
Greenschists are
metamorphic rocks that formed under the lowest temperatures and pressures usually produced by
regional metamorphism, typically and 2–10 kilobars ().
Greenschists commonly have an abundance of green minerals such as
chlorite
The chlorite ion, or chlorine dioxide anion, is the halite (oxyanion), halite with the chemical formula of . A chlorite (compound) is a compound that contains this group, with chlorine in the oxidation state of +3. Chlorites are also known as s ...
,
serpentine, and
epidote, and
platy minerals such as
muscovite and platy serpentine.
[ The platiness gives the rock ]schistosity
Cleavage, in structural geology and petrology, describes a type of planar Rock (geology), rock feature that develops as a result of deformation (engineering), deformation and metamorphism. The degree of deformation and metamorphism along with roc ...
(a tendency to split into layers). Other common minerals include quartz
Quartz is a hard, crystalline mineral composed of silica (silicon dioxide). The Atom, atoms are linked in a continuous framework of SiO4 silicon–oxygen Tetrahedral molecular geometry, tetrahedra, with each oxygen being shared between two tet ...
, orthoclase
Orthoclase, or orthoclase feldspar ( endmember formula K Al Si3 O8), is an important tectosilicate mineral which forms igneous rock. The name is from the Ancient Greek for "straight fracture", because its two cleavage planes are at right angles ...
, talc, carbonate mineral
Carbonate minerals are those minerals containing the carbonate ion, .
Carbonate divisions Anhydrous carbonates
*Calcite group: trigonal
**Calcite CaCO3
**Gaspéite (Ni,Mg,Fe2+)CO3
**Magnesite MgCO3
**Otavite CdCO3
**Rhodochrosite MnCO3
**Sider ...
s and amphibole
Amphibole ( ) is a group of inosilicate minerals, forming prism or needlelike crystals, composed of double chain tetrahedra, linked at the vertices and generally containing ions of iron and/or magnesium in their structures. Its IMA symbol is ...
( actinolite).[
Greenschist is a general field ]petrologic
Petrology () is the branch of geology that studies rock (geology), rocks, their mineralogy, composition, texture, structure and the conditions under which they form. Petrology has three subdivisions: igneous petrology, igneous, metamorphic rock, ...
term for metamorphic or altered mafic volcanic rock
Volcanic rocks (often shortened to volcanics in scientific contexts) are rocks formed from lava erupted from a volcano. Like all rock types, the concept of volcanic rock is artificial, and in nature volcanic rocks grade into hypabyssal and me ...
. In Europe, the term ''prasinite'' is sometimes used. A ''greenstone'' is sometimes a greenschist but can also be rock types without any schistosity, especially metabasalt ( spilite). However, basalts may remain quite black if primary pyroxene
The pyroxenes (commonly abbreviated Px) are a group of important rock-forming inosilicate minerals found in many igneous and metamorphic rocks. Pyroxenes have the general formula , where X represents ions of calcium (Ca), sodium (Na), iron ( ...
does not revert to chlorite or actinolite. To qualify for the name, a rock must also exhibit schistosity or some foliation or layering. The rock is derived from basalt
Basalt (; ) is an aphanite, aphanitic (fine-grained) extrusive igneous rock formed from the rapid cooling of low-viscosity lava rich in magnesium and iron (mafic lava) exposed at or very near the planetary surface, surface of a terrestrial ...
, gabbro
Gabbro ( ) is a phaneritic (coarse-grained and magnesium- and iron-rich), mafic intrusive igneous rock formed from the slow cooling magma into a holocrystalline mass deep beneath the Earth's surface. Slow-cooling, coarse-grained gabbro is ch ...
or similar rocks containing sodium
Sodium is a chemical element; it has Symbol (chemistry), symbol Na (from Neo-Latin ) and atomic number 11. It is a soft, silvery-white, highly reactive metal. Sodium is an alkali metal, being in group 1 element, group 1 of the peri ...
-rich plagioclase
Plagioclase ( ) is a series of Silicate minerals#Tectosilicates, tectosilicate (framework silicate) minerals within the feldspar group. Rather than referring to a particular mineral with a specific chemical composition, plagioclase is a continu ...
feldspar
Feldspar ( ; sometimes spelled felspar) is a group of rock-forming aluminium tectosilicate minerals, also containing other cations such as sodium, calcium, potassium, or barium. The most common members of the feldspar group are the ''plagiocl ...
, chlorite, epidote and quartz.
Petrology
''Greenschist'' is defined by the presence of the minerals chlorite
The chlorite ion, or chlorine dioxide anion, is the halite (oxyanion), halite with the chemical formula of . A chlorite (compound) is a compound that contains this group, with chlorine in the oxidation state of +3. Chlorites are also known as s ...
, epidote, or actinolite, which give the rock its green color. Greenschists also have pronounced schistosity
Cleavage, in structural geology and petrology, describes a type of planar Rock (geology), rock feature that develops as a result of deformation (engineering), deformation and metamorphism. The degree of deformation and metamorphism along with roc ...
