Uranium
Uranium is a chemical element; it has chemical symbol, symbol U and atomic number 92. It is a silvery-grey metal in the actinide series of the periodic table. A uranium atom has 92 protons and 92 electrons, of which 6 are valence electrons. Ura ...
(U) is a naturally occurring
radioactive
Radioactive decay (also known as nuclear decay, radioactivity, radioactive disintegration, or nuclear disintegration) is the process by which an unstable atomic nucleus loses energy by radiation. A material containing unstable nuclei is conside ...
element (radioelement) with no
stable isotope
Stable nuclides are Isotope, isotopes of a chemical element whose Nucleon, nucleons are in a configuration that does not permit them the surplus energy required to produce a radioactive emission. The Atomic nucleus, nuclei of such isotopes are no ...
s. It has two
primordial isotopes,
uranium-238
Uranium-238 ( or U-238) is the most common isotope of uranium found in nature, with a relative abundance of 99%. Unlike uranium-235, it is non-fissile, which means it cannot sustain a chain reaction in a thermal-neutron reactor. However, it i ...
and
uranium-235
Uranium-235 ( or U-235) is an isotope of uranium making up about 0.72% of natural uranium. Unlike the predominant isotope uranium-238, it is fissile, i.e., it can sustain a nuclear chain reaction. It is the only fissile isotope that exists in nat ...
, that have long
half-lives and are found in appreciable quantity in
Earth's crust
Earth's crust is its thick outer shell of rock, referring to less than one percent of the planet's radius and volume. It is the top component of the lithosphere, a solidified division of Earth's layers that includes the crust and the upper ...
. The
decay product
In nuclear physics, a decay product (also known as a daughter product, daughter isotope, radio-daughter, or daughter nuclide) is the remaining nuclide left over from radioactive decay. Radioactive decay often proceeds via a sequence of steps ( d ...
uranium-234 is also found. Other isotopes such as
uranium-233
Uranium-233 ( or U-233) is a fissile isotope of uranium that is bred from thorium-232 as part of the thorium fuel cycle. Uranium-233 was investigated for use in nuclear weapons and as a Nuclear fuel, reactor fuel. It has been used successfully ...
have been produced in
breeder reactors. In addition to isotopes found in nature or nuclear reactors, many isotopes with far shorter half-lives have been produced, ranging from U to U (except for U). The
standard atomic weight of
natural uranium is .
Natural uranium consists of three main
isotope
Isotopes are distinct nuclear species (or ''nuclides'') of the same chemical element. They have the same atomic number (number of protons in their Atomic nucleus, nuclei) and position in the periodic table (and hence belong to the same chemica ...
s, U (99.2739–99.2752%
natural abundance), U (0.7198–0.7202%), and U (0.0050–0.0059%). All three isotopes are
radioactive
Radioactive decay (also known as nuclear decay, radioactivity, radioactive disintegration, or nuclear disintegration) is the process by which an unstable atomic nucleus loses energy by radiation. A material containing unstable nuclei is conside ...
(i.e., they are
radioisotope
A radionuclide (radioactive nuclide, radioisotope or radioactive isotope) is a nuclide that has excess numbers of either neutrons or protons, giving it excess nuclear energy, and making it unstable. This excess energy can be used in one of three ...
s), and the most abundant and stable is uranium-238, with a half-life of (about the
age of the Earth
The age of Earth is estimated to be 4.54 ± 0.05 billion years. This age may represent the age of Earth's accretion (astrophysics), accretion, or Internal structure of Earth, core formation, or of the material from which Earth formed. This dating ...
).
Uranium-238 is an
alpha emitter, decaying through the 18-member
uranium series
In nuclear science a decay chain refers to the predictable series of radioactive disintegrations undergone by the nuclei of certain unstable chemical elements.
Radioactive isotopes do not usually decay directly to stable isotopes, but rather ...
into
lead-206. The
decay series of uranium-235 (historically called actino-uranium) has 15 members and ends in lead-207. The constant rates of decay in these series makes comparison of the ratios of parent-to-daughter elements useful in
radiometric dating
Radiometric dating, radioactive dating or radioisotope dating is a technique which is used to Chronological dating, date materials such as Rock (geology), rocks or carbon, in which trace radioactive impurity, impurities were selectively incorporat ...
. Uranium-233 is made from
thorium-232
Thorium-232 () is the main naturally occurring isotope of thorium, with a relative abundance of 99.98%. It has a half life of 14.05 billion years, which makes it the longest-lived isotope of thorium. It decays by alpha decay to radium-228; its de ...
by
neutron
The neutron is a subatomic particle, symbol or , that has no electric charge, and a mass slightly greater than that of a proton. The Discovery of the neutron, neutron was discovered by James Chadwick in 1932, leading to the discovery of nucle ...
bombardment.
