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James Muspratt (12 August 1793 – 4 May 1886) was a British chemical manufacturer who was the first to make
alkali In chemistry, an alkali (; from ar, القلوي, al-qaly, lit=ashes of the saltwort) is a basic, ionic salt of an alkali metal or an alkaline earth metal. An alkali can also be defined as a base that dissolves in water. A solution of a ...
by the
Leblanc process The Leblanc process (pronounced leh-blaank) was an early industrial process for making ''soda ash'' (sodium carbonate) used throughout the 19th century, named after its inventor, Nicolas Leblanc. It involved two stages: making sodium sulfate from ...
on a large scale in the United Kingdom.


Early life

James Muspratt was born in Dublin of English parents, the youngest of three children. At the age of fourteen he was apprenticed to a wholesale druggist, but his father died in 1810 and his mother soon afterwards.Trevor I. Williams, (2004
‘Muspratt, James (1793–1886)’
'' Oxford Dictionary of National Biography'', Oxford University Press Retrieved on 9 March 2007
He left Dublin and in 1812 he went to Spain to take part in the Peninsular War. He followed the British army on foot into the interior, was laid up with fever at Madrid, and, narrowly escaping capture by the French, succeeded in making his way to
Lisbon Lisbon (; pt, Lisboa ) is the capital and largest city of Portugal, with an estimated population of 544,851 within its administrative limits in an area of 100.05 km2. Grande Lisboa, Lisbon's urban area extends beyond the city's administr ...
where he joined the navy. After taking part in the blockade of Brest he deserted because of the harshness of the discipline.


Industry

Returning to Dublin in about 1814, he came into an inheritance and in 1818 established a chemical works in partnership with Thomas Abbott. Here he began to manufacture chemical products such as hydrochloric and
acetic Acetic acid , systematically named ethanoic acid , is an acidic, colourless liquid and organic compound with the chemical formula (also written as , , or ). Vinegar is at least 4% acetic acid by volume, making acetic acid the main component ...
acids and turpentine, adding
prussiate of potash Potassium ferrocyanide is the inorganic compound with formula K4 e(CN)6�3H2O. It is the potassium salt of the complex (chemistry), coordination complex e(CN)6−. This salt forms lemon-yellow monoclinic crystals. Synthesis In 1752, th ...
a few years later.
Sodium carbonate Sodium carbonate, , (also known as washing soda, soda ash and soda crystals) is the inorganic compound with the formula Na2CO3 and its various hydrates. All forms are white, odourless, water-soluble salts that yield moderately alkaline solutions ...
, also known as soda ash, is an effective industrial
alkali In chemistry, an alkali (; from ar, القلوي, al-qaly, lit=ashes of the saltwort) is a basic, ionic salt of an alkali metal or an alkaline earth metal. An alkali can also be defined as a base that dissolves in water. A solution of a ...
. The manufacture of sodium carbonate from
common salt Salt is a mineral composed primarily of sodium chloride (NaCl), a chemical compound belonging to the larger class of Salt (chemistry), salts; salt in the form of a natural crystallinity, crystalline mineral is known as rock salt or halite. ...
was first developed in France in the 1790s and known as the
Leblanc process The Leblanc process (pronounced leh-blaank) was an early industrial process for making ''soda ash'' (sodium carbonate) used throughout the 19th century, named after its inventor, Nicolas Leblanc. It involved two stages: making sodium sulfate from ...
. Muspratt was attracted towards manufacturing it, but could not raise the capital for the relatively expensive Leblanc plant and also considered that Dublin was not a suitable location for this. He perceived Merseyside as better because of the neighbouring coal fields, the proximity to the salt district of Cheshire, and the proximity to glassmaking industry. The glassmakers were the main prospective customer base for the
sodium carbonate Sodium carbonate, , (also known as washing soda, soda ash and soda crystals) is the inorganic compound with the formula Na2CO3 and its various hydrates. All forms are white, odourless, water-soluble salts that yield moderately alkaline solutions ...
alkali. In 1822 he went to Liverpool and took a lease of an abandoned glass-works on the bank of the Leeds and Liverpool Canal. Though already determined to work the Leblanc process, he did not immediately possess the capital for it, and he therefore continued the production of prussiate of potash, which was profitable, and plough the profits into building the lead chambers and the other necessaries of a complete Leblanc works. Fortuitously in 1823 the duty or tax of £30 per ton was taken off salt. He began to make sodium carbonate alkali by the Leblanc process in 1823. In 1828 he built works at St Helens, (then in Lancashire), in partnership with Josias Gamble, another Irish-born chemist. But after two years the partnership ended and Muspratt moved to
Newton-le-Willows Newton-le-Willows is a market town in the Metropolitan Borough of St Helens, Merseyside, England. The population at the 2011 census was 22,114. Newton-le-Willows is on the eastern edge of St Helens, south of Wigan and north of Warrington. The ...
, (then in Lancashire). This factory closed in 1851. He was repeatedly involved in
litigation - A lawsuit is a proceeding by a party or parties against another in the civil court of law. The archaic term "suit in law" is found in only a small number of laws still in effect today. The term "lawsuit" is used in reference to a civil actio ...
because of the pollution caused. In 1828 he was cited as causing a public nuisance and fined one 
shilling The shilling is a historical coin, and the name of a unit of modern currencies formerly used in the United Kingdom, Australia, New Zealand, other British Commonwealth countries and Ireland, where they were generally equivalent to 12 pence o ...
. In 1831 he was indicted but was acquitted on this occasion. In 1838 after a trial lasting three days, with 40 witnesses for the prosecution and 46 for the defence, a jury found Muspratt guilty of "creating and maintaining a nuisance". At this time he was employing 120 on the Vauxhall Road site which had two chimneys, one of which was 50 yards high.


