
An imaging spectrometer is an instrument used in
hyperspectral imaging
Hyperspectral imaging collects and processes information from across the electromagnetic spectrum. The goal of hyperspectral imaging is to obtain the spectrum for each pixel in the image of a scene, with the purpose of finding objects, identifyi ...
and imaging spectroscopy to acquire a spectrally-resolved image of an object or scene, usually to support analysis of the composition the object being imaged.
The spectral data produced for a pixel is often referred to as a
datacube due to the three-dimensional representation of the data. Two axes of the image correspond to vertical and horizontal distance and the third to
wavelength
In physics and mathematics, wavelength or spatial period of a wave or periodic function is the distance over which the wave's shape repeats.
In other words, it is the distance between consecutive corresponding points of the same ''phase (waves ...
. The principle of operation is the same as that of the simple
spectrometer
A spectrometer () is a scientific instrument used to separate and measure Spectrum, spectral components of a physical phenomenon. Spectrometer is a broad term often used to describe instruments that measure a continuous variable of a phenomeno ...
, but special care is taken to avoid
optical aberration
In optics, aberration is a property of optical systems, such as Lens (optics), lenses and mirrors, that causes the ''image'' created by the optical system to not be a faithful reproduction of the ''object'' being observed. Aberrations cause the i ...
s for better image quality.
Example imaging spectrometer types include: filtered camera,
whiskbroom scanner,
pushbroom scanner,
integral field spectrograph
Integral field spectrographs (IFS) combine spectrographic and imaging capabilities in the optical or infrared wavelength domains (0.32 μm – 24 μm) to get from a single exposure spatially resolved Spectrum, spectra in a bi-dimensional region. T ...
(or related dimensional reformatting techniques), wedge imaging spectrometer, Fourier transform imaging spectrometer,
computed tomography imaging spectrometer
The computed tomography imaging spectrometer (CTIS) is a snapshot hyperspectral imaging, snapshot imaging spectrometer which can produce ''in fine'' the three-dimensional (i.e. spatial and spectral) Hyperspectral imaging, hyperspectral datacube of ...
(CTIS), image replicating imaging spectrometer (IRIS), coded aperture snapshot spectral imager (CASSI), and
image mapping spectrometer (IMS).
Background
In 1704,
Sir Isaac Newton
Sir Isaac Newton () was an English polymath active as a mathematician, physicist, astronomer, alchemist, theologian, and author. Newton was a key figure in the Scientific Revolution and the Enlightenment that followed. His book (''Mathe ...
demonstrated that white light could be split up into component colours. The subsequent
history of spectroscopy
Modern spectroscopy in the Western world started in the 17th century. New designs in optics, specifically prisms, enabled systematic observations of the solar spectrum. Isaac Newton first applied the word ''spectrum'' to describe the rainbow of c ...
led to precise measurements and provided the empirical foundations for atomic and
molecular physics
Molecular physics is the study of the physical properties of molecules and molecular dynamics. The field overlaps significantly with physical chemistry, chemical physics, and quantum chemistry. It is often considered as a sub-field of atomic, mo ...
(Born & Wolf, 1999). Significant achievements in imaging spectroscopy are attributed to airborne instruments, particularly arising in the early 1980s and 1990s (Goetz et al., 1985; Vane et al., 1984). However, it was not until 1999 that the first imaging spectrometer was launched in space (the
NASA Moderate-resolution Imaging Spectroradiometer, or MODIS).
Terminology and definitions evolve over time. At one time, >10 spectral bands sufficed to justify the term ''imaging spectrometer'' but presently the term is seldom defined by a total minimum number of spectral bands, rather by a contiguous (or redundant) statement of
spectral bands
Spectral bands are regions of a given spectrum, having a specific range of wavelengths or frequencies. Most often, it refers to electromagnetic bands, regions of the electromagnetic spectrum.
More generally, spectral bands may also be means in ...
.
Principle
Imaging spectrometers are used specifically for the purpose of measuring the spectral content of light and electromagnetic light. The spectral data gathered is used to give the operator insight into the sources of radiation. Prism spectrometers use a classical method of dispersing radiation by means of a prism as a refracting element.