Uranium-235 is important for both
nuclear reactor
A nuclear reactor is a device used to initiate and control a Nuclear fission, fission nuclear chain reaction. They are used for Nuclear power, commercial electricity, nuclear marine propulsion, marine propulsion, Weapons-grade plutonium, weapons ...
s (energy production) and
nuclear weapon
A nuclear weapon is an explosive device that derives its destructive force from nuclear reactions, either fission (fission or atomic bomb) or a combination of fission and fusion reactions (thermonuclear weapon), producing a nuclear exp ...
s because it is the only isotope existing in nature to any appreciable extent that is
fissile
In nuclear engineering, fissile material is material that can undergo nuclear fission when struck by a neutron of low energy. A self-sustaining thermal Nuclear chain reaction#Fission chain reaction, chain reaction can only be achieved with fissil ...
in response to
thermal neutron
The neutron detection temperature, also called the neutron energy, indicates a free neutron's kinetic energy, usually given in electron volts. The term ''temperature'' is used, since hot, thermal and cold neutrons are moderated in a medium wit ...
s, i.e., thermal
neutron capture
Neutron capture is a nuclear reaction in which an atomic nucleus and one or more neutrons collide and merge to form a heavier nucleus. Since neutrons have no electric charge, they can enter a nucleus more easily than positively charged protons, wh ...
has a high probability of inducing fission. A
chain reaction
A chain reaction is a sequence of reactions where a reactive product or by-product causes additional reactions to take place. In a chain reaction, positive feedback leads to a self-amplifying chain of events.
Chain reactions are one way that sys ...
can be sustained with a large enough (
critical) mass of uranium-235. Uranium-238 is also important because it is
fertile: it absorbs neutrons to produce a radioactive isotope that decays into
plutonium-239
Plutonium-239 ( or Pu-239) is an isotope of plutonium. Plutonium-239 is the primary fissile isotope used for the production of nuclear weapons, although uranium-235 is also used for that purpose. Plutonium-239 is also one of the three main iso ...
, which also is fissile.
List of isotopes
, -
, U
,
, style="text-align:right" , 92
, style="text-align:right" , 122
,
,
,
α
, Th
, 0+
,
,
, -id=Uranium-215
, rowspan=2, U
, rowspan=2,
, rowspan=2 style="text-align:right" , 92
, rowspan=2 style="text-align:right" , 123
, rowspan=2, 215.026720(11)
, rowspan=2, 1.4(9) ms
, α
, Th
, rowspan=2, 5/2−#
, rowspan=2,
, rowspan=2,
, -
,
β?
, Pa
, -id=Uranium-216
, U
,
, style="text-align:right" , 92
, style="text-align:right" , 124
, 216.024760(30)
,
, α
, Th
, 0+
,
,
, -id=Uranium-216m
, style="text-indent:1em" , U
,
, colspan="3" style="text-indent:2em" , 2206 keV
,
, α
, Th
, 8+
,
,
, -id=Uranium-217
, rowspan=2, U
, rowspan=2,
, rowspan=2 style="text-align:right" , 92
, rowspan=2 style="text-align:right" , 125
, rowspan=2, 217.024660(86)#
, rowspan=2,
, α
, Th
, rowspan=2, (1/2−)
, rowspan=2,
, rowspan=2,
, -
, β?
, Pa
, -id=Uranium-218
, U
,
, style="text-align:right" , 92
, style="text-align:right" , 126
, 218.023505(15)
,
, α
, Th
, 0+
,
,
, -id=Uranium-218m
, rowspan=2 style="text-indent:1em" , U
, rowspan=2,
, rowspan=2 colspan="3" style="text-indent:2em" , 2117 keV
, rowspan=2,
, α
, Th
, rowspan=2, 8+
, rowspan=2,
, rowspan=2,
, -
, IT?
, U
, -id=Uranium-219
, rowspan=2, U
, rowspan=2,
, rowspan=2 style="text-align:right" , 92
, rowspan=2 style="text-align:right" , 127
, rowspan=2, 219.025009(14)
, rowspan=2, 60(7) μs
, α
, Th
, rowspan=2, (9/2+)
, rowspan=2,
, rowspan=2,
, -
, β?
, Pa
, -id=Uranium-221
, rowspan=2, U
, rowspan=2,
, rowspan=2 style="text-align:right" , 92
, rowspan=2 style="text-align:right" , 129
, rowspan=2, 221.026323(77)
, rowspan=2, 0.66(14) μs
, α
, Th
, rowspan=2, (9/2+)
, rowspan=2,
, rowspan=2,
, -
, β?
, Pa
, -id=Uranium-222
, rowspan=2, U
, rowspan=2,
, rowspan=2 style="text-align:right" , 92
, rowspan=2 style="text-align:right" , 130
, rowspan=2, 222.026058(56)
, rowspan=2, 4.7(7) μs
, α
, Th
, rowspan=2, 0+
, rowspan=2,
, rowspan=2,
, -
, β?