Retirement

In 1851 Muspratt largely withdrew from the business although he supported his sons, Richard and Frederic in starting new alkali works at Wood End, Widnes and Flint. After his retirement in 1857 his business was continued by his four sons. However, in 1867 he took over the management of Frederic's factory at Wood End before passing it on to another son,
Edmund Edmund is a masculine given name or surname in the English language. The name is derived from the Old English elements ''ēad'', meaning "prosperity" or "riches", and ''mund'', meaning "protector". Persons named Edmund include: People Kings and ...
. In the 1830s he had experimented in producing sodium carbonate alkali by the
ammonia-soda process The Solvay process or ammonia-soda process is the major industrial process for the production of sodium carbonate (soda ash, Na2CO3). The ammonia-soda process was developed into its modern form by the Belgian chemist Ernest Solvay during the 1860s. ...
but was unsuccessful. In 1834–1835, in conjunction with Charles Tennant, he purchased
sulphur Sulfur (or sulphur in British English) is a chemical element with the symbol S and atomic number 16. It is abundant, multivalent and nonmetallic. Under normal conditions, sulfur atoms form cyclic octatomic molecules with a chemical formula ...
mines in Sicily, to provide the raw material for the
sulphuric acid Sulfuric acid (American spelling and the preferred IUPAC name) or sulphuric acid ( Commonwealth spelling), known in antiquity as oil of vitriol, is a mineral acid composed of the elements sulfur, oxygen and hydrogen, with the molecular formu ...
needed for the Leblanc process. However, when the
Neapolitan Neapolitan means of or pertaining to Naples, a city in Italy; or to: Geography and history * Province of Naples, a province in the Campania region of southern Italy that includes the city * Duchy of Naples, in existence during the Early and Hig ...
government imposed a prohibitive duty on sulphur, Muspratt found a substitute in iron pyrites which was introduced as the raw material for the manufacture of
sulphuric acid Sulfuric acid (American spelling and the preferred IUPAC name) or sulphuric acid ( Commonwealth spelling), known in antiquity as oil of vitriol, is a mineral acid composed of the elements sulfur, oxygen and hydrogen, with the molecular formu ...
. Muspratt had been one of the original subscribers to the
St Helens and Runcorn Gap Railway St Helens and Runcorn Gap Railway was an early railway line owned by a company of the same name in Lancashire, England, which opened in 1833. It was later known as St Helens Railway. It ran originally from the town of St Helens to the area whi ...
in 1833 when he purchased 15 shares at £100 each. In 1819 he married Julia Josephine Connor with whom he had 10 children, three of whom died in infancy. He built a house, Seaforth Hall on
dune A dune is a landform composed of wind- or water-driven sand. It typically takes the form of a mound, ridge, or hill. An area with dunes is called a dune system or a dune complex. A large dune complex is called a dune field, while broad, f ...
s at Seaforth.Hardie, p.22. In 1825 he helped to found the Liverpool Institute for Boys and in 1848 he assisted his son James Sheridan to establish the Liverpool College of Practical Chemistry. He died at Seaforth Hall in 1886 and was buried in
Walton, Merseyside Walton is an area of Liverpool, England, north of Anfield and east of Bootle and Orrell Park. Historically in Lancashire, it is largely residential, with a diverse population. History The name may derive from the same origin as Wales. The inco ...
, parish churchyard.


References


Notes


Bibliography

*Hardie, D. W. F. (1950) ''A History of the Chemical Industry of Widnes'',
Imperial Chemical Industries Imperial Chemical Industries (ICI) was a British chemical company. It was, for much of its history, the largest manufacturer in Britain. It was formed by the merger of four leading British chemical companies in 1926. Its headquarters were at M ...
. * *


Further reading

* {{DEFAULTSORT:Muspratt, James 1793 births 1886 deaths British chemists Businesspeople from Dublin (city) Businesspeople from Liverpool James 19th-century British businesspeople