The imaging spectrometer works by imaging a
radiation
In physics, radiation is the emission or transmission of energy in the form of waves or particles through space or a material medium. This includes:
* ''electromagnetic radiation'' consisting of photons, such as radio waves, microwaves, infr ...
source onto what is called a "slit" by means of a source imager. A collimator collimates the beam that is dispersed by a refracting prism and re-imaged onto a detection system by a re-imager. Special care is taken to produce the best possible image of the source onto the slit. The purpose of the collimator and re-imaging optics are to take the best possible image of the slit. An area-array of elements fills the detection system at this stage. The source image is reimaged, every point, as a line spectrum on what is called a detector-array column. The detector array signals supply data pertaining to spectral content, in particular, spatially resolved source points inside source area. These source points are imaged onto the slit and then re-imaged onto the detector array. Simultaneously, the system provides spectral information about the source area and its line of spatially resolved points. The line is then scanned in order to build a database of information about the spectral content.
In imaging spectroscopy (also
hyperspectral imaging
Hyperspectral imaging collects and processes information from across the electromagnetic spectrum. The goal of hyperspectral imaging is to obtain the spectrum for each pixel in the image of a scene, with the purpose of finding objects, identifyi ...
or
spectral imaging
Spectral imaging is imaging that uses multiple bands across the electromagnetic spectrum. While an ordinary camera captures light across three wavelength bands in the visible spectrum, red, green, and blue (RGB), spectral imaging encompasses a ...
) each
pixel
In digital imaging, a pixel (abbreviated px), pel, or picture element is the smallest addressable element in a Raster graphics, raster image, or the smallest addressable element in a dot matrix display device. In most digital display devices, p ...
of an image acquires many bands of light intensity data from the spectrum, instead of just the three bands of the
RGB color model
The RGB color model is an additive color, additive color model in which the red, green, and blue primary colors of light are added together in various ways to reproduce a broad array of colors. The name of the model comes from the initials ...
. More precisely, it is the simultaneous acquisition of spatially
coregistered images in many
spectrally contiguous
bands Bands may refer to:
* Bands (song), song by American rapper Comethazine
* Bands (neckwear), form of formal neckwear
* Bands (Italian Army irregulars)
Bands () was an Italian military term for Irregular military, irregular forces, composed of nati ...
.
Some spectral images contain only a few
image plane
In 3D computer graphics, the image plane is that plane in the world which is identified with the plane of the display monitor used to view the image that is being rendered. It is also referred to as screen space. If one makes the analogy of taki ...
s of a spectral
data cube
In computer programming contexts, a data cube (or datacube) is a multi-dimensional ("n-D") array of values. Typically, the term data cube is applied in contexts where these arrays are massively larger than the hosting computer's main memory; exa ...
, while others are better thought of as full spectra at every location in the image. For example,
solar physicist
Solar physics is the branch of astrophysics that specializes in the study of the Sun. It intersects with many disciplines of pure physics and astrophysics.
Because the Sun is uniquely situated for close-range observing (other stars cannot be reso ...
s use the
spectroheliograph
The spectroheliograph is an instrument used in astronomy which captures a photography, photographic image of the Sun at a single wavelength of light, a monochromatic image. The wavelength is usually chosen to coincide with a optical spectrum, spec ...
to make images of the
Sun
The Sun is the star at the centre of the Solar System. It is a massive, nearly perfect sphere of hot plasma, heated to incandescence by nuclear fusion reactions in its core, radiating the energy from its surface mainly as visible light a ...
built up by scanning the slit of a spectrograph, to study the behavior of surface features on the Sun; such a spectroheliogram may have a
spectral resolution
The spectral resolution of a spectrograph, or, more generally, of a frequency spectrum, is a measure of its ability to resolve features in the electromagnetic spectrum. It is usually denoted by \Delta\lambda, and is closely related to the resolvi ...
of over 100,000 (
) and be used to measure local motion (via the
Doppler shift
The Doppler effect (also Doppler shift) is the change in the frequency of a wave in relation to an observer who is moving relative to the source of the wave. The ''Doppler effect'' is named after the physicist Christian Doppler, who described t ...
) and even the
magnetic field
A magnetic field (sometimes called B-field) is a physical field that describes the magnetic influence on moving electric charges, electric currents, and magnetic materials. A moving charge in a magnetic field experiences a force perpendicular ...