, Pa
, -id=Uranium-223
, rowspan=2, U
, rowspan=2,
, rowspan=2 style="text-align:right" , 92
, rowspan=2 style="text-align:right" , 131
, rowspan=2, 223.027961(63)
, rowspan=2, 65(12) μs
, α
, Th
, rowspan=2, 7/2+#
, rowspan=2,
, rowspan=2,
, -
, β?
, Pa
, -id=Uranium-224
, rowspan=2, U
, rowspan=2,
, rowspan=2 style="text-align:right" , 92
, rowspan=2 style="text-align:right" , 132
, rowspan=2, 224.027636(16)
, rowspan=2, 396(17) μs
, α
, Th
, rowspan=2, 0+
, rowspan=2,
, rowspan=2,
, -
, β?
, Pa
, -id=Uranium-225
, U
,
, style="text-align:right" , 92
, style="text-align:right" , 133
, 225.029385(11)
, 62(4) ms
, α
, Th
, 5/2+#
,
,
, -id=Uranium-226
, U
,
, style="text-align:right" , 92
, style="text-align:right" , 134
, 226.029339(12)
, 269(6) ms
, α
, Th
, 0+
,
,
, -id=Uranium-227
, rowspan=2, U
, rowspan=2,
, rowspan=2 style="text-align:right" , 92
, rowspan=2 style="text-align:right" , 135
, rowspan=2, 227.0311811(91)
, rowspan=2, 1.1(1) min
, α
, Th
, rowspan=2, (3/2+)
, rowspan=2,
, rowspan=2,
, -
, β?
, Pa
, -id=Uranium-228
, rowspan=2, U
, rowspan=2,
, rowspan=2 style="text-align:right" , 92
, rowspan=2 style="text-align:right" , 136
, rowspan=2, 228.031369(14)
, rowspan=2, 9.1(2) min
, α (97.5%)
, Th
, rowspan=2, 0+
, rowspan=2,
, rowspan=2,
, -
,
EC (2.5%)
, Pa
, -id=Uranium-229
, rowspan=2, U
, rowspan=2,
, rowspan=2 style="text-align:right" , 92
, rowspan=2 style="text-align:right" , 137
, rowspan=2, 229.0335060(64)
, rowspan=2, 57.8(5) min
, β (80%)
, Pa
, rowspan=2, (3/2+)
, rowspan=2,
, rowspan=2,
, -
, α (20%)
, Th
, -id=Uranium-230
, rowspan=3, U
, rowspan=3,
, rowspan=3 style="text-align:right" , 92
, rowspan=3 style="text-align:right" , 138
, rowspan=3, 230.0339401(48)
, rowspan=3, 20.23(2) d
, α
, Th
, rowspan=3, 0+
, rowspan=3,
, rowspan=3,
, -
,
SF ?
, (various)
, -
,
CD (4.8×10%)
,
Pb Ne
, -id=Uranium-231
, rowspan=2, U
, rowspan=2,
, rowspan=2 style="text-align:right" , 92
, rowspan=2 style="text-align:right" , 139
, rowspan=2, 231.0362922(29)
, rowspan=2, 4.2(1) d
, EC
, Pa
, rowspan=2, 5/2+#
, rowspan=2,
, rowspan=2,
, -
, α (.004%)
, Th
, -
, rowspan=4,
U
, rowspan=4,
, rowspan=4 style="text-align:right" , 92
, rowspan=4 style="text-align:right" , 140
, rowspan=4, 232.0371548(19)
, rowspan=4, 68.9(4) y
, α
, Th
, rowspan=4, 0+
, rowspan=4,
, rowspan=4,
, -
, CD (8.9×10%)
, Pb
Ne
, -
, SF (10%)
, (various)
, -
, CD?
, Hg
Mg
, -
, rowspan=4,
U
, rowspan=4,
, rowspan=4 style="text-align:right" , 92
, rowspan=4 style="text-align:right" , 141
, rowspan=4, 233.0396343(24)
, rowspan=4, 1.592(2)×10 y
, α
, Th
, rowspan=4, 5/2+
, rowspan=4, Trace
[Intermediate decay product of Np]
, rowspan=4,
, -
, CD (≤7.2×10%)
, Pb
Ne
, -
, SF ?
, (various)
, -
, CD ?
