Ion Pump
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An ion pump (also referred to as a sputter ion pump) is a type of
vacuum pump A vacuum pump is a type of pump device that draws gas particles from a sealed volume in order to leave behind a partial vacuum. The first vacuum pump was invented in 1650 by Otto von Guericke, and was preceded by the suction pump, which dates to ...
which operates by
sputtering In physics, sputtering is a phenomenon in which microscopic particles of a solid material are ejected from its surface, after the material is itself bombarded by energetic particles of a plasma or gas. It occurs naturally in outer space, and c ...
a metal
getter A getter is a deposit of reactive material that is placed inside a vacuum system to complete and maintain the vacuum. When gas molecules strike the getter material, they combine with it chemically or by adsorption. Thus the getter removes small ...
. Under ideal conditions, ion pumps are capable of reaching pressures as low as 10−11 mbar. An ion pump first ionizes gas within the vessel it is attached to and employs a strong electrical potential, typically 3–7 kV, which accelerates the ions into a solid electrode. Small bits of the electrode are sputtered into the chamber. Gasses are trapped by a combination of chemical reactions with the surface of the highly-reactive sputtered material, and being physically trapped underneath that material.


History

The first evidence for pumping from electrical discharge was found 1858 by
Julius Plücker Julius Plücker (16 June 1801 – 22 May 1868) was a German mathematician and physicist. He made fundamental contributions to the field of analytical geometry and was a pioneer in the investigations of cathode rays that led eventually to the di ...
, who did early experiments on electrical discharge in vacuum tubes. In 1937,
Frans Michel Penning Frans Michel Penning (12 September 1894 – 6 December 1953) was a Dutch experimental physicist. He received his PhD from the University of Leiden in 1923, and studied low pressure gas discharges at the Philips Laboratory in Eindhoven, developing ...
observed some evidence of pumping in the operation of his cold cathode gauge. These early effects were comparatively slow to pump, and were therefore not commercialized. A major advance came in the 1950s, when
Varian Associates Varian Associates was one of the first high-tech companies in Silicon Valley. It was founded in 1948 by Russell H. and Sigurd F. Varian, William Webster Hansen, and Edward Ginzton to sell the klystron, the first vacuum tube which could amp ...
were researching improvements for the performance of
vacuum tube A vacuum tube, electron tube, thermionic valve (British usage), or tube (North America) is a device that controls electric current flow in a high vacuum between electrodes to which an electric voltage, potential difference has been applied. It ...
s, particularly on improving the vacuum inside the
klystron A klystron is a specialized linear-beam vacuum tube, invented in 1937 by American electrical engineers Russell and Sigurd Varian,Pond, Norman H. "The Tube Guys". Russ Cochran, 2008 p.31-40 which is used as an amplifier for high radio frequenci ...
. In 1957, Lewis D Hall, John C Helmer, and Robert L Jepsen filed a patent for a significantly improved pump, one of the earliest pumps that could get a vacuum chamber to
ultra-high vacuum Ultra-high vacuum (often spelled ultrahigh in American English, UHV) is the vacuum regime characterised by pressures lower than about . UHV conditions are created by pumping the gas out of a UHV chamber. At these low pressures the mean free path of ...
pressures.


Working principle

The basic element of the common ion pump is a
Penning trap A Penning trap is a device for the storage of charged particles using a homogeneous magnetic field and a quadrupole electric field. It is mostly found in the physical sciences and related fields of study for precision measurements of properties o ...
. A swirling cloud of
electron The electron (, or in nuclear reactions) is a subatomic particle with a negative one elementary charge, elementary electric charge. It is a fundamental particle that comprises the ordinary matter that makes up the universe, along with up qua ...
s produced by an electric discharge is temporarily stored in the anode region of a Penning trap. These electrons ionize incoming gas atoms and molecules. The resultant swirling ions are accelerated to strike a chemically active cathode (usually titanium). On impact the accelerated ions will either become buried within the cathode or sputter cathode material onto the walls of the pump. The freshly sputtered chemically active cathode material acts as a
getter A getter is a deposit of reactive material that is placed inside a vacuum system to complete and maintain the vacuum. When gas molecules strike the getter material, they combine with it chemically or by adsorption. Thus the getter removes small ...
that then evacuates the gas by both chemisorption and
physisorption Physisorption, also called physical adsorption, is a process in which the electronic structure of the atom or molecule is barely wikt:perturb, perturbed upon adsorption. Overview The fundamental interacting force of physisorption is Van der Waals ...
resulting in a net pumping action. Inert and lighter gases, such as He and H2 tend not to sputter and are absorbed by
physisorption Physisorption, also called physical adsorption, is a process in which the electronic structure of the atom or molecule is barely wikt:perturb, perturbed upon adsorption. Overview The fundamental interacting force of physisorption is Van der Waals ...
. Some fraction of the energetic gas ions (including gas that is not chemically active with the cathode material) can strike the cathode and acquire an electron from the surface, neutralizing it as it rebounds. These rebounding energetic neutrals are buried in exposed pump surfaces. Both the pumping rate and capacity of such capture methods are dependent on the specific gas species being collected and the cathode material absorbing it. Some species, such as carbon monoxide, will chemically bind to the surface of a cathode material. Others, such as hydrogen, will diffuse into the metallic structure. In the former example, the pump rate can drop as the cathode material becomes coated. In the latter, the rate remains fixed by the rate at which the hydrogen diffuses.


