Fulgarite
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Fulgurites (), commonly called "fossilized lightning", are natural tubes, clumps, or masses of
sintered Sintering or frittage is the process of compacting and forming a solid mass of material by pressure or heat without melting it to the point of liquefaction. Sintering happens as part of a manufacturing process used with metals, ceramics, pla ...
,
vitrified Vitrification (, via French ') is the full or partial transformation of a substance into a glass, that is to say, a non- crystalline or amorphous solid. Glasses differ from liquids structurally and glasses possess a higher degree of connectivity ...
, or fused
soil Soil, also commonly referred to as earth, is a mixture of organic matter, minerals, gases, water, and organisms that together support the life of plants and soil organisms. Some scientific definitions distinguish dirt from ''soil'' by re ...
,
sand Sand is a granular material composed of finely divided mineral particles. Sand has various compositions but is usually defined by its grain size. Sand grains are smaller than gravel and coarser than silt. Sand can also refer to a textural ...
, rock, organic debris and other sediments that sometimes form when
lightning Lightning is a natural phenomenon consisting of electrostatic discharges occurring through the atmosphere between two electrically charged regions. One or both regions are within the atmosphere, with the second region sometimes occurring on ...
discharges into ground. When composed of silica, fulgurites are classified as a variety of the
mineraloid A mineraloid is a naturally occurring substance that resembles a mineral, but does not demonstrate the crystallinity of a mineral. Mineraloid substances possess chemical compositions that vary beyond the generally accepted ranges for specific mi ...
lechatelierite Lechatelierite is silica glass, amorphous SiO2, non-crystalline mineraloid. It is named for Henry Louis Le Chatelier. Structure Lechatelierite is a mineraloid as it does not have a crystal structure. Although not a true mineral, it is often clas ...
. When ordinary negative polarity cloud-ground lightning discharges into a grounding substrate, greater than 100 million volts (100 MV) of potential difference may be bridged. Such current may propagate into
silica Silicon dioxide, also known as silica, is an oxide of silicon with the chemical formula , commonly found in nature as quartz. In many parts of the world, silica is the major constituent of sand. Silica is one of the most complex and abundant f ...
-rich
quartz Quartz is a hard, crystalline mineral composed of silica (silicon dioxide). The Atom, atoms are linked in a continuous framework of SiO4 silicon–oxygen Tetrahedral molecular geometry, tetrahedra, with each oxygen being shared between two tet ...
ose sand, mixed soil,
clay Clay is a type of fine-grained natural soil material containing clay minerals (hydrous aluminium phyllosilicates, e.g. kaolinite, ). Most pure clay minerals are white or light-coloured, but natural clays show a variety of colours from impuriti ...
, or other sediments, rapidly vaporizing and melting resistant materials within such a common dissipation regime. This results in the formation of generally hollow and/or vesicular, branching assemblages of glassy tubes, crusts, and clumped masses. Fulgurites have no fixed composition because their chemical composition is determined by the physical and chemical properties of whatever material is being struck by lightning. Fulgurites are structurally similar to
Lichtenberg figure A Lichtenberg figure (German: ''Lichtenberg-Figur''), or Lichtenberg dust figure, is a branching electric discharge that sometimes appears on the surface or in the interior of Electrical insulation, insulating materials. Lichtenberg figures a ...
s, which are the branching patterns produced on surfaces of insulators during
dielectric breakdown In electronics, electrical breakdown or dielectric breakdown is a process that occurs when an electrically insulating material (a dielectric), subjected to a high enough voltage, suddenly becomes a conductor and current flows through it. All ...
by high-voltage discharges, such as lightning.


Description

Fulgurites are formed when lightning strikes the ground, fusing and vitrifying mineral grains. The primary SiO2 phase in common tube fulgurites is
lechatelierite Lechatelierite is silica glass, amorphous SiO2, non-crystalline mineraloid. It is named for Henry Louis Le Chatelier. Structure Lechatelierite is a mineraloid as it does not have a crystal structure. Although not a true mineral, it is often clas ...