, Hg
Mg
, -
, rowspan=5,
U[Used in uranium–thorium dating][Used in uranium–uranium dating]
, rowspan=5, Uranium II
, rowspan=5 style="text-align:right" , 92
, rowspan=5 style="text-align:right" , 142
, rowspan=5, 234.0409503(12)
, rowspan=5, 2.455(6)×10 y
, α
, Th
, rowspan=5, 0+
, rowspan=5,
.000054(5)ref group="n">Intermediate
decay product
In nuclear physics, a decay product (also known as a daughter product, daughter isotope, radio-daughter, or daughter nuclide) is the remaining nuclide left over from radioactive decay. Radioactive decay often proceeds via a sequence of steps ( d ...
of U
, rowspan=5, 0.000050–
0.000059
, -
, SF (1.64×10%)
, (various)
, -
, CD (1.4×10%)
, Hg
Mg
, -
, CD (≤9×10%)
, Pb
Ne
, -
, CD (≤9×10%)
, Pb
Ne
, -id=Uranium-234m
, style="text-indent:1em" , U
,
, colspan="3" style="text-indent:2em" , 1421.257(17) keV
, 33.5(20) ms
,
IT
, U
, 6−
,
,
, -
, rowspan=5,
U[Primordial ]radionuclide
A radionuclide (radioactive nuclide, radioisotope or radioactive isotope) is a nuclide that has excess numbers of either neutrons or protons, giving it excess nuclear energy, and making it unstable. This excess energy can be used in one of three ...
[Used in ]Uranium–lead dating
Uranium–lead dating, abbreviated U–Pb dating, is one of the oldest and most refined of the radiometric dating schemes. It can be used to date rocks that formed and crystallised from about 1 million years to over 4.5 billion years ago with routi ...
[Important in nuclear reactors]
, rowspan=5, Actin Uranium
Actino-Uranium
, rowspan=5 style="text-align:right" , 92
, rowspan=5 style="text-align:right" , 143
, rowspan=5, 235.0439281(12)
, rowspan=5, 7.038(1)×10 y
, α
, Th
, rowspan=5, 7/2−
, rowspan=5,
.007204(6), rowspan=5, 0.007198–
0.007207
, -
, SF (7×10%)
, (various)
, -
, CD (8×10%)
, Pb
Ne
, -
, CD (8×10%)
, Pb
Ne
, -
, CD (8×10%)
, Hg
Mg
, -id=Uranium-235m1
, style="text-indent:1em" , U
,
, colspan="3" style="text-indent:2em" , 0.076737(18) keV
, 25.7(1) min
, IT
, ''U''
, 1/2+
,
,
, -id=Uranium-235m2
, style="text-indent:1em" , U
,
, colspan="3" style="text-indent:2em" , 2500(300) keV
, 3.6(18) ms
, SF
, (various)
,
,
,
, -
, rowspan=4,
U
, rowspan=4, Thoruranium
, rowspan=4 style="text-align:right" , 92
, rowspan=4 style="text-align:right" , 144
, rowspan=4, 236.0455661(12)
, rowspan=4, 2.342(3)×10 y
, α
, ''Th''
, rowspan=4, 0+
, rowspan=4, Trace
[Intermediate decay product of Pu, also produced by ]neutron capture
Neutron capture is a nuclear reaction in which an atomic nucleus and one or more neutrons collide and merge to form a heavier nucleus. Since neutrons have no electric charge, they can enter a nucleus more easily than positively charged protons, wh ...
of U
, rowspan=4,
, -
, SF (9.6×10%)
, (various)
, -
, CD (≤2.0×10%)
, Hg
Mg
, -
, CD (≤2.0×10%)
, Hg
Mg
, -id=Uranium-236m1
, style="text-indent:1em" , U
,
, colspan="3" style="text-indent:2em" , 1052.5(6) keV
, 100(4) ns
, IT
, U
, 4−
,
,
, -id=Uranium-236m2
, rowspan=2 style="text-indent:1em" , U
, rowspan=2,
, rowspan=2 colspan="3" style="text-indent:2em" , 2750(3) keV
, rowspan=2, 120(2) ns
, IT (87%)
, U
, rowspan=2, (0+)
, rowspan=2,
, rowspan=2,
, -
, SF (13%)
, (various)
, -
, U
,
, style="text-align:right" , 92
, style="text-align:right" , 145
, 237.0487283(13)
, 6.752(2) d
,
β
, Np
, 1/2+
, Trace
[Neutron capture product, parent of trace quantities of Np]
,
, -id=Uranium-237m
, style="text-indent:1em" , U
,
, colspan="3" style="text-indent:2em" , 274.0(10) keV
, 155(6) ns
, IT
, U
, 7/2−
,
,
, -
, rowspan=3,
U
, rowspan=3, Uranium I
, rowspan=3 style="text-align:right" , 92
, rowspan=3 style="text-align:right" , 146
, rowspan=3, 238.050787618(15)
, rowspan=3, 4.468(3)×10 y
, α
, Th
, rowspan=3, 0+
, rowspan=3,
.992742(10), rowspan=3, 0.992739–
0.992752
, -
, SF (5.44×10%)
, (various)
, -
,
ββ (2.2×10%)
, Pu
, -id=Uranium-238m
, rowspan=2 style="text-indent:1em" , U
, rowspan=2,
, rowspan=2 colspan="3" style="text-indent:2em" , 2557.9(5) keV
, rowspan=2, 280(6) ns
, IT (97.4%)
, ''U''
, rowspan=2, 0+
, rowspan=2,
, rowspan=2,
, -
, SF (2.6%)
, (various)
, -
, U
,
, style="text-align:right" , 92
, style="text-align:right" , 147
, 239.0542920(16)
, 23.45(2) min
, β
, Np
, 5/2+
, Trace
[Neutron capture product; parent of trace quantities of Pu]
,
, -id=Uranium-239m1
, style="text-indent:1em" , U
,
, colspan="3" style="text-indent:2em" , 133.7991(10) keV
, 780(40) ns
, IT
, U
, 1/2+
,
,
, -id=Uranium-239m2
, rowspan=2 style="text-indent:1em" , U
, rowspan=2,
, rowspan=2 colspan="3" style="text-indent:2em" , 2500(900)# keV
, rowspan=2, >250 ns
, SF?
