In
statistical mechanics, the Griffiths inequality, sometimes also called Griffiths–Kelly–Sherman inequality or GKS inequality, named after
Robert B. Griffiths
Robert B. Griffiths (February 25, 1937) is an American physicist at Carnegie Mellon University. He is the originator of the consistent histories approach to quantum mechanics, which has since been developed by himself, Roland Omnès, Murray Gell- ...
, is a
correlation inequality
A correlation inequality is any of a number of inequalities satisfied by the correlation functions of a model. Such inequalities are of particular use in statistical mechanics and in percolation theory.
Examples include:
* Bell's inequality
* FK ...
for
ferromagnetic
Ferromagnetism is a property of certain materials (such as iron) which results in a large observed magnetic permeability, and in many cases a large magnetic coercivity allowing the material to form a permanent magnet. Ferromagnetic materials ...
spin systems. Informally, it says that in ferromagnetic spin systems, if the 'a-priori distribution' of the spin is invariant under spin flipping, the correlation of any monomial of the spins is non-negative; and the two point correlation of two monomial of the spins is non-negative.
The inequality was proved by Griffiths for Ising ferromagnets with two-body interactions,
then generalised by Kelly and Sherman to interactions involving an arbitrary number of spins,
and then by Griffiths to systems with arbitrary spins. A more general formulation was given by
Ginibre,
and is now called the Ginibre inequality.
Definitions
Let
be a configuration of (continuous or discrete) spins on a
lattice ''Λ''. If ''A'' ⊂ ''Λ'' is a list of lattice sites, possibly with duplicates, let
be the product of the spins in ''A''.
Assign an ''a-priori'' measure ''dμ(σ)'' on the spins;
let ''H'' be an energy functional of the form
:
where the sum is over lists of sites ''A'', and let
:
be the
partition function. As usual,
:
stands for the
ensemble average
In physics, specifically statistical mechanics, an ensemble (also statistical ensemble) is an idealization consisting of a large number of virtual copies (sometimes infinitely many) of a system, considered all at once, each of which represents ...
.
The system is called ''ferromagnetic'' if, for any list of sites ''A'', ''J
A ≥ 0''. The system is called ''invariant under spin flipping'' if, for any ''j'' in ''Λ'', the measure ''μ'' is preserved under the sign flipping map ''σ → τ'', where
:
Statement of inequalities
First Griffiths inequality
In a ferromagnetic spin system which is invariant under spin flipping,
:
for any list of spins ''A''.
Second Griffiths inequality
In a ferromagnetic spin system which is invariant under spin flipping,
:
for any lists of spins ''A'' and ''B''.
The first inequality is a special case of the second one, corresponding to ''B'' = ∅.
Proof
Observe that the partition function is non-negative by definition.
''Proof of first inequality'': Expand
:
then
:
where ''n
A(j)'' stands for the number of times that ''j'' appears in ''A''. Now, by invariance under spin flipping,
:
if at least one ''n(j)'' is odd, and the same expression is obviously non-negative for even values of ''n''. Therefore, ''Z''<''σ
A''>≥0, hence also <''σ
A''>≥0.
''Proof of second inequality''. For the second Griffiths inequality, double the random variable, i.e. consider a second copy of the spin,
, with the same distribution of
. Then
:
Introduce the new variables
:
The doubled system
is ferromagnetic in
because
is a polynomial in
with positive coefficients
:
Besides the measure on
is invariant under spin flipping because
is.
Finally the monomials
,
are polynomials in
with positive coefficients
:
The first Griffiths inequality applied to
gives the result.
More details are in and.
Extension: Ginibre inequality
The Ginibre inequality is an extension, found by Jean Ginibre,
[ of the Griffiths inequality.
]
Formulation
Let (Γ, ''μ'') be a probability space
In probability theory, a probability space or a probability triple (\Omega, \mathcal, P) is a mathematical construct that provides a formal model of a random process or "experiment". For example, one can define a probability space which models t ...
