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Gum printing is a way of making photographic reproductions without the use of
silver halide A silver halide (or silver salt) is one of the chemical compounds that can form between the Chemical element, element silver (Ag) and one of the halogens. In particular, bromine (Br), chlorine (Cl), iodine (I) and fluorine (F) may each combine wit ...
s. The process uses salts of dichromate in common with a number of other related processes such as sun printing. Gum prints tend to be multi-layered images sometimes combined with other
alternative process The term alternative process refers to any non-traditional or non-commercial photographic printing process. Currently, the standard analog photographic printing process for black-and-white photographs is the gelatin silver process. Standard dig ...
printing methods such as
cyanotype The cyanotype (from , and , ) is a slow-reacting, photographic printing formulation sensitive to a limited near-ultraviolet and blue light spectrum, the range 300 nm to 400 nm known as UVA radiation. It produces a monochrome, blu ...
and
platinotype Platinum prints, also called ''platinotypes'', are photographic prints made by a monochrome photographic printing, printing process involving platinum. Platinum tones range from warm black, to reddish brown, to expanded mid-tone grays that are ...
. A heavy weight cotton watercolor or printmaking paper that can withstand repeated and extended soakings is best. Each layer of pigment is individually coated, registered, exposed and washed. Separation negatives of cyan, magenta, and yellow or red, green, and blue are used for a full-color image. Some photographers prefer substituting the cyan emulsion in the
CMYK The CMYK color model (also known as process color, or four color) is a subtractive color model, based on the CMY color model, used in color printing, and is also used to describe the printing process itself. The abbreviation ''CMYK'' refers ...
separations with a cyanotype layer. A simple duotone separation combining orange watercolor pigment and a cyanotype can yield surprisingly beautiful results.


History

Gum bichromate, or gum dichromate as it is also known, is a photographic printing process invented in the early days of photography when, in 1839, Mungo Ponton discovered that dichromates are light sensitive.
William Henry Fox Talbot William Henry Fox Talbot (; 11 February 180017 September 1877) was an English scientist, inventor, and photography pioneer who invented the Salt print, salted paper and calotype processes, precursors to photographic processes of the later 19th ...
later found that sensitized dichromated
colloids A colloid is a mixture in which one substance consisting of microscopically dispersed insoluble particles is suspended throughout another substance. Some definitions specify that the particles must be dispersed in a liquid, while others exten ...
such as
gelatin Gelatin or gelatine () is a translucent, colorless, flavorless food ingredient, commonly derived from collagen taken from animal body parts. It is brittle when dry and rubbery when moist. It may also be referred to as hydrolyzed collagen, coll ...
and
gum arabic Gum arabic (gum acacia, gum sudani, Senegal gum and by other names) () is a tree gum exuded by two species of '' Acacia sensu lato:'' '' Senegalia senegal,'' and '' Vachellia seyal.'' However, the term "gum arabic" does not indicate a partic ...
became insoluble in water after exposure to sunlight. Alphonse Poitevin added carbon pigment to the colloids in 1855, creating the first
carbon print A carbon print is a photographic print with an image consisting of pigmented gelatin, rather than of silver or other metallic particles suspended in a uniform layer of gelatin, as in typical black-and-white prints, or of chromogenic dyes, as in t ...
. In 1858, John Pouncy used colored pigment with gum arabic to create the first color images.


Gum printing

When mixtures of mucilaginous,
protein Proteins are large biomolecules and macromolecules that comprise one or more long chains of amino acid residue (biochemistry), residues. Proteins perform a vast array of functions within organisms, including Enzyme catalysis, catalysing metab ...
-containing materials together with soluble salts of dichromate are exposed to ultraviolet light, the protein content becomes tanned and resistant to solution in water. The untanned material can be washed away in warm water leaving a hardened, tanned protein negative. For gum printing a solution of
gum arabic Gum arabic (gum acacia, gum sudani, Senegal gum and by other names) () is a tree gum exuded by two species of '' Acacia sensu lato:'' '' Senegalia senegal,'' and '' Vachellia seyal.'' However, the term "gum arabic" does not indicate a partic ...
is mixed with either potassium or ammonium dichromate. The higher the proportion of dichromate, the more sensitive the mixture. However, increasing the concentration of dichromate also reduces the contrast which is very low at best. The right concentration of dichromate is always a compromise between speed and contrast. Using
ammonium dichromate Ammonium dichromate is an inorganic compound with the Chemical formula, formula (NH4)2Cr2O7. In this compound, as in all chromates and dichromates, chromium is in a +6 oxidation state, commonly known as hexavalent chromium. It is a salt consisting ...
allows concentrations up to 15% of the active ingredient whereas
potassium dichromate Potassium dichromate is the inorganic compound with the formula . An orange solid, it is used in diverse laboratory and industrial applications. As with all hexavalent chromium compounds, it is chronically harmful to health. It is a crystalline ...
is limited to about 10%. Exceeding these concentrations results in deposits of
chromic acid Chromic acid is a chemical compound with the chemical formula . It is also a jargon for a solution formed by the addition of sulfuric acid to aqueous solutions of dichromate. It consists at least in part of chromium trioxide. The term "chromic ...
in the dried film which ruins any attempts at printing. The greatest sensitivity expressed as an
ASA Asa may refer to: People and fictional characters * Asa (given name), a given name, including a list of people and fictional characters so named * Asa people, an ethnic group based in Tanzania * Aṣa, Nigerian-French singer, songwriter, and reco ...
speed rating is estimated to be about ASA 0.003. The resulting mucilaginous mixture is spread on a suitable base and allowed to dry in the dark. A contact negative the same size of the finished print is then placed on top of the dried coating and exposed to an
ultraviolet light Ultraviolet radiation, also known as simply UV, is electromagnetic radiation of wavelengths of 10–400 nanometers, shorter than that of visible light, but longer than X-rays. UV radiation is present in sunlight and constitutes about 10% of th ...
source, typically bright sunshine. Often more than one negative is used to provide detail in all tonal ranges. Using multiple exposures requires very careful registration. In exposing the paper, the thinnest parts of the negatives will allow the most exposure and cause the areas to be darker. The densest parts of the negative require more exposure. The exposed print is then developed gradually in a succession of trays of still water (approximately ten-minute intervals) at room temperature until the bath water is clear. The gum is soft and easily removed at this stage. The negative is then carefully dried until the negative image will be visible as raised areas of clear colourless gum. This surface can then be inked using proprietary oil-based printing ink and impressions made using a simple pressure printing press. Each negative can be made to yield several copies or even copies in different colours. However the fragile nature of the dried gum surface usually will restrict re-use to only one or two copies.


