ISOSTATICALLY PRESSED NICKEL ALLOY TEST SPECIMENS - NARA - 17441738

Hot isostatic pressing (HIP) is a

manufacturing Manufacturing is the creation or production of goods with the help of equipment, labor, machines, tools, and chemical or biological processing or formulation. It is the essence of the secondary sector of the economy. The term may refer ...

process, used to reduce the

porosity Porosity or void fraction is a measure of the void (i.e. "empty") spaces in a material, and is a fraction of the volume of voids over the total volume, between 0 and 1, or as a percentage between 0% and 100%. Strictly speaking, some tests measure ...

metal A metal () is a material that, when polished or fractured, shows a lustrous appearance, and conducts electrical resistivity and conductivity, electricity and thermal conductivity, heat relatively well. These properties are all associated wit ...

s and increase the

density Density (volumetric mass density or specific mass) is the ratio of a substance's mass to its volume. The symbol most often used for density is ''ρ'' (the lower case Greek letter rho), although the Latin letter ''D'' (or ''d'') can also be u ...

of many

ceramic A ceramic is any of the various hard, brittle, heat-resistant, and corrosion-resistant materials made by shaping and then firing an inorganic, nonmetallic material, such as clay, at a high temperature. Common examples are earthenware, porcela ...

materials. This improves the material's mechanical properties and workability. The HIP process subjects a component to both elevated temperature and isostatic gas pressure within a high-pressure containment vessel, unlike the cold isostatic pressing (CIP), where the component is maintained at room temperature. The pressurizing gas most widely used is

argon Argon is a chemical element; it has symbol Ar and atomic number 18. It is in group 18 of the periodic table and is a noble gas. Argon is the third most abundant gas in Earth's atmosphere, at 0.934% (9340 ppmv). It is more than twice as abu ...

. An

inert gas An inert gas is a gas that does not readily undergo chemical reactions with other chemical substances and therefore does not readily form chemical compounds. Though inert gases have a variety of applications, they are generally used to prevent u ...

is used so that the material does not chemically react. The choice of metal can minimize negative effects of chemical reactions. Nickel, stainless or

mild steel Carbon steel is a steel with carbon content from about 0.05 up to 2.1 percent by weight. The definition of carbon steel from the American Iron and Steel Institute (AISI) states: * no minimum content is specified or required for chromium, cobalt ...

, or other metals can be chosen depending on the desired

redox Redox ( , , reduction–oxidation or oxidation–reduction) is a type of chemical reaction in which the oxidation states of the reactants change. Oxidation is the loss of electrons or an increase in the oxidation state, while reduction is t ...

conditions. The chamber is heated, causing the

pressure Pressure (symbol: ''p'' or ''P'') is the force applied perpendicular to the surface of an object per unit area over which that force is distributed. Gauge pressure (also spelled ''gage'' pressure)The preferred spelling varies by country and eve ...

inside the vessel to increase. Many systems use associated gas pumping to achieve the necessary pressure level. Pressure is applied to the material from all directions (hence the term "isostatic"). For processing

casting Casting is a manufacturing process in which a liquid material is usually poured into a mold, which contains a hollow cavity of the desired shape, and then allowed to solidify. The solidified part is also known as a casting, which is ejected or ...

s, metal powders can also be turned to compact solids by this method, the inert gas is applied between and , with being most common. Process soak temperatures range from for

aluminium Aluminium (or aluminum in North American English) is a chemical element; it has chemical symbol, symbol Al and atomic number 13. It has a density lower than that of other common metals, about one-third that of steel. Aluminium has ...

castings to for

nickel Nickel is a chemical element; it has symbol Ni and atomic number 28. It is a silvery-white lustrous metal with a slight golden tinge. Nickel is a hard and ductile transition metal. Pure nickel is chemically reactive, but large pieces are slo ...

-based

superalloy A superalloy, or high-performance alloy, is an alloy with the ability to operate at a high fraction of its melting point. Key characteristics of a superalloy include mechanical strength, thermal creep deformation resistance, surface stability, ...

s. When castings are treated with HIP, the simultaneous application of heat and pressure eliminates internal voids and microporosity through a combination of

plastic deformation In engineering, deformation (the change in size or shape of an object) may be ''elastic'' or ''plastic''. If the deformation is negligible, the object is said to be ''rigid''. Main concepts Occurrence of deformation in engineering application ...