. Schistosity is a thin layering of the rock produced by metamorphism
Metamorphism is the transformation of existing Rock (geology), rock (the protolith) to rock with a different mineral composition or Texture (geology), texture. Metamorphism takes place at temperatures in excess of , and often also at elevated ...
(a ''foliation
In mathematics (differential geometry), a foliation is an equivalence relation on an topological manifold, ''n''-manifold, the equivalence classes being connected, injective function, injectively immersed submanifolds, all of the same dimension ...
'') that permits the rock to easily be split into flakes or slabs less than thick. This arises from the presence of chlorite or other platy minerals that become aligned in layers during metamorphism.
Greenschist may also contain albite
Albite is a plagioclase feldspar mineral. It is the sodium endmember of the plagioclase solid solution series. It represents a plagioclase with less than 10% anorthite content. The pure albite endmember has the formula . It is a tectosilicat ...
and often has a lepidoblastic, nematoblastic or schistose texture defined primarily by chlorite and actinolite. Grain size is rarely coarse, due primarily to the mineral assemblage. Chlorite and to a lesser extent actinolite typically exhibit small, flat or acicular crystal habits.
''Greenstone'' is a field term for any massive mafic volcanic rock that has been altered to a greenish color by the formation of the same minerals that give the green color to greenschist, whether or not the rock displays schistosity. The term has also been used to describe any igneous intrusions into the Coal Measures Group of Scotland, to describe chamosite-rich mudstone of Early Jurassic
The Early Jurassic Epoch (geology), Epoch (in chronostratigraphy corresponding to the Lower Jurassic series (stratigraphy), Series) is the earliest of three epochs of the Jurassic Period. The Early Jurassic starts immediately after the Triassic� ...
age in Great Britain, or for nephrite or other greenish gemstones.
Greenschist facies
Greenschist facies is determined by the particular temperature and pressure conditions required to metamorphose basalt to form the typical greenschist facies minerals chlorite, actinolite, and albite. Greenschist facies results from low temperature, moderate pressure metamorphism. Metamorphic conditions which create typical greenschist facies assemblages are called the ''Barrovian Facies Sequence'', and the lower-pressure ''Abukuma Facies Series''. Temperatures of approximately and depths of about are the typical envelope of greenschist facies rocks.
The equilibrium mineral assemblage of rocks subjected to greenschist facies conditions depends on primary rock composition.
* Basalt: ''chlorite + actinolite + albite +/- epidote''
* Ultramafic: ''chlorite + serpentine +/- talc +/- tremolite +/- diopside +/- brucite
Brucite is the mineral form of magnesium hydroxide, with the chemical formula Magnesium, Mg(hydroxyl, OH)2. It is a common alteration product of periclase in marble; a low-temperature hydrothermal Vein (geology), vein mineral in metamorphosed li ...
''
* Pelites: ''quartz
Quartz is a hard, crystalline mineral composed of silica (silicon dioxide). The Atom, atoms are linked in a continuous framework of SiO4 silicon–oxygen Tetrahedral molecular geometry, tetrahedra, with each oxygen being shared between two tet ...
+/- albite
Albite is a plagioclase feldspar mineral. It is the sodium endmember of the plagioclase solid solution series. It represents a plagioclase with less than 10% anorthite content. The pure albite endmember has the formula . It is a tectosilicat ...
+/- k-feldspar +/- chlorite, muscovite, garnet
Garnets () are a group of silicate minerals that have been used since the Bronze Age as gemstones and abrasives.
Garnet minerals, while sharing similar physical and crystallographic properties, exhibit a wide range of chemical compositions, de ...
, pyrophyllite +/- graphite
Graphite () is a Crystallinity, crystalline allotrope (form) of the element carbon. It consists of many stacked Layered materials, layers of graphene, typically in excess of hundreds of layers. Graphite occurs naturally and is the most stable ...
''
* Calc-silicates: ''calcite
Calcite is a Carbonate minerals, carbonate mineral and the most stable Polymorphism (materials science), polymorph of calcium carbonate (CaCO3). It is a very common mineral, particularly as a component of limestone. Calcite defines hardness 3 on ...
+/- dolomite +/- quartz +/- micas, scapolite, wollastonite
Wollastonite is a calcium Silicate minerals, inosilicate mineral (calcium, Casilicon, Sioxygen, O3) that may contain small amounts of iron, magnesium, and manganese substituting for calcium. It is usually white. It forms when impure limestone or D ...
, etc.
In greater detail the greenschist facies is subdivided into subgreenschist, lower and upper greenschist. Lower temperatures are transitional with and overlap the prehnite-pumpellyite facies and higher temperatures overlap with and include sub-amphibolite
Amphibolite () is a metamorphic rock that contains amphibole, especially hornblende and actinolite, as well as plagioclase feldspar, but with little or no quartz. It is typically dark-colored and dense, with a weakly foliated or schistose ...
facies.
If burial continues along Barrovian Sequence metamorphic trajectories, greenschist facies gives rise to amphibolite facies assemblages, dominated by amphibole and eventually to granulite facies. Lower pressure, normally contact metamorphism produces albite
Albite is a plagioclase feldspar mineral. It is the sodium endmember of the plagioclase solid solution series. It represents a plagioclase with less than 10% anorthite content. The pure albite endmember has the formula . It is a tectosilicat ...