(via the
Zeeman splitting
The Zeeman effect () is the splitting of a spectral line into several components in the presence of a static magnetic field. It is caused by the interaction of the magnetic field with the magnetic moment of the atomic electron associated with ...
or
Hanle effect The Hanle effect, also known as zero-field level crossing, is a reduction in the polarization of light when the atoms emitting the light are subject to a magnetic field in a particular direction, and when they have themselves been excited by polariz ...
) at each location in the image plane. The
multispectral image
Multispectral imaging captures image data within specific wavelength ranges across the electromagnetic spectrum. The wavelengths may be separated by filters or detected with the use of instruments that are sensitive to particular wavelengths, ...
s collected by the
Opportunity rover
''Opportunity'', also known as MER-B (Mars Exploration Rover – B) or MER-1, and nicknamed Oppy, is a Robotics, robotic rover (space exploration), rover that was active on Mars from 2004 until 2018. ''Opportunity'' was operational on Mars for ...
, in contrast, have only four wavelength bands and hence are only a little more than
3-color images.
Unmixing
Hyperspectral data is often used to determine what materials are present in a scene. Materials of interest could include roadways, vegetation, and specific targets (i.e. pollutants, hazardous materials, etc.). Trivially, each pixel of a hyperspectral image could be compared to a material database to determine the type of material making up the pixel. However, many hyperspectral imaging platforms have low resolution (>5m per pixel) causing each pixel to be a mixture of several materials. The process of unmixing one of these 'mixed' pixels is called hyperspectral image unmixing or simply hyperspectral unmixing.
A solution to hyperspectral unmixing is to reverse the mixing process. Generally, two models of mixing are assumed: linear and nonlinear.
Linear mixing models the ground as being flat and incident sunlight on the ground causes the materials to radiate some amount of the incident energy back to the sensor. Each pixel then, is modeled as a linear sum of all the radiated energy curves of materials making up the pixel. Therefore, each material contributes to the sensor's observation in a positive linear fashion. Additionally, a conservation of energy constraint is often observed thereby forcing the weights of the linear mixture to sum to one in addition to being positive. The model can be described mathematically as follows:
:
where
represents a pixel observed by the sensor,
is a matrix of material reflectance signatures (each signature is a column of the matrix), and
is the proportion of material present in the observed pixel. This type of model is also referred to as a
simplex
In geometry, a simplex (plural: simplexes or simplices) is a generalization of the notion of a triangle or tetrahedron to arbitrary dimensions. The simplex is so-named because it represents the simplest possible polytope in any given dimension. ...
.
With
satisfying the two constraints:
1. Abundance Nonnegativity Constraint (ANC) - each element of x is positive.
2. Abundance Sum-to-one Constraint (ASC) - the elements of x must sum to one.
Non-linear mixing results from multiple scattering often due to non-flat surface such as buildings and vegetation.
There are many algorithms to unmix hyperspectral data each with their own strengths and weaknesses. Many algorithms assume that pure pixels (pixels which contain only one materials) are present in a scene.
Some algorithms to perform unmixing are listed below:
* Pixel Purity Index Works by projecting each pixel onto one vector from a set of random vectors spanning the reflectance space. A pixel receives a score when it represent an extremum of all the projections. Pixels with the highest scores are deemed to be spectrally pure.
* N-FINDR
* Gift Wrapping Algorithm
* Independent Component Analysis Endmember Extraction Algorithm - works by assuming that pure pixels occur independently than mixed pixels. Assumes pure pixels are present.
* Vertex Component Analysis - works on the fact that the affine transformation of a simplex is another simplex which helps to find hidden (folded) vertices of the simplex. Assumes pure pixels are present.
* Principal component analysis - could also be used to determine endmembers, projection on principal axes could permit endmember selection
mith, Johnson et Adams (1985), Bateson et Curtiss (1996)* Multi endmembers spatial mixture analysis based on the SMA algorithm
* Spectral phasor analysis based on Fourier transformation of spectra and plotting them on a 2D plot.
Non-linear unmixing algorithms also exist:
support vector machine
In machine learning, support vector machines (SVMs, also support vector networks) are supervised max-margin models with associated learning algorithms that analyze data for classification and regression analysis. Developed at AT&T Bell Laborato ...
s or analytical neural network.