, (various)
, rowspan=2, 0+
, rowspan=2,
, rowspan=2,
, -
, IT?
, U
, -id=Uranium-240
, rowspan=2, U
, rowspan=2,
, rowspan=2 style="text-align:right" , 92
, rowspan=2 style="text-align:right" , 148
, rowspan=2, 240.0565924(27)
, rowspan=2, 14.1(1) h
, β
, Np
, rowspan=2, 0+
, rowspan=2, Trace
[Intermediate decay product of Pu]
, rowspan=2,
, -
, α?
, Th
, -
, U
,
, style="text-align:right" , 92
, style="text-align:right" , 149
, 241.06031(5)
, ~40 min
, β
, Np
, 7/2+#
,
, -->
, -id=Uranium-242
, U
,
, style="text-align:right" , 92
, style="text-align:right" , 150
, 242.06296(10)
, 16.8(5) min
, β
, Np
, 0+
,
,
Actinides vs fission products
Uranium-214
Uranium-214 is the lightest known isotope of uranium. It was discovered at the Spectrometer for Heavy Atoms and Nuclear Structure (SHANS) at the Heavy Ion Research Facility in
Lanzhou
Lanzhou is the capital and largest city of Gansu province in northwestern China. Located on the banks of the Yellow River, it is a key regional transportation hub, connecting areas further west by rail to the eastern half of the country. His ...
,
China
China, officially the People's Republic of China (PRC), is a country in East Asia. With population of China, a population exceeding 1.4 billion, it is the list of countries by population (United Nations), second-most populous country after ...
in 2021, produced by firing argon-36 at tungsten-182. It alpha-decays with a half-life of .
Uranium-232
Uranium-232 has a half-life of 68.9 years and is a side product in the
thorium cycle. It has been cited as an obstacle to
nuclear proliferation
Nuclear proliferation is the spread of nuclear weapons to additional countries, particularly those not recognized as List of states with nuclear weapons, nuclear-weapon states by the Treaty on the Non-Proliferation of Nuclear Weapons, commonl ...
using U, because the intense
gamma radiation
A gamma ray, also known as gamma radiation (symbol ), is a penetrating form of electromagnetic radiation arising from high energy interactions like the radioactive decay of atomic nuclei or astronomical events like solar flares. It consists o ...
from
Tl (a daughter of U, produced relatively quickly) makes U contaminated with it more difficult to handle. Uranium-232 is a rare example of an
even-even isotope that is
fissile
In nuclear engineering, fissile material is material that can undergo nuclear fission when struck by a neutron of low energy. A self-sustaining thermal Nuclear chain reaction#Fission chain reaction, chain reaction can only be achieved with fissil ...
with both thermal and fast neutrons.
Uranium-233
Uranium-233 is a fissile isotope that is bred from
thorium-232
Thorium-232 () is the main naturally occurring isotope of thorium, with a relative abundance of 99.98%. It has a half life of 14.05 billion years, which makes it the longest-lived isotope of thorium. It decays by alpha decay to radium-228; its de ...
as part of the thorium fuel cycle. U was investigated for use in nuclear weapons and as a reactor fuel. It was occasionally tested but never deployed in nuclear weapons and has not been used commercially as a nuclear fuel.
It has been used successfully in experimental nuclear reactors and has been proposed for much wider use as a nuclear fuel. It has a half-life of around 160,000 years.
Uranium-233 is produced by neutron irradiation of thorium-232. When thorium-232 absorbs a
neutron
The neutron is a subatomic particle, symbol or , that has no electric charge, and a mass slightly greater than that of a proton. The Discovery of the neutron, neutron was discovered by James Chadwick in 1932, leading to the discovery of nucle ...
, it becomes
thorium-233, which has a half-life of only 22 minutes. Thorium-233
beta decay
In nuclear physics, beta decay (β-decay) is a type of radioactive decay in which an atomic nucleus emits a beta particle (fast energetic electron or positron), transforming into an isobar of that nuclide. For example, beta decay of a neutron ...
s into
protactinium-233. Protactinium-233 has a half-life of 27 days and beta decays into uranium-233; some proposed molten salt reactor designs attempt to physically isolate the protactinium from further neutron capture before beta decay can occur.
