Iron meteorites, also called siderites or
ferrous
In chemistry, iron(II) refers to the chemical element, element iron in its +2 oxidation number, oxidation state. The adjective ''ferrous'' or the prefix ''ferro-'' is often used to specify such compounds, as in ''ferrous chloride'' for iron(II ...
meteorites, are a type of
meteorite
A meteorite is a rock (geology), rock that originated in outer space and has fallen to the surface of a planet or Natural satellite, moon. When the original object enters the atmosphere, various factors such as friction, pressure, and chemical ...
that consist overwhelmingly of an
iron–nickel alloy known as
meteoric iron that usually consists of two
mineral
In geology and mineralogy, a mineral or mineral species is, broadly speaking, a solid substance with a fairly well-defined chemical composition and a specific crystal structure that occurs naturally in pure form.John P. Rafferty, ed. (2011): Mi ...
phases:
kamacite and
taenite. Most iron meteorites originate from
cores of
planetesimals,
with the exception of the
IIE iron meteorite group.
The iron found in iron meteorites was one of the earliest sources of usable iron available to
human
Humans (''Homo sapiens'') or modern humans are the most common and widespread species of primate, and the last surviving species of the genus ''Homo''. They are Hominidae, great apes characterized by their Prehistory of nakedness and clothing ...
s, due to the malleability and ductility of the meteoric iron, before the development of
smelting
Smelting is a process of applying heat and a chemical reducing agent to an ore to extract a desired base metal product. It is a form of extractive metallurgy that is used to obtain many metals such as iron-making, iron, copper extraction, copper ...
that signaled the beginning of the
Iron Age
The Iron Age () is the final epoch of the three historical Metal Ages, after the Chalcolithic and Bronze Age. It has also been considered as the final age of the three-age division starting with prehistory (before recorded history) and progre ...
.
Occurrence
Although they are fairly rare compared to the
stony meteorites, comprising only about 5.7% of witnessed falls, iron meteorites have historically been heavily over-represented in
meteorite
A meteorite is a rock (geology), rock that originated in outer space and has fallen to the surface of a planet or Natural satellite, moon. When the original object enters the atmosphere, various factors such as friction, pressure, and chemical ...
collections. This is due to several factors:
* They are easily recognized as unusual, as opposed to stony meteorites. Modern-day searches for meteorites in deserts and Antarctica yield a much more representative sample of meteorites overall.
* They are much more resistant to weathering.
* They are much more likely to survive atmospheric entry, and are more resistant to the resulting
ablation. Hence, they are more likely to be found as large pieces.
* They can be found even when buried by use of surface metal-detecting equipment, due to their metallic composition.
Because they are also denser than stony meteorites, iron meteorites also account for almost 90% of the mass of all known meteorites, about 500 tons. All the largest known meteorites are of this type, including the largest—the
Hoba meteorite.
Origin
Iron meteorites have been linked to
M-type asteroids because both have similar spectral characteristics in the visible and near-infrared. Iron meteorites are thought to be the fragments of the cores of larger ancient
asteroid
An asteroid is a minor planet—an object larger than a meteoroid that is neither a planet nor an identified comet—that orbits within the Solar System#Inner Solar System, inner Solar System or is co-orbital with Jupiter (Trojan asteroids). As ...
s that have been shattered by impacts. The heat released from the radioactive decay of the short-lived nuclides
26Al and
60Fe is considered as a plausible cause for the melting and differentiation of their parent bodies in the early Solar System.
Melting produced from the heat of impacts is another cause of melting and differentiation. The
IIE iron meteorites may be a notable exception, in that they probably originate from the crust of
S-type asteroid 6 Hebe.
Chemical and isotope analysis indicates that at least about 50 distinct parent bodies were involved. This implies that there were once at least this many large,
differentiated, asteroids in the asteroid belt – many more than today.
Composition
The overwhelming bulk of these meteorites consists of the FeNi-alloys
kamacite and
taenite. Minor minerals, when occurring, often form rounded nodules of
troilite or
graphite
Graphite () is a Crystallinity, crystalline allotrope (form) of the element carbon. It consists of many stacked Layered materials, layers of graphene, typically in excess of hundreds of layers. Graphite occurs naturally and is the most stable ...