, creep, and

diffusion bonding Diffusion bonding or diffusion welding is a solid-state welding technique used in metalworking, capable of joining similar and dissimilar metals. It operates on the principle of solid-state diffusion, wherein the atoms of two solid, metallic surfa ...

; this process improves fatigue resistance of the component. Primary applications are the reduction of

microshrinkage A casting defect is an undesired irregularity in a metal casting process. Some defects can be tolerated while others can be repaired, otherwise they must be eliminated. They are broken down into five main categories: ''gas porosity'', ''shrinkage ...

, the consolidation of powder metals, ceramic composites and metal cladding. Hot isostatic pressing is thus also used as part of a

sintering Sintering or frittage is the process of compacting and forming a solid mass of material by pressure or heat without melting it to the point of liquefaction. Sintering happens as part of a manufacturing process used with metals, ceramics, plas ...

(

powder metallurgy Powder metallurgy (PM) is a term covering a wide range of ways in which materials or components are made from metal powders. PM processes are sometimes used to reduce or eliminate the need for subtractive manufacturing, subtractive processes in ma ...

) process and for fabrication of

metal matrix composite In materials science, a metal matrix composite (MMC) is a composite material with fibers or particles dispersed in a metallic matrix, such as copper, aluminum, or steel. The secondary phase is typically a ceramic (such as alumina or silicon carb ...

s, often being used for postprocessing in

additive manufacturing 3D printing, or additive manufacturing, is the construction of a three-dimensional object from a CAD model or a digital 3D model. It can be done in a variety of processes in which material is deposited, joined or solidified under computer ...

. The process can be used to produce waste form classes. Calcined radioactive waste (waste with additives) is packed into a thin walled metal canister. The

adsorbed Adsorption is the adhesion of atoms, ions or molecules from a gas, liquid or dissolved solid to a surface. This process creates a film of the ''adsorbate'' on the surface of the ''adsorbent''. This process differs from absorption, in which a f ...

gases are removed with high heat and the remaining material compressed to full density using argon gas during the heat cycle. This process can shrink steel canisters to minimize space in disposal containers and during transport. It was invented in the 1950s at the

Battelle Memorial Institute Battelle Memorial Institute (or simply Battelle) is an American private nonprofit applied science and technology development company headquartered in Columbus, Ohio. History The institute was founded in 1929 by Gordon Battelle. Originall ...

and has been used to prepare

nuclear fuel Nuclear fuel refers to any substance, typically fissile material, which is used by nuclear power stations or other atomic nucleus, nuclear devices to generate energy. Oxide fuel For fission reactors, the fuel (typically based on uranium) is ...

for

submarines A submarine (often shortened to sub) is a watercraft capable of independent operation underwater. (It differs from a submersible, which has more limited underwater capability.) The term "submarine" is also sometimes used historically or info ...

since the 1960s. It is used to prepare inactive ceramics as well, and the

Idaho National Laboratory Idaho National Laboratory (INL) is one of the national laboratories of the United States Department of Energy and is managed by the Battelle Energy Alliance. Historically, the lab has been involved with nuclear research, although the labora ...

has validated it for the consolidation of radioactive ceramic waste forms.

ANSTO The Australian Nuclear Science and Technology Organisation (ANSTO) is a statutory body of the Australian Government that is responsible for nuclear research and the production of radioisotopes for nuclear medicine. It was established in Apr ...

(Australian Nuclear Science and Technology Organisation) is using HIP as part of a process to immobilize waste

radionuclides A radionuclide (radioactive nuclide, radioisotope or radioactive isotope) is a nuclide that has excess numbers of either neutrons or protons, giving it excess nuclear energy, and making it unstable. This excess energy can be used in one of three ...

from

molybdenum-99 Molybdenum (42Mo) has 39 known isotopes, ranging in atomic mass from 81 to 119, as well as four metastable nuclear isomers. Seven isotopes occur naturally, with atomic masses of 92, 94, 95, 96, 97, 98, and 100. All unstable isotopes of molybdenum ...

production.

References

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External links

European Powder Metallurgy Association (EPMA) - Hot Isostatic Pressing
EPMA HIP info page Industrial processes Metallurgical processes Metalworking