. For functions ''f'', ''h'' on Γ, denote
:
Let A be a set of real functions on ''Γ'' such that. for every ''f''1,''f''2,...,''f''''n'' in A, and for any choice of signs ±,
:
Then, for any ''f'',''g'',−''h'' in the convex cone
In linear algebra, a ''cone''—sometimes called a linear cone for distinguishing it from other sorts of cones—is a subset of a vector space that is closed under scalar multiplication; that is, is a cone if x\in C implies sx\in C for every .
...
generated by A,
:
Proof
Let
:
Then
:
Now the inequality follows from the assumption and from the identity
:
Examples
* To recover the (second) Griffiths inequality, take Γ = Λ, where Λ is a lattice, and let ''μ'' be a measure on Γ that is invariant under sign flipping. The cone A of polynomials with positive coefficients satisfies the assumptions of the Ginibre inequality.
* (Γ, ''μ'') is a commutative
In mathematics, a binary operation is commutative if changing the order of the operands does not change the result. It is a fundamental property of many binary operations, and many mathematical proofs depend on it. Most familiar as the name o ...
compact group
In mathematics, a compact (topological) group is a topological group whose topology realizes it as a compact topological space (when an element of the group is operated on, the result is also within the group). Compact groups are a natural ge ...
with the Haar measure, A is the cone of real positive definite functions on Γ.
* Γ is a totally ordered set
In mathematics, a total or linear order is a partial order in which any two elements are comparable. That is, a total order is a binary relation \leq on some set X, which satisfies the following for all a, b and c in X:
# a \leq a ( reflexiv ...
, A is the cone of real positive non-decreasing functions on Γ. This yields Chebyshev's sum inequality. For extension to partially ordered sets, see FKG inequality
In mathematics, the Fortuin–Kasteleyn–Ginibre (FKG) inequality is a correlation inequality, a fundamental tool in statistical mechanics and probabilistic combinatorics (especially random graphs and the probabilistic method), due to . Informall ...
.
Applications
* The thermodynamic limit
In statistical mechanics, the thermodynamic limit or macroscopic limit, of a system is the limit for a large number of particles (e.g., atoms or molecules) where the volume is taken to grow in proportion with the number of particles.S.J. Blunde ...
of the correlations of the ferromagnetic Ising model (with non-negative external field ''h'' and free boundary conditions) exists.
:This is because increasing the volume is the same as switching on new couplings ''J''''B'' for a certain subset ''B''. By the second Griffiths inequality
::
:Hence is monotonically increasing with the volume; then it converges since it is bounded by 1.
* The one-dimensional, ferromagnetic Ising model with interactions displays a phase transition if .
:This property can be shown in a hierarchical approximation, that differs from the full model by the absence of some interactions: arguing as above with the second Griffiths inequality, the results carries over the full model.
*The Ginibre inequality provides the existence of the thermodynamic limit for the free energy and spin correlations for the two-dimensional classical XY model
The classical XY model (sometimes also called classical rotor (rotator) model or O(2) model) is a lattice model of statistical mechanics. In general, the XY model can be seen as a specialization of Stanley's ''n''-vector model for .
Definition
...
.[ Besides, through Ginibre inequality, Kunz and Pfister proved the presence of a phase transition for the ferromagnetic XY model with interaction if .
* Aizenman and Simon used the Ginibre inequality to prove that the two point spin correlation of the ''ferromagnetic'' classical XY model in dimension , coupling and inverse temperature is ''dominated'' by (i.e. has upper bound given by) the two point correlation of the ''ferromagnetic'' ]Ising model
The Ising model () (or Lenz-Ising model or Ising-Lenz model), named after the physicists Ernst Ising and Wilhelm Lenz, is a mathematical model of ferromagnetism in statistical mechanics. The model consists of discrete variables that represent ...
in dimension , coupling , and inverse temperature
::
:Hence the critical of the XY model cannot be smaller than the double of the critical temperature of the Ising model
::
:in dimension ''D'' = 2 and coupling ''J'' = 1, this gives
::
* There exists a version of the Ginibre inequality for the Coulomb gas that implies the existence of thermodynamic limit of correlations.
* Other applications (phase transitions in spin systems, XY model, XYZ quantum chain) are reviewed in.
References
{{Reflist
Inequalities
Statistical mechanics