundamental research in atomic physics. In 1942, the Minerva Project was approved, involving construction of a new building and addition of a cascade generator and
particle accelerator A particle accelerator is a machine that uses electromagnetic fields to propel electric charge, charged particles to very high speeds and energies to contain them in well-defined particle beam, beams. Small accelerators are used for fundamental ...
. On 1 November 1943 Mattauch advanced to the position of deputy director of the Institute. On 15 February 1944 and again on 24 March 1944, as part of the
Bombing of Berlin in World War II Berlin, the capital of Germany, was subject to 363 air raids during the Second World War. It was bombed by the RAF Bomber Command between 1940 and 1945, the United States Army Air Forces' Eighth Air Force between 1943 and 1945, and the French ...
, the Institute suffered severe bombing damage. This included the director's house, one wing of the Institute, Mattauch's new mass spectrograph, and valuable research papers. The Institute was temporarily relocated to Tailfingen (now part of
Albstadt Albstadt () is the largest city in the district of Zollernalbkreis in Baden-Württemberg, Germany. It is located on the Swabian Jura mountains, about halfway between Stuttgart and Lake Constance. Geography Albstadt is spread across a variety of ...
) in the
Württemberg Württemberg ( ; ) is a historical German territory roughly corresponding to the cultural and linguistic region of Swabia. The main town of the region is Stuttgart. Together with Baden and Province of Hohenzollern, Hohenzollern, two other histo ...
district, in a textile factory belonging to the Ludwig Haasis company. On 1 April 1946, in
Göttingen Göttingen (, ; ; ) is a college town, university city in Lower Saxony, central Germany, the Capital (political), capital of Göttingen (district), the eponymous district. The River Leine runs through it. According to the 2022 German census, t ...
in the
British zone of occupation The British occupation zone in Germany (German: ''Britische Besatzungszone Deutschlands'') was one of the Allied-occupied areas in Germany after World War II. The United Kingdom, along with the Commonwealth, was one of the three major Allied po ...
,
Otto Hahn Otto Hahn (; 8 March 1879 – 28 July 1968) was a German chemist who was a pioneer in the field of radiochemistry. He is referred to as the father of nuclear chemistry and discoverer of nuclear fission, the science behind nuclear reactors and ...
became president of the
Kaiser Wilhelm Society The Kaiser Wilhelm Society for the Advancement of Science () was a German scientific institution established in the German Empire in 1911. Its functions were taken over by the Max Planck Society. The Kaiser Wilhelm Society was an umbrella organi ...
(Kaiser-Wilhelm-Gesellschaft, KWG). As of 1 October 1946, Hahn resigned as director of the Kaiser Wilhelm Institute of Chemistry, leaving Mattauch to manage the Institute. Mattauch officially became director on 31 July 1947. However, Mattauch suffered from
tuberculosis Tuberculosis (TB), also known colloquially as the "white death", or historically as consumption, is a contagious disease usually caused by ''Mycobacterium tuberculosis'' (MTB) bacteria. Tuberculosis generally affects the lungs, but it can al ...
and spent much of his time seeking treatment, traveling and working abroad. In 1948, Mattauch was a guest professor at the
University of Berne The University of Bern (, , ) is a public research university in the Swiss capital of Bern. It was founded in 1834. It is regulated and financed by the canton of Bern. It is a comprehensive university offering a broad choice of courses and progra ...
,
Switzerland Switzerland, officially the Swiss Confederation, is a landlocked country located in west-central Europe. It is bordered by Italy to the south, France to the west, Germany to the north, and Austria and Liechtenstein to the east. Switzerland ...
. In his absence, Strassman became acting director. Mattauch and
Fritz Strassmann Friedrich Wilhelm Strassmann (; 22 February 1902 – 22 April 1980) was a German chemist who, with Otto Hahn in December 1938, identified the element barium as a product of the bombardment of uranium with neutrons. Their observation was the key ...
actively supported the proposed appointment of