Probabilistic method
In mathematics, the probabilistic method is a nonconstructive method, primarily used in combinatorics and pioneered by Paul Erdős, for proving the existence of a prescribed kind of mathematical object. It works by showing that if one randomly c ...
s have also been attempted to unmix pixel through
Monte Carlo
Monte Carlo ( ; ; or colloquially ; , ; ) is an official administrative area of Monaco, specifically the Ward (country subdivision), ward of Monte Carlo/Spélugues, where the Monte Carlo Casino is located. Informally, the name also refers to ...
unmixing algorithm.
Once the fundamental materials of a scene are determined, it is often useful to construct an abundance map of each material which displays the fractional amount of material present at each pixel. Often
linear programming
Linear programming (LP), also called linear optimization, is a method to achieve the best outcome (such as maximum profit or lowest cost) in a mathematical model whose requirements and objective are represented by linear function#As a polynomia ...
is done to observed ANC and ASC.
Applications
Planetary observations
The practical application of imaging spectrometers is they are used to observe the planet Earth from orbiting satellites. The spectrometer functions by recording all points of color on a picture, thus, the spectrometer is focused on specific parts of the Earth's surface to record data. The advantages of spectral content data include vegetation identification, physical condition analysis, mineral identification for the purpose of potential mining, and the assessment of polluted waters in oceans, coastal zones and inland waterways.
Prism spectrometers are ideal for Earth observation because they measure wide spectral ranges competently. Spectrometers can be set to cover a range from 400 nm to 2,500 nm, which interests scientists who are able to observe Earth by means of aircraft and satellite. The spectral resolution of the prism spectrometer is not desirable for most scientific applications; thus, its purpose is specific to recording spectral content of areas with greater spatial variations.
Venus express
''Venus Express'' (VEX) was the first Venus exploration mission of the European Space Agency (ESA). Launched in November 2005, it arrived at Venus in April 2006 and began continuously sending back science data from its polar orbit around Venus. ...
, orbiting Venus, had a number of imaging spectrometers covering NIR-vis-UV.
Geophysical imaging
One application is spectral
geophysical imaging
Geophysical imaging (also known as geophysical tomography) is a minimally destructive geophysical technique that investigates the subsurface of a terrestrial planet. Geophysical imaging is a noninvasive imaging technique with a high parametrical ...
, which allows quantitative and qualitative characterization of the surface and of the
atmosphere
An atmosphere () is a layer of gases that envelop an astronomical object, held in place by the gravity of the object. A planet retains an atmosphere when the gravity is great and the temperature of the atmosphere is low. A stellar atmosph ...
, using
radiometric
Radiometry is a set of techniques for measuring electromagnetic radiation, including visible light. Radiometric techniques in optics characterize the distribution of the radiation's power in space, as opposed to photometric techniques, which ch ...
measurements. These measurements can then be used for unambiguous direct and indirect identification of surface materials and atmospheric trace gases, the measurement of their relative concentrations, subsequently the assignment of the proportional contribution of mixed pixel signals (e.g., the spectral unmixing problem), the derivation of their spatial distribution (mapping problem), and finally their study over time (multi-temporal analysis). The
Moon Mineralogy Mapper
The Moon Mineralogy Mapper (M3) is one of two instruments of NASA that was carried by India's first mission to the Moon, Chandrayaan-1, launched October 22, 2008. It is an imaging spectrometer, and the team is led by Principal investigator Carle ...
on
Chandrayaan-1
Chandrayaan-1 (; from Sanskrit: , "Moon" and , "craft, vehicle") was the first Indian lunar probe under the Chandrayaan programme. It was launched by the Indian Space Research Organisation (ISRO) in October 2008, and operated until August 200 ...
was a geophysical imaging spectrometer.
Disadvantages
The lenses of the prism
spectrometer
A spectrometer () is a scientific instrument used to separate and measure Spectrum, spectral components of a physical phenomenon. Spectrometer is a broad term often used to describe instruments that measure a continuous variable of a phenomeno ...
are used for both collimation and re-imaging; however, the imaging spectrometer is limited in its performance by the image quality provided by the collimators and re-imagers. The resolution of the slit image at each wavelength limits spatial resolution; likewise, the resolution of optics across the slit image at each wavelength limits spectral resolution. Moreover, distortion of the slit image at each wavelength can complicate the interpretation of the spectral data.