Gum bichromate

Gum bichromate is a 19th-century photographic printing process based on the light sensitivity of dichromates. It is capable of rendering painterly images from photographic negatives. Gum printing is traditionally a multi-layered printing process, but satisfactory results may be obtained from a single pass. Any color can be used for gum printing, so natural-color photographs are also possible by using this technique in layers.


Process overview

Gum bichromate, or gum dichromate as it is also known, is a photographic printing process invented in the early days of photography when, in 1839, Mungo Ponton discovered that dichromates are light sensitive.
William Henry Fox Talbot William Henry Fox Talbot (; 11 February 180017 September 1877) was an English scientist, inventor, and photography pioneer who invented the Salt print, salted paper and calotype processes, precursors to photographic processes of the later 19th ...
later found that sensitized dichromated
colloids A colloid is a mixture in which one substance consisting of microscopically dispersed insoluble particles is suspended throughout another substance. Some definitions specify that the particles must be dispersed in a liquid, while others exten ...
such as
gelatin Gelatin or gelatine () is a translucent, colorless, flavorless food ingredient, commonly derived from collagen taken from animal body parts. It is brittle when dry and rubbery when moist. It may also be referred to as hydrolyzed collagen, coll ...
and
gum arabic Gum arabic (gum acacia, gum sudani, Senegal gum and by other names) () is a tree gum exuded by two species of '' Acacia sensu lato:'' '' Senegalia senegal,'' and '' Vachellia seyal.'' However, the term "gum arabic" does not indicate a partic ...
became insoluble in water after exposure to sunlight. Alphonse Poitevin added carbon pigment to the colloids in 1855, creating the first
carbon print A carbon print is a photographic print with an image consisting of pigmented gelatin, rather than of silver or other metallic particles suspended in a uniform layer of gelatin, as in typical black-and-white prints, or of chromogenic dyes, as in t ...
. In 1858, John Pouncy used colored pigment with gum arabic to create the first color images. Low density photographic negatives of the same size as the final image are used for exposing the print. No
enlarger An enlarger is a specialized transparency Image projector, projector used to produce Photography, photographic prints from film or glass Negative (photography), negatives, or from reversal film, transparencies. Construction All enlargers consist ...
is used, but instead, a
contact print A contact print is a photographic image produced from Photographic film, film; sometimes from a film negative (photography), negative, and sometimes from a film positive or paper negative. In a darkroom an exposed and developed piece of film or ...
ing frame or vacuum exposure frame is used with an
ultraviolet Ultraviolet radiation, also known as simply UV, is electromagnetic radiation of wavelengths of 10–400 nanometers, shorter than that of visible light, but longer than X-rays. UV radiation is present in sunlight and constitutes about 10% of ...
light source such as a mercury vapor lamp, a common fluorescent
black light A blacklight, also called a UV-A light, Wood's lamp, or ultraviolet light, is a lamp (fixture), lamp that emits long-wave (UV-A) ultraviolet light and very little visible light. One type of lamp has a violet light filter, filter material, eith ...
, or the
sun The Sun is the star at the centre of the Solar System. It is a massive, nearly perfect sphere of hot plasma, heated to incandescence by nuclear fusion reactions in its core, radiating the energy from its surface mainly as visible light a ...
. The negative is sandwiched between the prepared paper and a sheet of glass in registration with previous passes. The print is then floated face down in a bath of room-temperature water to allow the soluble gum, excess dichromate, and pigment to wash away. Several changes of water bath are necessary to clear the print. Afterwards, the print is hung to dry. When all layers are complete and dry, a clearing bath of
sodium metabisulfite Sodium metabisulfite or sodium pyrosulfite (IUPAC spelling; Br. E. sodium metabisulphite or sodium pyrosulphite) is an inorganic compound of chemical formula Na2S2O5. The substance is sometimes referred to as disodium metabisulfite. It is used a ...
is used to extract any remaining dichromate so the print will be archival.


References


The gum bichromate process


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External links


Movie

Video/ Viméo
(
Wayback Machine The Wayback Machine is a digital archive of the World Wide Web founded by Internet Archive, an American nonprofit organization based in San Francisco, California. Launched for public access in 2001, the service allows users to go "back in ...
archive)
An introduction to the gum bichromate processIllustrated Gum Printing Tutorials and worksGum History, Tips, Process, and Original Image Galleries
{{photography subject Photographic processes