, an
amorphous In condensed matter physics and materials science, an amorphous solid (or non-crystalline solid) is a solid that lacks the long-range order that is a characteristic of a crystal. The terms "glass" and "glassy solid" are sometimes used synonymousl ...
silica glass. Many fulgurites show some evidence of crystallization: in addition to glasses, many are partially
protocrystalline A protocrystalline phase is a distinct phase occurring during crystal growth, which evolves into a microcrystalline form. The term is typically associated with silicon films in optical applications such as solar cells. Applications Silicon sol ...
or
microcrystalline A microcrystalline material is a crystallized substance or rock that contains small crystals visible only through microscopic examination. There is little agreement on the range of crystal sizes that should be regarded as microcrystalline, but ...
. Because fulgurites are generally amorphous in structure, fulgurites are classified as
mineraloid A mineraloid is a naturally occurring substance that resembles a mineral, but does not demonstrate the crystallinity of a mineral. Mineraloid substances possess chemical compositions that vary beyond the generally accepted ranges for specific mi ...
s. Peak temperatures within a lightning channel exceed 30,000 K, with sufficient pressure to produce
planar deformation features Planar deformation features, or PDFs, are optically recognizable microscopic features in grains of silicate minerals (usually quartz or feldspar), consisting of very narrow planes of glassy material arranged in parallel sets that have distinct ori ...
in SiO2, a kind of polymorphism. This is also known colloquially as
shocked quartz Shocked quartz is a form of quartz that has a microscopic structure that is different from normal quartz. Under intense pressure (but limited temperature), the crystalline structure of quartz is deformed along planes inside the crystal. These pla ...
. Material properties (size, color, texture) of fulgurites vary widely, depending on the size of the lightning bolt and the composition and moisture content of the surface struck by lightning. Most natural fulgurites fall on a spectrum from white to black. Iron is a common impurity that can result in a deep brownish-green coloration. Lechatelierite similar to fulgurites can also be produced via controlled (or uncontrolled) arcing of artificial electricity into a medium. Downed
high voltage High voltage electricity refers to electrical potential large enough to cause injury or damage. In certain industries, ''high voltage'' refers to voltage above a certain threshold. Equipment and conductors that carry high voltage warrant sp ...
power lines have produced brightly colored lechatelierites, due to the incorporation of
copper Copper is a chemical element; it has symbol Cu (from Latin ) and atomic number 29. It is a soft, malleable, and ductile metal with very high thermal and electrical conductivity. A freshly exposed surface of pure copper has a pinkish-orang ...
or other materials from the power lines. Brightly colored lechatelierites resembling fulgurites are usually synthetic and reflect the incorporation of synthetic materials. However, lightning can strike man-made objects, resulting in colored fulgurites. The interior of Type I (sand) fulgurites normally is smooth or lined with fine bubbles, while their exteriors are coated with rough sedimentary particles or small rocks. Other types of fulgurites are usually vesicular, and may lack an open central tube; their exteriors can be porous or smooth. Branching fulgurites display
fractal In mathematics, a fractal is a Shape, geometric shape containing detailed structure at arbitrarily small scales, usually having a fractal dimension strictly exceeding the topological dimension. Many fractals appear similar at various scale ...
-like
self-similarity In mathematics, a self-similar object is exactly or approximately similar to a part of itself (i.e., the whole has the same shape as one or more of the parts). Many objects in the real world, such as coastlines, are statistically self-similar ...
and structural
scale invariance In physics, mathematics and statistics, scale invariance is a feature of objects or laws that do not change if scales of length, energy, or other variables, are multiplied by a common factor, and thus represent a universality. The technical term ...
as a macroscopic or microscopic network of root-like branches, and can display this texture without central channels or obvious divergence from morphology of context or target (e.g. sheet-like melt, rock fulgurites). Fulgurites are usually fragile, making the field collection of large specimens difficult. Fulgurites can exceed 20 centimeters in diameter and can penetrate deep into the
subsoil Subsoil is the layer of soil under the topsoil on the surface of the ground. Like topsoil, it is composed of a variable mixture of small particles such as sand, silt and clay, but with a much lower percentage of organic matter and humus. The su ...