, surrounded by
schreibersite and
cohenite.
Schreibersite and
troilite also occur as plate shaped inclusions, which show up on cut surfaces as cm-long and mm-thick lamellae. The
troilite plates are called ''
Reichenbach lamellae''.
The chemical composition is dominated by the elements
Fe,
Ni and
Co, which make up more than 95%.
Ni is always present; the concentration is nearly always higher than 5% and may be as high as about 25%. A significant percentage of nickel can be used in the field to distinguish meteoritic irons from human-made iron products, which usually contain lower amounts of Ni, but it is not enough to prove meteoritic origin.
Use
Iron meteorites were historically used for their
meteoric iron, which was forged into cultural objects, tools or weapons. With the advent of smelting and the beginning of the
Iron Age
The Iron Age () is the final epoch of the three historical Metal Ages, after the Chalcolithic and Bronze Age. It has also been considered as the final age of the three-age division starting with prehistory (before recorded history) and progre ...
the importance of iron meteorites as a resource decreased, at least in those cultures that developed those techniques. In Ancient Egypt and other civilizations before the
Iron Age
The Iron Age () is the final epoch of the three historical Metal Ages, after the Chalcolithic and Bronze Age. It has also been considered as the final age of the three-age division starting with prehistory (before recorded history) and progre ...
, iron was as valuable as gold, since both came from meteorites, for example
Tutankhamun's meteoric iron dagger. The Inuit used the
Cape York meteorite
The Cape York meteorite, also known as the Innaanganeq meteorite, is one of the largest known iron meteorites, classified as a medium octahedrite in chemical group IIIAB meteorites, IIIAB. In addition to many small fragments, at least eight large ...
for a much longer time. Iron meteorites themselves were sometimes used unaltered as collectibles or even religious symbols (e.g.
Clackamas worshiping the
Willamette meteorite).
Today iron meteorites are prized collectibles for academic institutions and individuals. Some are also tourist attractions as in the case of the
Hoba meteorite.
Classification
Two classifications are in use: the classic structural classification and the newer chemical classification.
Structural classification
The older structural classification is based on the presence or absence of the
Widmanstätten pattern
Widmanstätten patterns (), also known as Thomson structures, are figures of long Phase (matter), phases of nickel–iron, found in the octahedrite shapes of iron meteorite crystals and some pallasites.
Iron meteorites are very often formed ...
, which can be assessed from the appearance of polished cross-sections that have been etched with acid. This is connected with the relative abundance of nickel to iron. The categories are:
*
Hexahedrites (H): low nickel, no
Widmanstätten pattern
Widmanstätten patterns (), also known as Thomson structures, are figures of long Phase (matter), phases of nickel–iron, found in the octahedrite shapes of iron meteorite crystals and some pallasites.
Iron meteorites are very often formed ...
, may present
Neumann lines;
*
Octahedrite
Octahedrites are the most common Iron meteorite#Structural classification, structural class of iron meteorites. The structures occur because the meteoric iron has a certain nickel concentration that leads to the exsolution of kamacite out of tae ...
s (O): average to high nickel,
Widmanstätten pattern
Widmanstätten patterns (), also known as Thomson structures, are figures of long Phase (matter), phases of nickel–iron, found in the octahedrite shapes of iron meteorite crystals and some pallasites.
Iron meteorites are very often formed ...
s, most common class. They can be further divided up on the basis of the width of the kamacite lamellae from
coarsest to
finest.
**Coarsest (Ogg): lamellae width > 3.3 mm
**Coarse (Og): lamellae width 1.3–3.3 mm
**Medium (Om): lamellae width 0.5–1.3 mm
**Fine (Of): lamellae width 0.2–0.5 mm
**Finest (Off): lamellae width < 0.2 mm
*
Plessitic (Opl): a transitional structure between octahedrites and ataxites
*
Ataxites (D): very high nickel, no
Widmanstätten pattern
Widmanstätten patterns (), also known as Thomson structures, are figures of long Phase (matter), phases of nickel–iron, found in the octahedrite shapes of iron meteorite crystals and some pallasites.