The refracting lenses used in the imaging spectrometer limit performance by the axial chromatic aberrations of the lens. These chromatic aberrations are bad because they create differences in focus, which prevent good resolution; however, if the range is restricted it is possible to achieve good resolution. Furthermore, chromatic aberrations can be corrected by using two or more refracting materials over the full visible range. It is harder to correct chromatic aberrations over wider spectral ranges without further optical complexity.
Systems
Spectrometers intended for very wide spectral ranges are best if made with all-mirror systems. These particular systems have no chromatic aberrations, and that is why they are preferable. On the other hand, spectrometers with single point or linear array detection systems require simpler mirror systems. Spectrometers using area-array detectors need more complex mirror systems to provide good resolution. It is conceivable that a
collimator
A collimator is a device which narrows a beam of particles or waves. To narrow can mean either to cause the directions of motion to become more aligned in a specific direction (i.e., make collimated light or parallel rays), or to cause the spat ...
could be made that would prevent all aberrations; however, this design is expensive because it requires the use of aspherical mirrors.
Smaller two-mirror systems can correct aberrations, but they are not suited for imaging spectrometers. Three mirror systems are compact and correct aberrations as well, but they require at least two asperical components. Systems with more than four mirrors tend to be large and a lot more complex. Catadioptric systems are used in Imagine Spectrometers and are compact, too; however, the collimator or imager will be made up of two curved mirrors and three refracting elements, and thus, the system is very complex.
Optical
Optics is the branch of physics that studies the behaviour and properties of light, including its interactions with matter and the construction of instruments that use or detect it. Optics usually describes the behaviour of visible, ultravio ...
complexity is unfavorable, however, because effects scatter all optical surfaces and stray reflections. Scattered radiation can interfere with the detector by entering into it and causing errors in recorded spectra. Stray radiation is referred to as
stray light
Stray light is light in an optical system which was not intended in the design. The light may be from the intended source, but follow paths other than intended, or it may be from a source other than that intended. This light will often set a worki ...
. By limiting the total number of surfaces that can contribute to scatter, it limits the introduction of stray light into the equation.
Imaging spectrometers are meant to produce well resolved images. In order for this to occur, imaging spectrometers need to be made with few optical surfaces and have no aspherical optical surfaces.
Sensors
Planned:
*
EnMAP
Current and Past:
*
AVIRIS — airborne
*
MODIS
The Moderate Resolution Imaging Spectroradiometer (MODIS) is a satellite-based sensor used for earth and climate measurements. There are two MODIS sensors in Earth orbit: one on board the Terra (EOS AM) satellite, launched by NASA in 19 ...
— on board
EOS
In ancient Greek mythology and Ancient Greek religion, religion, Eos (; Ionic Greek, Ionic and Homeric Greek ''Ēṓs'', Attic Greek, Attic ''Héōs'', "dawn", or ; Aeolic Greek, Aeolic ''Aúōs'', Doric Greek, Doric ''Āṓs'') is the go ...
Terra
Terra may often refer to:
* Terra (mythology), primeval Roman goddess
* An alternate name for planet Earth, as well as the Latin name for the planet
Terra may also refer to: Geography Astronomy
* Terra (satellite), a multi-national NASA scient ...
and
Aqua
Aqua is the Latin word for water. As such, it is often used in many words which relate to water, such as aquatic life. In English, it may also refer to:
Arts
* Aqua (color), a greenish-blue color
Business
* Aqua (Chicago), an 82-story resid ...
platforms
*
MERIS MEdium Resolution Imaging Spectrometer (MERIS) was one of the main instruments on board the European Space Agency (ESA)'s Envisat platform. The sensor was in orbit from 2002 to 2012. ESA formally announced the end of Envisat's mission on 9 May 2012. ...
— on board
Envisat
Envisat ("Environmental Satellite") is a large Earth-observing satellite which has been inactive since 2012. It is still in orbit and considered space debris. Operated by the European Space Agency (ESA), it was the world's largest civilian Ear ...
*Hyperion — on board
Earth Observing-1
Earth Observing-1 (EO-1) was a NASA Earth observation satellite created to develop and validate a number of instrument and spacecraft bus breakthrough technologies. It was intended to enable the development of future Earth imaging observatories t ...
*Several commercial manufacturers for laboratory, ground-based, aerial, or industrial imaging spectrographs
Examples
*
Ralph (New Horizons)
Ralph is a science instrument aboard the robotic ''New Horizons'' spacecraft, which was launched in 2006. Ralph is a visible and infrared imager and spectrometer to provide maps of relevant astronomical targets based on data from that hardware. Ra ...
