Gold(I) Iodide
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Gold monoiodide is the
inorganic compound An inorganic compound is typically a chemical compound that lacks carbon–hydrogen bonds⁠that is, a compound that is not an organic compound. The study of inorganic compounds is a subfield of chemistry known as ''inorganic chemistry''. Inorgan ...
of
gold Gold is a chemical element; it has chemical symbol Au (from Latin ) and atomic number 79. In its pure form, it is a brightness, bright, slightly orange-yellow, dense, soft, malleable, and ductile metal. Chemically, gold is a transition metal ...
and
iodine Iodine is a chemical element; it has symbol I and atomic number 53. The heaviest of the stable halogens, it exists at standard conditions as a semi-lustrous, non-metallic solid that melts to form a deep violet liquid at , and boils to a vi ...
with the formula AuI. It can be synthesized by dissolving gold powder in an aqueous solution of
iodine Iodine is a chemical element; it has symbol I and atomic number 53. The heaviest of the stable halogens, it exists at standard conditions as a semi-lustrous, non-metallic solid that melts to form a deep violet liquid at , and boils to a vi ...
and potassium iodide. With Lewis bases, AuI reacts to give numerous complexes.


Preparation

Gold monoiodide can be obtained by reacting a tetrachloridoauric acid solution with furthermore potassium iodide. It is also possible to produce it by reacting gold and iodine in a protective atmosphere at around 390 °C.


Properties

Gold monoiodide is a yellow, crystalline powder that gradually decomposes upon contact with water, humidity or light. It has a tetragonal crystal structure with the
space group In mathematics, physics and chemistry, a space group is the symmetry group of a repeating pattern in space, usually in three dimensions. The elements of a space group (its symmetry operations) are the rigid transformations of the pattern that ...
''P''42''/ncm'' (space group no. 138), a = 4.359 Å, c = 13.711 Å.


References

{{inorganic-compound-stub Gold(I) compounds Iodides Metal halides Gold–halogen compounds