Types

There are three main types of ion pumps: the conventional or standard diode pump, the noble diode pump and the triode pump.The pumping of helium and hydrogen by sputter- ion pumps part II
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Standard diode pump

A ''standard diode pump'' is a type of ion pump employed in high vacuum processes which contains only chemically active cathodes, in contrast to noble diode pumps. Two sub-types may be distinguished: the sputter ion pumps and the orbitron ion pumps.


Sputter ion pump

In the sputter ion pumps, one or more hollow anodes are placed between two cathode plates, with an intense magnetic field parallel to the axis of the anodes in order to augment the path of the electrons in the anode cells.


Orbitron ion pump

In the orbitron vacuum pumps, electrons are caused to travel in spiral orbits between a central anode, normally in the form of a cylindrical wire or rod, and an outer or boundary cathode, generally in the form of a cylindrical wall or cage. The orbiting of the electrons is achieved without the use of a magnetic field, even though a weak axial magnetic field may be employed.


Noble diode pump

A ''noble diode pump'' is a type of ion pump used in high-
vacuum A vacuum (: vacuums or vacua) is space devoid of matter. The word is derived from the Latin adjective (neuter ) meaning "vacant" or "void". An approximation to such vacuum is a region with a gaseous pressure much less than atmospheric pressur ...
applications that employs both a chemically reactive
cathode A cathode is the electrode from which a conventional current leaves a polarized electrical device such as a lead-acid battery. This definition can be recalled by using the mnemonic ''CCD'' for ''Cathode Current Departs''. Conventional curren ...
, such as
titanium Titanium is a chemical element; it has symbol Ti and atomic number 22. Found in nature only as an oxide, it can be reduced to produce a lustrous transition metal with a silver color, low density, and high strength, resistant to corrosion in ...
, and an additional
cathode A cathode is the electrode from which a conventional current leaves a polarized electrical device such as a lead-acid battery. This definition can be recalled by using the mnemonic ''CCD'' for ''Cathode Current Departs''. Conventional curren ...
composed of
tantalum Tantalum is a chemical element; it has Symbol (chemistry), symbol Ta and atomic number 73. It is named after Tantalus, a figure in Greek mythology. Tantalum is a very hard, ductility, ductile, lustre (mineralogy), lustrous, blue-gray transition ...
. The tantalum cathode serves as a high-inertia crystal lattice structure for the reflection and burial of neutrals, increasing pumping effectiveness of inert gas ions. Pumping intermittently high quantities of hydrogen with noble diodes should be done with great care, as hydrogen might over months get re-emitted out of the tantalum.


Applications

Ion pumps are commonly used in
ultra-high vacuum Ultra-high vacuum (often spelled ultrahigh in American English, UHV) is the vacuum regime characterised by pressures lower than about . UHV conditions are created by pumping the gas out of a UHV chamber. At these low pressures the mean free path of ...
(UHV) systems, as they can attain ultimate pressures less than 10−11 mbar. In contrast to other common UHV pumps, such as
turbomolecular pump A turbomolecular pump is a type of vacuum pump, superficially similar to a turbopump, used to obtain and maintain high vacuum. These pumps work on the principle that gas molecules can be given momentum in a desired direction by repeated collis ...
s and
diffusion pump Diffusion pumps use a high speed jet of vapor to direct gas molecules in the pump throat down into the bottom of the pump and out the exhaust. They were the first type of high vacuum pumps operating in the regime of free molecular flow, where the ...
s, ion pumps have no moving parts and use no oil. They are therefore clean, need little maintenance, and produce no vibrations. These advantages make ion pumps well-suited for use in
scanning probe microscopy Scanning probe microscopy (SPM) is a branch of microscopy that forms images of surfaces using a physical probe that scans the specimen. SPM was founded in 1981, with the invention of the scanning tunneling microscope, an instrument for imaging ...
, molecular beam epitaxy and other high-precision apparatuses.


Radicals

Recent work has suggested that
free radicals In chemistry, a radical, also known as a free radical, is an atom, molecule, or ion that has at least one unpaired electron, unpaired valence electron. With some exceptions, these unpaired electrons make radicals highly chemical reaction, chemi ...
escaping from ion pumps can influence the results of some experiments.


See also

* Electroosmotic flow * Marklund convection


References


Sources

* * *


External links


An Introduction to Ion Pumps
{{DEFAULTSORT:Ion Pump (Physics) Vacuum pumps