Gangue
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Gangue () is the commercially worthless material that surrounds, or is closely mixed with, a wanted
mineral In geology and mineralogy, a mineral or mineral species is, broadly speaking, a solid substance with a fairly well-defined chemical composition and a specific crystal structure that occurs naturally in pure form.John P. Rafferty, ed. (2011): Mi ...
in an
ore deposit Ore is natural rock or sediment that contains one or more valuable minerals, typically including metals, concentrated above background levels, and that is economically viable to mine and process. The grade of ore refers to the concentration ...
. It is thus distinct from
overburden In mining, overburden (also called waste or spoil) is the material that lies above an area that lends itself to economical exploitation, such as the rock, soil, and ecosystem that lies above a coal seam or ore body. Overburden is distinct from tai ...
, which is the waste rock or materials overlying an
ore Ore is natural rock or sediment that contains one or more valuable minerals, typically including metals, concentrated above background levels, and that is economically viable to mine and process. The grade of ore refers to the concentration ...
or mineral body that are displaced during
mining Mining is the Resource extraction, extraction of valuable geological materials and minerals from the surface of the Earth. Mining is required to obtain most materials that cannot be grown through agriculture, agricultural processes, or feasib ...
without being processed, The separation of valuable mineral from gangue minerals is known as
mineral processing Mineral processing is the process of separating commercially valuable minerals from their ores in the field of extractive metallurgy. Depending on the processes used in each instance, it is often referred to as ore dressing or ore milling. Be ...
, mineral dressing, or ore dressing. It is a necessary, and often significant, aspect of mining. It can be a complicated process, depending on the nature of the minerals involved. For example,
galena Galena, also called lead glance, is the natural mineral form of lead(II) sulfide (PbS). It is the most important ore of lead and an important source of silver. Galena is one of the most abundant and widely distributed sulfide minerals. It crysta ...
, an ore of lead, is usually found in large pieces within its gangue, so it does not normally need extensive processing to remove it; but
cassiterite Cassiterite is a tin oxide mineral, SnO2. It is generally opaque, but it is translucent in thin crystals. Its luster and multiple crystal faces produce a desirable gem. Cassiterite was the chief tin ore throughout ancient history and remains ...
, the chief ore mineral of
tin Tin is a chemical element; it has symbol Sn () and atomic number 50. A silvery-colored metal, tin is soft enough to be cut with little force, and a bar of tin can be bent by hand with little effort. When bent, a bar of tin makes a sound, the ...
, is usually disseminated as very small crystals throughout its gangue, so when it is mined from hard rock, the ore-bearing rock first needs to be crushed very finely, and then has to be subjected to sophisticated processes to separate the ore. For any particular ore deposit, and at any particular point in time, the concentration of the wanted mineral(s) in the gangue material will determine whether it is commercially viable to mine that deposit. The ease with which the wanted mineral(s) can be separated from gangue minerals also plays an important part. Early mining ventures, having relatively unsophisticated methods, often could not achieve a high degree of separation, so large quantities of minerals found their way into the waste mineral dumps of mines. As the value of a mineral increases, or when new and cheaper means of processing the ore to extract the wanted mineral(s) are introduced, it may become worthwhile to rework such old dumps to retrieve the wanted minerals they still contain.


Environmental impact of gangue minerals in mine tailings

Gangue minerals, once separated by mineral dressing processes of (most of) the valuable ore minerals and dumped in
mine tailings In mining, tailings or tails are the materials left over after the process of separating the valuable fraction from the uneconomic fraction (gangue) of an ore. Tailings are different from overburden, which is the waste rock or other material th ...
may be a significant environmental impact. In particular, oxidation of
pyrite The mineral pyrite ( ), or iron pyrite, also known as fool's gold, is an iron sulfide with the chemical formula Fe S2 (iron (II) disulfide). Pyrite is the most abundant sulfide mineral. Pyrite's metallic luster and pale brass-yellow hue ...
, a common gangue mineral, is one of the main sources of
acid mine drainage Acid mine drainage, acid and metalliferous drainage (AMD), or acid rock drainage (ARD) is the outflow of acidic water from metal mines and coal mines. Acid rock drainage occurs naturally within some environments as part of the rock weatherin ...
.


Re-use

Waste minerals that were once disgarded as gangue are sometimes salvaged and used commercially. For example, in
copper Copper is a chemical element; it has symbol Cu (from Latin ) and atomic number 29. It is a soft, malleable, and ductile metal with very high thermal and electrical conductivity. A freshly exposed surface of pure copper has a pinkish-orang ...
mines in the nineteenth century the mineral
arsenopyrite Arsenopyrite ( IMA symbol: Apy) is an iron arsenic sulfide (FeAsS). It is a hard ( Mohs 5.5–6) metallic, opaque, steel grey to silver white mineral with a relatively high specific gravity of 6.1. When dissolved in nitric acid, it releases el ...
was dumped until
arsenic Arsenic is a chemical element; it has Symbol (chemistry), symbol As and atomic number 33. It is a metalloid and one of the pnictogens, and therefore shares many properties with its group 15 neighbors phosphorus and antimony. Arsenic is not ...
compounds became popular as
insecticide Insecticides are pesticides used to kill insects. They include ovicides and larvicides used against insect eggs and larvae, respectively. The major use of insecticides is in agriculture, but they are also used in home and garden settings, i ...
s later in the century. Starting in the second half of the 20th century the environmental benefits of
recycling Recycling is the process of converting waste materials into new materials and objects. This concept often includes the recovery of energy from waste materials. The recyclability of a material depends on its ability to reacquire the propert ...
gangue gained prominence. For example, in 2002, about 130 million tons of gangue were produced per year from coal mining in China. This, mixed with the 60 million tons of coal mud also produced, could be used for power generation; and the coal mining gangue could be combined with coal fly ash to produce building materials. The estimated cost of such projects would be up to 4 billion yuan, but would be expected to save just over 4 million tons of standard coal per year.


See also

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References


Further reading

* ''An Elementary Outline Of Mechanical Processes'', by G. W. Danforth. 1912; 49. Elimination Of Gangue {{Authority control History of mining Ore deposits