Uranium-233 usually fissions on neutron absorption but sometimes retains the neutron, becoming
uranium-234. The capture-to-fission ratio is smaller than the other two major fissile fuels,
uranium-235
Uranium-235 ( or U-235) is an isotope of uranium making up about 0.72% of natural uranium. Unlike the predominant isotope uranium-238, it is fissile, i.e., it can sustain a nuclear chain reaction. It is the only fissile isotope that exists in nat ...
and
plutonium-239
Plutonium-239 ( or Pu-239) is an isotope of plutonium. Plutonium-239 is the primary fissile isotope used for the production of nuclear weapons, although uranium-235 is also used for that purpose. Plutonium-239 is also one of the three main iso ...
; it is also lower than that of short-lived
plutonium-241, but bested by very difficult-to-produce
neptunium-236
Neptunium (93Np) is usually considered an artificial element, although trace quantities are found in nature, so a standard atomic weight cannot be given. Like all trace or artificial elements, it has no stable isotopes. The first isotope to be syn ...
.
Uranium-234
U occurs in natural uranium as an indirect decay product of uranium-238, but makes up only 55 parts per
million
1,000,000 (one million), or one thousand thousand, is the natural number following 999,999 and preceding 1,000,001. The word is derived from the early Italian ''millione'' (''milione'' in modern Italian), from ''mille'', "thousand", plus the ...
of the uranium because its
half-life Half-life is a mathematical and scientific description of exponential or gradual decay.
Half-life, half life or halflife may also refer to:
Film
* Half-Life (film), ''Half-Life'' (film), a 2008 independent film by Jennifer Phang
* ''Half Life: ...
of 245,500 years is only about 1/18,000 that of U. The path of production of U is this: U
alpha decay
Alpha decay or α-decay is a type of radioactive decay in which an atomic nucleus emits an alpha particle (helium nucleus). The parent nucleus transforms or "decays" into a daughter product, with a mass number that is reduced by four and an a ...
s to
thorium-234
Thorium (90Th) has seven naturally occurring isotopes but none are stable. One isotope, 232Th, is ''relatively'' stable, with a half-life of 1.405×1010 years, considerably longer than the age of the Earth, and even slightly longer than the gen ...
. Next, with a short
half-life Half-life is a mathematical and scientific description of exponential or gradual decay.
Half-life, half life or halflife may also refer to:
Film
* Half-Life (film), ''Half-Life'' (film), a 2008 independent film by Jennifer Phang
* ''Half Life: ...
, Th
beta decay
In nuclear physics, beta decay (β-decay) is a type of radioactive decay in which an atomic nucleus emits a beta particle (fast energetic electron or positron), transforming into an isobar of that nuclide. For example, beta decay of a neutron ...
s to
protactinium-234. Finally, Pa beta decays to U.
U
alpha decay
Alpha decay or α-decay is a type of radioactive decay in which an atomic nucleus emits an alpha particle (helium nucleus). The parent nucleus transforms or "decays" into a daughter product, with a mass number that is reduced by four and an a ...
s to
thorium-230, except for a small percentage of nuclei that undergo
spontaneous fission.
Extraction of small amounts of U from natural uranium could be done using
isotope separation, similar to normal uranium-enrichment. However, there is no real demand in
chemistry
Chemistry is the scientific study of the properties and behavior of matter. It is a physical science within the natural sciences that studies the chemical elements that make up matter and chemical compound, compounds made of atoms, molecules a ...
,
physics
Physics is the scientific study of matter, its Elementary particle, fundamental constituents, its motion and behavior through space and time, and the related entities of energy and force. "Physical science is that department of knowledge whi ...
, or engineering for isolating U. Very small pure samples of U can be extracted via the chemical
ion-exchange process, from samples of
plutonium-238 that have aged somewhat to allow some alpha decay to U.
Enriched uranium
Enriched uranium is a type of uranium in which the percent composition of uranium-235 (written 235U) has been increased through the process of isotope separation. Naturally occurring uranium is composed of three major isotopes: uranium-238 (23 ...
contains more U than natural uranium as a byproduct of the uranium enrichment process aimed at obtaining
uranium-235
Uranium-235 ( or U-235) is an isotope of uranium making up about 0.72% of natural uranium. Unlike the predominant isotope uranium-238, it is fissile, i.e., it can sustain a nuclear chain reaction. It is the only fissile isotope that exists in nat ...
, which concentrates lighter isotopes even more strongly than it does U. The increased percentage of U in enriched natural uranium is acceptable in current nuclear reactors, but (re-enriched)
reprocessed uranium might contain even higher fractions of U, which is undesirable.
This is because U is not
fissile
In nuclear engineering, fissile material is material that can undergo nuclear fission when struck by a neutron of low energy. A self-sustaining thermal Nuclear chain reaction#Fission chain reaction, chain reaction can only be achieved with fissil ...