Lise Meitner Elise Lise Meitner ( ; ; 7 November 1878 – 27 October 1968) was an Austrian-Swedish nuclear physicist who was instrumental in the discovery of nuclear fission. After completing her doctoral research in 1906, Meitner became the second woman ...
as head of the physics department of the
University of Mainz The Johannes Gutenberg University Mainz () is a public research university in Mainz, Rhineland Palatinate, Germany. It has been named after the printer Johannes Gutenberg since 1946. it had approximately 32,000 students enrolled in around 100 a ...
. Hahn and Strassman asked Meitner to return as director, but she declined their offer. As of 1949, the Kaiser-Wilhelm-Gesellschaft was renamed the Max-Planck-Gesellschaft (MPG). Also in 1949, the renamed
Max Planck Institute for Chemistry The Max Planck Institute for Chemistry (Otto Hahn Institute; ) is a non-university research institute under the auspices of the Max Planck Society (German: Max-Planck-Gesellschaft) in Mainz, Germany. It was created as the Kaiser Wilhelm Instit ...
moved from Tailfingen to
Mainz Mainz (; #Names and etymology, see below) is the capital and largest city of the German state of Rhineland-Palatinate, and with around 223,000 inhabitants, it is List of cities in Germany by population, Germany's 35th-largest city. It lies in ...
,
Germany Germany, officially the Federal Republic of Germany, is a country in Central Europe. It lies between the Baltic Sea and the North Sea to the north and the Alps to the south. Its sixteen States of Germany, constituent states have a total popu ...
. At this time it consisted of two departments: Mass Spectrometry and Nuclear Physics was Mattauch's department, while Nuclear Chemistry was Strassmann's department. Given Mattauch's continued absence, Strassman formally replaced Mattauch as director, becoming the second director of the Max Planck Institute for Chemistry on 28 April 1950. However, restructuring of the Institute by the Senate of the MPG occurred in 1952, changing its research focus. Strassman resigned on 31 March 1953, and moved to the
University of Mainz The Johannes Gutenberg University Mainz () is a public research university in Mainz, Rhineland Palatinate, Germany. It has been named after the printer Johannes Gutenberg since 1946. it had approximately 32,000 students enrolled in around 100 a ...
. Mattauch again became the director of the Max Planck Institute for Chemistry. The Institute officially opened new facilities in Mainz in 1956. In 1957, Mattauch was one of the Göttinger Achtzehn (Göttingen eighteen), a group of eighteen leading nuclear researchers of the
Federal Republic of Germany Germany, officially the Federal Republic of Germany, is a country in Central Europe. It lies between the Baltic Sea and the North Sea to the north and the Alps to the south. Its sixteen constituent states have a total population of over 84 ...
who wrote a
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( Göttinger Manifest, Göttinger Erklärung) opposing
chancellor Chancellor () is a title of various official positions in the governments of many countries. The original chancellors were the of Roman courts of justice—ushers, who sat at the (lattice work screens) of a basilica (court hall), which separa ...
Konrad Adenauer Konrad Hermann Joseph Adenauer (5 January 1876 – 19 April 1967) was a German statesman and politician who served as the first Chancellor of Germany, chancellor of West Germany from 1949 to 1963. From 1946 to 1966, he was the first leader of th ...
and defense secretary Franz-Josef Strauß's move to arm the West German army with
tactical nuclear weapon A tactical nuclear weapon (TNW) or non-strategic nuclear weapon (NSNW) is a nuclear weapon that is designed to be used on a battlefield in military situations, mostly with friendly forces in proximity and perhaps even on contested friendly territ ...
s. Mattauch retired in 1965. Christian Junge (1912-1996) succeeded Josef Mattauch as director of the Institute on October 1, 1968. Josef Heinrich Elisabeth Mattauch died 10 August 1976 in
Klosterneuburg Klosterneuburg () is a town in the Tulln District of the Austrian state of Lower Austria. Frequently abbreviated to Kloburg by locals, it has a population of about 27,500. The Stift Klosterneuburg ( Klosterneuburg Monastery), which was establish ...
,
Austria Austria, formally the Republic of Austria, is a landlocked country in Central Europe, lying in the Eastern Alps. It is a federation of nine Federal states of Austria, states, of which the capital Vienna is the List of largest cities in Aust ...
.


