Hydrogarnet
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Hydrogrossular is a
calcium Calcium is a chemical element; it has symbol Ca and atomic number 20. As an alkaline earth metal, calcium is a reactive metal that forms a dark oxide-nitride layer when exposed to air. Its physical and chemical properties are most similar to it ...
aluminium Aluminium (or aluminum in North American English) is a chemical element; it has chemical symbol, symbol Al and atomic number 13. It has a density lower than that of other common metals, about one-third that of steel. Aluminium has ...
garnet Garnets () are a group of silicate minerals that have been used since the Bronze Age as gemstones and abrasives. Garnet minerals, while sharing similar physical and crystallographic properties, exhibit a wide range of chemical compositions, de ...
series (formula: Ca3Al2(SiO4)3−''x''(OH)4''x'', with hydroxide (OH) partially replacing silica (SiO4)). The endmembers of the hydrogarnet family (
grossular Grossular is a calcium-aluminium species of the garnet group of minerals. It has the chemical formula of Ca3Al2(SiO4)3 but the calcium may, in part, be replaced by ferrous iron and the aluminium by ferric iron. The name grossular is derived from ...
, hibschite, and katoite) depend on the degree of substitution (''x''): * grossular: ''x'' = 0 * hibschite: 0.2 < ''x'' < 1.5 * katoite: 1.5 < ''x'' < 3. Hydrogrossular is a garnet variety in which a Si4+ is missing from a tetrahedral site. Charge balance is maintained by bonding a H+ to each of the four oxygens surrounding the vacant site. Hydrogrossular is found in massive crystal habit, sometimes grown in with idocrase. Hydrogrossular is
translucent In the field of optics, transparency (also called pellucidity or diaphaneity) is the physical property of allowing light to pass through the material without appreciable light scattering by particles, scattering of light. On a macroscopic scale ...
to
opaque Opacity is the measure of impenetrability to electromagnetic or other kinds of radiation, especially visible light. In radiative transfer, it describes the absorption and scattering of radiation in a medium, such as a plasma, dielectric, shie ...
, and found in green to bluish green, pink, white, and gray. The cause of the green color is
chromium Chromium is a chemical element; it has Symbol (chemistry), symbol Cr and atomic number 24. It is the first element in Group 6 element, group 6. It is a steely-grey, Luster (mineralogy), lustrous, hard, and brittle transition metal. Chromium ...
, and possibly
iron Iron is a chemical element; it has symbol Fe () and atomic number 26. It is a metal that belongs to the first transition series and group 8 of the periodic table. It is, by mass, the most common element on Earth, forming much of Earth's o ...
. Pink hydrogrossular is caused by the presence of
manganese Manganese is a chemical element; it has Symbol (chemistry), symbol Mn and atomic number 25. It is a hard, brittle, silvery metal, often found in minerals in combination with iron. Manganese was first isolated in the 1770s. It is a transition m ...
. Hydrogrossular may have dark gray to black small inclusions. It has similarities to
jade Jade is an umbrella term for two different types of decorative rocks used for jewelry or Ornament (art), ornaments. Jade is often referred to by either of two different silicate mineral names: nephrite (a silicate of calcium and magnesium in t ...
, and has the
misnomer A misnomer is a name that is incorrectly or unsuitably applied. Misnomers often arise because something was named long before its correct nature was known, or because an earlier form of something has been replaced by a later form to which the nam ...
s ''Transvaal jade'', and ''African jade''. Hydrogrossular is sometimes used as a
gemstone A gemstone (also called a fine gem, jewel, precious stone, semiprecious stone, or simply gem) is a piece of mineral crystal which, when cut or polished, is used to make jewellery, jewelry or other adornments. Certain Rock (geology), rocks (such ...
, being
cabochon A cabochon (; ) is a gemstone that has been shaped and polished, as opposed to faceted. The resulting form is usually a convex (rounded) obverse with a flat reverse. Cabochon was the default method of preparing gemstones before gemstone cuttin ...
cut, or made into
bead A bead is a small, decorative object that is formed in a variety of shapes and sizes of a material such as stone, bone, shell, glass, plastic, wood, or pearl and with a small hole for threading or stringing. Beads range in size from under 1 ...
s. Sources for green and pink hydrogrossular are
South Africa South Africa, officially the Republic of South Africa (RSA), is the Southern Africa, southernmost country in Africa. Its Provinces of South Africa, nine provinces are bounded to the south by of coastline that stretches along the Atlantic O ...
,
Canada Canada is a country in North America. Its Provinces and territories of Canada, ten provinces and three territories extend from the Atlantic Ocean to the Pacific Ocean and northward into the Arctic Ocean, making it the world's List of coun ...
, and the
United States The United States of America (USA), also known as the United States (U.S.) or America, is a country primarily located in North America. It is a federal republic of 50 U.S. state, states and a federal capital district, Washington, D.C. The 48 ...
. White hydrogrossular is sourced from
Burma Myanmar, officially the Republic of the Union of Myanmar; and also referred to as Burma (the official English name until 1989), is a country in northwest Southeast Asia. It is the largest country by area in Mainland Southeast Asia and ha ...
and
China China, officially the People's Republic of China (PRC), is a country in East Asia. With population of China, a population exceeding 1.4 billion, it is the list of countries by population (United Nations), second-most populous country after ...
.


References


External links


Grossular-Hibschite Series on Mindat
Aluminium minerals Calcium minerals Cement Garnet gemstones {{silicate-mineral-stub