, and tends to absorb slow
neutrons in a
nuclear reactor
A nuclear reactor is a device used to initiate and control a Nuclear fission, fission nuclear chain reaction. They are used for Nuclear power, commercial electricity, nuclear marine propulsion, marine propulsion, Weapons-grade plutonium, weapons ...
—becoming U.
U has a
neutron capture
Neutron capture is a nuclear reaction in which an atomic nucleus and one or more neutrons collide and merge to form a heavier nucleus. Since neutrons have no electric charge, they can enter a nucleus more easily than positively charged protons, wh ...
cross section of about 100
barns for
thermal neutrons, and about 700 barns for its
resonance integral—the average over neutrons having various intermediate energies. In a nuclear reactor, non-fissile isotopes capture a neutron breeding fissile isotopes. U is converted to U more easily and therefore at a greater rate than
uranium-238
Uranium-238 ( or U-238) is the most common isotope of uranium found in nature, with a relative abundance of 99%. Unlike uranium-235, it is non-fissile, which means it cannot sustain a chain reaction in a thermal-neutron reactor. However, it i ...
is to
plutonium-239
Plutonium-239 ( or Pu-239) is an isotope of plutonium. Plutonium-239 is the primary fissile isotope used for the production of nuclear weapons, although uranium-235 is also used for that purpose. Plutonium-239 is also one of the three main iso ...
(via
neptunium-239
Neptunium (93Np) is usually considered an artificial element, although trace quantities are found in nature, so a standard atomic weight cannot be given. Like all trace or artificial elements, it has no stable isotopes. The first isotope to be ...
), because U has a much smaller neutron-capture
cross section of just 2.7 barns.
Uranium-235
Uranium-235 makes up about 0.72% of natural uranium. Unlike the predominant isotope
uranium-238
Uranium-238 ( or U-238) is the most common isotope of uranium found in nature, with a relative abundance of 99%. Unlike uranium-235, it is non-fissile, which means it cannot sustain a chain reaction in a thermal-neutron reactor. However, it i ...
, it is
fissile
In nuclear engineering, fissile material is material that can undergo nuclear fission when struck by a neutron of low energy. A self-sustaining thermal Nuclear chain reaction#Fission chain reaction, chain reaction can only be achieved with fissil ...
, i.e., it can sustain a
fission chain reaction
A chain reaction is a sequence of reactions where a reactive product or by-product causes additional reactions to take place. In a chain reaction, positive feedback leads to a self-amplifying chain of events.
Chain reactions are one way that sys ...
. It is the only
fissile isotope that is a
primordial nuclide or found in significant quantity in nature.
Uranium-235 has a
half-life Half-life is a mathematical and scientific description of exponential or gradual decay.
Half-life, half life or halflife may also refer to:
Film
* Half-Life (film), ''Half-Life'' (film), a 2008 independent film by Jennifer Phang
* ''Half Life: ...
of 703.8
million years
Million years ago, abbreviated as Mya, Myr (megayear) or Ma (megaannum), is a unit of time equal to (i.e. years), or approximately 31.6 teraseconds.
Usage
Myr is in common use in fields such as Earth science and cosmology. Myr is also used ...
. It was discovered in 1935 by
Arthur Jeffrey Dempster. Its (fission) nuclear
cross section for slow
thermal neutron
The neutron detection temperature, also called the neutron energy, indicates a free neutron's kinetic energy, usually given in electron volts. The term ''temperature'' is used, since hot, thermal and cold neutrons are moderated in a medium wit ...
is about 504.81
barns. For fast
neutrons it is on the order of 1 barn. At thermal energy levels, about 5 of 6 neutron absorptions result in fission and 1 of 6 result in neutron capture forming
uranium-236
Uranium-236 ( or U-236) is an isotope of uranium that is neither fissile with thermal neutrons, nor very good fertile material, but is generally considered a nuisance and long-lived radioactive waste. It is found in spent nuclear fuel and in ...
. The fission-to-capture ratio improves for faster neutrons.
Uranium-236
Uranium-236 has a half-life of about 23 million years; and is neither fissile with thermal neutrons, nor very good fertile material, but is generally considered a nuisance and long-lived
radioactive waste
Radioactive waste is a type of hazardous waste that contains radioactive material. It is a result of many activities, including nuclear medicine, nuclear research, nuclear power generation, nuclear decommissioning, rare-earth mining, and nuclear ...
. It is found in spent
nuclear fuel
Nuclear fuel refers to any substance, typically fissile material, which is used by nuclear power stations or other atomic nucleus, nuclear devices to generate energy.
Oxide fuel
For fission reactors, the fuel (typically based on uranium) is ...
and in the reprocessed uranium made from spent nuclear fuel.