, Visible and ultraviolet imaging spectrometer on
New Horizons
''New Horizons'' is an Interplanetary spaceflight, interplanetary space probe launched as a part of NASA's New Frontiers program. Engineered by the Johns Hopkins University Applied Physics Laboratory (APL) and the Southwest Research Institut ...
*
Jovian Infrared Auroral Mapper
Jovian Infrared Auroral Mapper (JIRAM) is an instrument on the Juno (spacecraft), ''Juno'' spacecraft in orbit of the planet Jupiter. It is an image spectrometer and was contributed by Italy. Similar instruments are on ESA ''Rosetta (spacecraft) ...
, infrared imaging spectrometer on
Juno Jupiter orbiter
*
Mapping Imaging Spectrometer for Europa (planned for developmental
Europa Clipper
Europa Clipper (previously known as Europa Multiple Flyby Mission) is a space probe developed by NASA to study Europa (moon), Europa, a Galilean moon of Jupiter. It was launched on October 14, 2024. The spacecraft used a gravity assist from Mar ...
spacecraft
*
Compact Reconnaissance Imaging Spectrometer for Mars (CRISM), imaging spectrometer in Mars orbit aboard Mars Reconnaissance Orbiter
*
Special Sensor Ultraviolet Limb Imager, to observe the earth's ionosphere and thermosphere
See also
*
Landsat
The Landsat program is the longest-running enterprise for acquisition of satellite imagery of Earth. It is a joint NASA / USGS program. On 23 July 1972, the Earth Resources Technology Satellite was launched. This was eventually renamed to Lan ...
*
Remote sensing
Remote sensing is the acquisition of information about an physical object, object or phenomenon without making physical contact with the object, in contrast to in situ or on-site observation. The term is applied especially to acquiring inform ...
*
Hyperspectral imaging
Hyperspectral imaging collects and processes information from across the electromagnetic spectrum. The goal of hyperspectral imaging is to obtain the spectrum for each pixel in the image of a scene, with the purpose of finding objects, identifyi ...
*
Full Spectral Imaging
*
List of Earth observation satellites
Earth observation satellites are Earth-orbiting spacecraft with sensors used to collect imagery and measurements of the surface of the earth. These satellites are used to monitor short-term weather, long-term climate change, natural disasters ...
*
Chemical Imaging
Chemical imaging (as quantitative – ''chemical mapping'') is the analytical capability to create a visual image of components distribution from simultaneous measurement of spectra and spatial, time information. Hyperspectral imaging measures con ...
*
Infrared Microscopy
Microscopy is the technical field of using microscopes to view subjects too small to be seen with the naked eye (objects that are not within the resolution range of the normal eye). There are three well-known branches of microscopy: optical, el ...
*
Phasor approach to fluorescence lifetime and spectral imaging
*
Video spectroscopy
References
Further readling
* Goetz, A.F.H., Vane, G., Solomon, J.E., & Rock, B.N. (1985) Imaging spectrometry for earth remote sensing. Science, 228, 1147.
* Schaepman, M. (2005) Spectrodirectional Imaging: From Pixels to Processes. Inaugural address, Wageningen University, Wageningen (NL).
* Vane, G., Chrisp, M., Emmark, H., Macenka, S., & Solomon, J. (1984) Airborne Visible Infrared Imaging Spec-trometer (
AVIRIS): An Advanced Tool for Earth Remote Sensing. European Space Agency, (Special Publication) ESA SP, 2, 751.
External links
List of imaging spectrometer instruments* About imaging spectroscopy (USGS): http://speclab.cr.usgs.gov/aboutimsp.html
* Link to resources (OKSI): http://www.techexpo.com/WWW/opto-knowledge/IS_resources.html
* Special Interest Group Imaging Spectroscopy (EARSeL): https://web.archive.org/web/20051230225147/http://www.op.dlr.de/dais/SIG-IS/SIG-IS.html
* Applications of Spectroscopic and Chemical Imaging in Research: http://www3.imperial.ac.uk/vibrationalspectroscopyandchemicalimaging/research
* Analysis tool for spectral unmixing : http://www.spechron.com
{{Satellite and spacecraft instruments
Image sensors
Spectrometers