Research

Mattauch primarily focused on mass spectroscopy and research into the binding energy of atomic nuclei. In the early 1930s, at the University of Vienna, Mattauch worked with Richard F. K. Herzog on fundamental aspects of ion optics as they applied to mass spectroscopy. They developed the Mattauch-Herzog double-focusing mass spectrometer. The
sector mass spectrometer A sector instrument is a general term for a class of mass spectrometer that uses a static electric (E) or magnetic (B) sector or some combination of the two (separately in space) as a mass analyzer. Popular combinations of these sectors have been ...
that they presented in 1934 became known throughout the scientific world as the “Mattauch-Herzog-System”. The Mattauch–Herzog geometry consists of a \pi / 4\sqrt radian electric sector, a drift length which is followed by a
right angle In geometry and trigonometry, a right angle is an angle of exactly 90 Degree (angle), degrees or radians corresponding to a quarter turn (geometry), turn. If a Line (mathematics)#Ray, ray is placed so that its endpoint is on a line and the ad ...
(\pi / 2) magnetic sector of opposite curvature direction. The entry of the ions sorted primarily by charge into the magnetic field produces an energy focussing effect and much higher transmission than a standard energy filter. The advantage of this geometry is that the ions of different masses are all focused onto the same flat plane, which allows the use of a photographic plate or other flat detector array. He developed the Mattauch isobar rule ("Isobarenregel") in 1934, which was used to predict the radioactivity of the elements
technetium Technetium is a chemical element; it has Symbol (chemistry), symbol Tc and atomic number 43. It is the lightest element whose isotopes are all radioactive. Technetium and promethium are the only radioactive elements whose neighbours in the sense ...
and
promethium Promethium is a chemical element; it has Symbol (chemistry), symbol Pm and atomic number 61. All of its isotopes are Radioactive decay, radioactive; it is extremely rare, with only about 500–600 grams naturally occurring in the Earth's crust a ...
. According to the rule, "if two adjacent elements on the periodic table have isotopes with the same mass number (isobars), one of the isotopes must be radioactive." Although the rule does not, in fact, hold for all elements, Mattauch was able to correctly predict that the last of the rare earth elements, element 61 (later named promethium), would not have stable isotopes. This led researchers to the realization that element 61 was likely to be extremely rare, and was not likely to be found naturally. In the 1950s, a period of stability after the war, Mattauch was able to build a strong mass spectrometry program at the Max Planck Institute. Using mass spectrometry he and other researchers were able to determine precise measurements of isotope masses, work that had started in Berlin. Measuring nuclear masses, they were able to precisely determine the nuclear masses of neutrons, protons and chlorine. They also focused on the
noble gases The noble gases (historically the inert gases, sometimes referred to as aerogens) are the members of group 18 of the periodic table: helium (He), neon (Ne), argon (Ar), krypton (Kr), xenon (Xe), radon (Rn) and, in some cases, oganesson (Og) ...
, measuring tiny amounts of noble gases from meteorites.


Decorations and awards

* 1957,
Wilhelm Exner Medal The Wilhelm Exner Medal has been awarded by the Austrian Industry Association, (ÖGV), for excellence in research and science since 1921. The medal is dedicated to Wilhelm Exner (1840–1931), former president of the Association, who initialize ...
* 1964,
Austrian Decoration for Science and Art The Austrian Decoration for Science and Art () is a state decoration of the Republic of Austria and forms part of the Orders, decorations, and medals of Austria, Austrian national honours system. History The "Austrian Decoration for Science a ...
(Österreichisches Ehrenzeichen für Wissenschaft und Kunst) * 1965, Honorary doctorate from the
Vienna University of Technology TU Wien () is a public research university in Vienna, Austria. The university's teaching and research are focused on engineering, computer science, and natural sciences. It currently has about 28,100 students (29% women), eight faculties, and ...


References


Further reading

* {{DEFAULTSORT:Mattauch, Josef 1895 births 1976 deaths 20th-century German physicists Mass spectrometrists Max Planck Society people People from Ostrava Recipients of the Austrian Decoration for Science and Art Rare earth scientists Max Planck Institute directors