-epidote hornfels while higher pressures at great depth produces eclogite.
Oceanic basalts in the vicinity of mid-ocean ridge
A mid-ocean ridge (MOR) is a undersea mountain range, seafloor mountain system formed by plate tectonics. It typically has a depth of about and rises about above the deepest portion of an ocean basin. This feature is where seafloor spreading ...
s typically exhibit sub-greenschist alteration. The greenstone belts of the various Archean
The Archean ( , also spelled Archaean or Archæan), in older sources sometimes called the Archaeozoic, is the second of the four geologic eons of Earth's history of Earth, history, preceded by the Hadean Eon and followed by the Proterozoic and t ...
craton
A craton ( , , or ; from "strength") is an old and stable part of the continental lithosphere, which consists of Earth's two topmost layers, the crust and the uppermost mantle. Having often survived cycles of merging and rifting of contine ...
s are commonly altered to the greenschist facies. These ancient rocks are noted as host rocks for a variety of ore deposits in Australia
Australia, officially the Commonwealth of Australia, is a country comprising mainland Australia, the mainland of the Australia (continent), Australian continent, the island of Tasmania and list of islands of Australia, numerous smaller isl ...
, Namibia
Namibia, officially the Republic of Namibia, is a country on the west coast of Southern Africa. Its borders include the Atlantic Ocean to the west, Angola and Zambia to the north, Botswana to the east and South Africa to the south; in the no ...
and Canada
Canada is a country in North America. Its Provinces and territories of Canada, ten provinces and three territories extend from the Atlantic Ocean to the Pacific Ocean and northward into the Arctic Ocean, making it the world's List of coun ...
.
Greenschist-like rocks can also be formed under blueschist facies conditions if the original rock ( protolith) contains enough magnesium
Magnesium is a chemical element; it has Symbol (chemistry), symbol Mg and atomic number 12. It is a shiny gray metal having a low density, low melting point and high chemical reactivity. Like the other alkaline earth metals (group 2 ...
. This explains the scarcity of blueschist preserved from before the Neoproterozoic Era 1000 Ma ago when the Earth's oceanic crust
Oceanic crust is the uppermost layer of the oceanic portion of the tectonic plates. It is composed of the upper oceanic crust, with pillow lavas and a dike complex, and the lower oceanic crust, composed of troctolite, gabbro and ultramaf ...
contained more magnesium than today's oceanic crust.
Use
Europe
In Minoan Crete, greenschist and blueschist were used to pave streets and courtyard
A courtyard or court is a circumscribed area, often surrounded by a building or complex, that is open to the sky.
Courtyards are common elements in both Western and Eastern building patterns and have been used by both ancient and contemporary a ...
s between 1650 and 1600 BC. These rocks were likely quarried in Agia Pelagia on the north coast of central Crete.
Across Europe, greenschist rocks have been used to make axes. Several sites, including Great Langdale
Great Langdale is a valley in the Lake District National Park in North West England, the epithet "Great" distinguishing it from the neighbouring valley of Little Langdale. Langdale is also the name of a valley in the Howgill Fells, elsewhere ...
in England, have been identified.
Eastern North America
A form of chlorite schist was popular in prehistoric Native American communities for the production of axes and celts
The Celts ( , see Names of the Celts#Pronunciation, pronunciation for different usages) or Celtic peoples ( ) were a collection of Indo-European languages, Indo-European peoples. "The Celts, an ancient Indo-European people, reached the apoge ...
, as well as ornamental items. In the Middle Woodland period, greenschist was one of the many trade items that were part of the Hopewell culture exchange network, sometimes transported over thousands of kilometers.
During the time of the Mississippian culture, the polity
A polity is a group of people with a collective identity, who are organized by some form of political Institutionalisation, institutionalized social relations, and have a capacity to mobilize resources.
A polity can be any group of people org ...
of Moundville apparently had some control over the production and distribution of greenschist. The Moundville source has been shown to be from two localities in the Hillabee Formation of central and eastern Alabama.
See also
* List of minerals
* List of rock types
* Metamorphism
Metamorphism is the transformation of existing Rock (geology), rock (the protolith) to rock with a different mineral composition or Texture (geology), texture. Metamorphism takes place at temperatures in excess of , and often also at elevated ...
* Pounamu, another type of rock frequently called greenstone
References
* Blatt, Harvey and Robert J. Tracy (1996). Petrology; Igneous, Sedimentary, and Metamorphic, 2nd Ed., W. H. Freeman. .
*Gall, Daniel G. and Vincas P. Steponaitis, "Composition and Provenance of Greenstone Artifacts from Moundville," Southeastern Archaeology 20(2):99–117 001.
*Steponaitis, Vincas P. Prehistoric Archaeology in the Southeastern United States, 1970–1985. Annual Review of Anthropology, Vol. 15. (1986), pp. 363–404.
{{Rock type
Schist
Metamorphic petrology
he:צפחה#צפחות ירוקות