Iron meteorites are very often formed ...
, rare.
Chemical classification
A newer chemical classification scheme based on the proportions of the trace elements
Ga,
Ge and
Ir separates the iron meteorites into classes corresponding to distinct
asteroid
An asteroid is a minor planet—an object larger than a meteoroid that is neither a planet nor an identified comet—that orbits within the Solar System#Inner Solar System, inner Solar System or is co-orbital with Jupiter (Trojan asteroids). As ...
parent bodies. This classification is based on diagrams that plot
nickel content against different trace elements (e.g. Ga, Ge and Ir). The different iron meteorite groups appear as data point clusters.
There were originally four of these groups designated by the Roman numerals I, II, III, IV. When more chemical data became available these were split, e.g. Group IV was split into
IVA and IVB meteorites. Even later some groups got joined again when intermediate meteorites were discovered, e.g. IIIA and IIIB were combined into the IIIAB meteorites.
In 2006 iron meteorites were classified into 13 groups (one for uncategorized irons):
*
IAB
** IA: Medium and coarse octahedrites, 6.4–8.7% Ni, 55–100 ppm Ga, 190–520 ppm Ge, 0.6–5.5 ppm Ir, Ge-Ni correlation negative.
** IB: Ataxites and medium octahedrites, 8.7–25% Ni, 11–55 ppm Ga, 25–190 ppm Ge, 0.3–2 ppm Ir, Ge-Ni correlation negative.
*
IC: 6.1–6.8% Ni. The Ni concentrations are positively correlated with As (4–9 μg/g), Au (0.6–1.0 μg/g) and P (0.17–0.40%) and negatively correlated with Ga (54–42 μg/g), Ir (9–0.07 μg/g) and W (2.4–0.8 μg/g).
*
IIAB
** IIA: Hexahedrites, 5.3–5.7% Ni, 57–62 ppm Ga, 170–185 ppm Ge, 2–60 ppm Ir.
** IIB: Coarsest octahedrites, 5.7–6.4% Ni, 446–59 pm Ga, 107–183 ppm Ge, 0.01–0.5 ppm Ir, Ge-Ni correlation negative.
*
IIC: Plessitic octahedrites, 9.3–11.5% Ni, 37–39 ppm Ga, 88–114 ppm Ge, 4–11 ppm Ir, Ge-Ni correlation positive
*
IID: Fine to medium octahedrites, 9.8–11.3%Ni, 70–83 ppm Ga, 82–98 ppm Ge, 3.5–18 ppm Ir, Ge-Ni correlation positive
*
IIE: octahedrites of various coarseness, 7.5–9.7% Ni, 21–28 ppm Ga, 60–75 ppm Ge, 1–8 ppm Ir, Ge-Ni correlation absent
*
IIIAB: Medium octahedrites, 7.1–10.5% Ni, 16–23 ppm Ga, 27–47 ppm Ge, 0.01–19 ppm Ir
*
IIICD: Ataxites to fine octahedrites, 10–23% Ni, 1.5–27 ppm Ga, 1.4–70 ppm Ge, 0.02–0.55 ppm Ir
*
IIIE: Coarse octahedrites, 8.2–9.0% Ni, 17–19 ppm Ga, 3–37 ppm Ge, 0.05–6 ppm Ir, Ge-Ni correlation absent
*
IIIF: Medium to coarse octahedrites, 6.8–7.8% Ni,6.3–7.2 ppm Ga, 0.7–1.1 ppm Ge, 1.3–7.9 ppm Ir, Ge–Ni correlation absent
*
IVA: Fine octahedrites, 7.4–9.4% Ni, 1.6–2.4 ppm Ga, 0.09–0.14 ppm Ge, 0.4–4 ppm Ir, Ge-Ni correlation positive
*
IVB: Ataxites, 16–26% Ni, 0.17–0.27 ppm Ga, 0,03–0,07 ppm Ge, 13–38 ppm Ir, Ge–Ni correlation positive
* Ungrouped meteorites. This is actually quite a large collection (about 15% of the total) of over 100 meteorites that do not fit into any of the larger classes above, and come from about 50 distinct parent bodies.