Uranium-237
Uranium-237 has a half-life of about 6.75 days. It decays into
neptunium-237 by
beta decay
In nuclear physics, beta decay (β-decay) is a type of radioactive decay in which an atomic nucleus emits a beta particle (fast energetic electron or positron), transforming into an isobar of that nuclide. For example, beta decay of a neutron ...
. It was discovered by Japanese physicist
Yoshio Nishina in 1940, who in a near-miss discovery, inferred the creation of element 93, but was unable to isolate the then-unknown element or measure its decay properties.
Uranium-238
Uranium-238 (U or U-238) is the most common
isotope
Isotopes are distinct nuclear species (or ''nuclides'') of the same chemical element. They have the same atomic number (number of protons in their Atomic nucleus, nuclei) and position in the periodic table (and hence belong to the same chemica ...
of
uranium
Uranium is a chemical element; it has chemical symbol, symbol U and atomic number 92. It is a silvery-grey metal in the actinide series of the periodic table. A uranium atom has 92 protons and 92 electrons, of which 6 are valence electrons. Ura ...
in nature. It is not
fissile
In nuclear engineering, fissile material is material that can undergo nuclear fission when struck by a neutron of low energy. A self-sustaining thermal Nuclear chain reaction#Fission chain reaction, chain reaction can only be achieved with fissil ...
, but is
fertile: it can capture a slow
neutron
The neutron is a subatomic particle, symbol or , that has no electric charge, and a mass slightly greater than that of a proton. The Discovery of the neutron, neutron was discovered by James Chadwick in 1932, leading to the discovery of nucle ...
and after two
beta decays become fissile
plutonium-239
Plutonium-239 ( or Pu-239) is an isotope of plutonium. Plutonium-239 is the primary fissile isotope used for the production of nuclear weapons, although uranium-235 is also used for that purpose. Plutonium-239 is also one of the three main iso ...
. Uranium-238 is fissionable by fast neutrons, but cannot support a chain reaction because inelastic scattering reduces
neutron energy below the range where fast fission of one or more next-generation nuclei is probable. Doppler broadening of U's neutron absorption resonances, increasing absorption as fuel temperature increases, is also an essential negative feedback mechanism for reactor control.
About 99.284% of natural uranium is uranium-238, which has a half-life of 1.41×10 seconds (4.468×10 years). Depleted uranium has an even higher concentration of U, and even low-enriched uranium (LEU) is still mostly U. Reprocessed uranium is also mainly U, with about as much uranium-235 as natural uranium, a comparable proportion of uranium-236, and much smaller amounts of other isotopes of uranium such as
uranium-234,
uranium-233
Uranium-233 ( or U-233) is a fissile isotope of uranium that is bred from thorium-232 as part of the thorium fuel cycle. Uranium-233 was investigated for use in nuclear weapons and as a Nuclear fuel, reactor fuel. It has been used successfully ...
, and
uranium-232.
Uranium-239
Uranium-239 is usually produced by exposing U to
neutron radiation
Neutron radiation is a form of ionizing radiation that presents as free neutrons. Typical phenomena are nuclear fission or nuclear fusion causing the release of free neutrons, which then react with nuclei of other atoms to form new nuclides— ...
in a nuclear reactor. U has a half-life of about 23.45 minutes and
beta decay
In nuclear physics, beta decay (β-decay) is a type of radioactive decay in which an atomic nucleus emits a beta particle (fast energetic electron or positron), transforming into an isobar of that nuclide. For example, beta decay of a neutron ...
s into
neptunium-239
Neptunium (93Np) is usually considered an artificial element, although trace quantities are found in nature, so a standard atomic weight cannot be given. Like all trace or artificial elements, it has no stable isotopes. The first isotope to be ...
, with a total decay energy of about 1.29 MeV. The most common gamma decay at 74.660 keV accounts for the difference in the two major channels of beta emission energy, at 1.28 and 1.21 MeV.
Np then, with a half-life of about 2.356 days, beta-decays to
plutonium-239
Plutonium-239 ( or Pu-239) is an isotope of plutonium. Plutonium-239 is the primary fissile isotope used for the production of nuclear weapons, although uranium-235 is also used for that purpose. Plutonium-239 is also one of the three main iso ...
.
Uranium-241
In 2023, in a paper published in ''
Physical Review Letters
''Physical Review Letters'' (''PRL''), established in 1958, is a peer-reviewed, scientific journal that is published 52 times per year by the American Physical Society. The journal is considered one of the most prestigious in the field of physics ...
'', a group of researchers based in South Korea reported that they had found uranium-241 in an experiment involving U+Pt multinucleon transfer reactions.
Its half-life is about 40 minutes.
References
{{Authority control
Uranium
Uranium
Uranium is a chemical element; it has chemical symbol, symbol U and atomic number 92. It is a silvery-grey metal in the actinide series of the periodic table. A uranium atom has 92 protons and 92 electrons, of which 6 are valence electrons. Ura ...