Additional groups and grouplets are discussed in the scientific literature:
*
IIG:
Hexahedrites with coarse
schreibersite.
Meteoric iron has low nickel concentration.
Magmatic and nonmagmatic (primitive) irons
The iron meteorites were previously divided into two classes: magmatic irons and non magmatic or primitive irons. Now this definition is deprecated.
Stony–iron meteorites
There are also specific categories for mixed-composition meteorites, in which iron and 'stony' materials are combined.
* Stony–iron meteorites
**
Pallasites
*** Main group pallasites
*** Eagle station pallasite grouplet
***
Pyroxene Pallasite grouplet
**
Mesosiderite group
Gallery
File:Hoba Meteorite sire.jpg, The Hoba meteorite, the biggest known iron meteorite. It lies in Namibia
Namibia, officially the Republic of Namibia, is a country on the west coast of Southern Africa. Its borders include the Atlantic Ocean to the west, Angola and Zambia to the north, Botswana to the east and South Africa to the south; in the no ...
and weighs about 60 tons.
File:Willamette Meteorite AMNH.jpg, The Willamette Meteorite on display at the American Museum of Natural History. It weighs about 14,500 kilograms (32,000 pounds). This is the largest meteorite ever found in the United States.
File:Bendeg%C3%B3_meteorite,_front,_National_Museum,_Rio_de_Janeiro.jpg, The Bendegó meteorite, weighing 5,360 kilograms (11,600 pounds), was found in 1784 and brought in 1888 to its current location at National Museum of Brazil in Rio de Janeiro. It is the largest meteorite ever found in Brazil.
File:Meteoric iron 635 kg - foto Marco Busdraghi.JPG, The Otumpa mass, meteoric iron weighing 635 kilograms (1,400 pounds), from the Campo del Cielo, exhibited in the Natural History Museum, London
The Natural History Museum in London is a museum that exhibits a vast range of specimens from various segments of natural history. It is one of three major museums on Exhibition Road in South Kensington, the others being the Science Museum (Lo ...
, found in 1783 in Chaco, Argentina.
File:SikhoteAlinMeteorite.jpg, A individual meteorite from the 1947 Sikhote-Alin meteorite shower (coarsest octahedrite
Octahedrites are the most common Iron meteorite#Structural classification, structural class of iron meteorites. The structures occur because the meteoric iron has a certain nickel concentration that leads to the exsolution of kamacite out of tae ...
, class IIAB). This specimen is about wide.
File:ChingaMeteorite.jpg, A individual Chinga iron meteorite ( Ataxite, class IVB).Chinga meteorite
at Meteoritical Bulletin Database. This specimen is about 9 centimeters wide.
File:Meteorite_fragment_from_the_Cañon_Diablo_Meteorite.jpg, Meteorite fragment from the Cañon Diablo Meteorite 90mm wide
File:Gibeon Meteorite.jpg, The Gibeon meteorite: Year found: 1836, Country: Namibia, individual weighing 3986 grams. This specimen is in the private collection of Howardite meteorites.
File:Murnpeowie meteorite.jpg, The Murnpeowie meteorite, with regmaglypts resembling thumbprints, discovered on Murnpeowie Station, South Australia
South Australia (commonly abbreviated as SA) is a States and territories of Australia, state in the southern central part of Australia. With a total land area of , it is the fourth-largest of Australia's states and territories by area, which in ...
in 1910.
File:Iron meteorite, 5cm, 77gm.jpg, Iron meteorite, 5 cm long, weighing 77 grams
See also
*
Glossary of meteoritics
*
Hraschina meteorite
*
Meteoritics
Notes
References
External links
Meteorite articles, including discussions of iron meteorites, in Planetary Science Research Discoveriesfrom Meteorites Australia
{{DEFAULTSORT:Iron Meteorite