, sometimes occurring as far as below the surface that was struck, although they may also form directly on a sedimentary surface. One of the longest fulgurites to have been found in modern times was a little over in length, found in northern
Florida Florida ( ; ) is a U.S. state, state in the Southeastern United States, Southeastern region of the United States. It borders the Gulf of Mexico to the west, Alabama to the northwest, Georgia (U.S. state), Georgia to the north, the Atlantic ...
. The
Yale University Yale University is a Private university, private Ivy League research university in New Haven, Connecticut, United States. Founded in 1701, Yale is the List of Colonial Colleges, third-oldest institution of higher education in the United Stat ...
Peabody Museum of Natural History The Peabody Museum of Natural History at Yale University (also known as the Yale Peabody Museum of Natural History or the Yale Peabody Museum) is one of the oldest, largest, and most prolific university natural history museums in the world. It ...
displays one of the longest known preserved fulgurites, approximately in length.
Charles Darwin Charles Robert Darwin ( ; 12 February 1809 – 19 April 1882) was an English Natural history#Before 1900, naturalist, geologist, and biologist, widely known for his contributions to evolutionary biology. His proposition that all speci ...
in ''
The Voyage of the Beagle ''The Voyage of the Beagle'' is the title most commonly given to the book written by Charles Darwin and published in 1839 as his ''Journal and Remarks'', bringing him considerable fame and respect. This was the third volume of ''The Narrative ...
'' recorded that tubes such as these found in
Drigg Drigg is a village on the coast of the Irish Sea in the Cumberland district of the county of Cumbria, England. It borders the Lake District National Park. Next to the village is the site of the UK's low-level radioactive waste storage facility. ...
,
Cumberland Cumberland ( ) is an area of North West England which was historically a county. The county was bordered by Northumberland to the north-east, County Durham to the east, Westmorland to the south-east, Lancashire to the south, and the Scottish ...
, UK reached a length of . Fulgerites at Winans Lake,
Livingston County, Michigan Livingston County ( ) is a Counties of the United States, county in the U.S. state of Michigan. As of the 2020 United States census, 2020 census, its population was 193,866. It is part of the Detroit-Warren, Michigan, Warren-Dearborn, Michigan, ...
, extended discontinuously throughout a 30 m range and arguably include the largest reported fulgurite mass ever recovered and described: its largest section extending approximately 16 ft (4.88 m) in length by 1 ft in diameter (30 cm).


Classification

Fulgurites have been classified into five types related to the type of sediment in which the fulgurite formed, as follows: * Type I – sand fulgurites with tubaceous structure; their central axial void may be collapsed * Type II – soil fulgurites; these are glass-rich, and form in a wide range of sediment compositions, including clay-rich soils, silt-rich soils, gravel-rich soils, and
loess A loess (, ; from ) is a clastic rock, clastic, predominantly silt-sized sediment that is formed by the accumulation of wind-blown dust. Ten percent of Earth's land area is covered by loesses or similar deposition (geology), deposits. A loess ...
oid; these may be tubaceous, branching, vesicular, irregular/slaggy, or may display a combination of these structures, and can produce exogenic fulgurites (droplet fulgurites) * Type III –
caliche Caliche () is a soil accumulation of soluble calcium carbonate at depth, where it precipitates and binds other materials—such as gravel, sand, clay, and silt. It occurs worldwide, in aridisol and mollisol soil orders—generally in arid or se ...
or calcic sediment fulgurites, having thick, often surficially glazed granular walls with calcium-rich vitreous groundmass with little or no lechatelierite glass; their shapes are variable, with multiple narrow central channels common, and can span the entire range of morphological and structural variation for fulguritic objects * Type IV – rock fulgurites, which are either crusts on minimally altered rocks, networks of tunneling within rocks, vesicular outgassed rocks (often glazed by a
silicide A silicide is a type of chemical compound that combines silicon and a usually more electropositive element. Silicon is more electropositive than carbon. In terms of their physical properties, silicides are structurally closer to borides than t ...
-rich and/or metal oxide crust), or completely vitrified and dense rock material and masses of these forms with little sedimentary groundmass * Type V – ropletfulgurites (exogenic fulgurites), which show evidence of ejection (e.g. spheroidal, filamentous, or aerodynamic), related by composition to Type II and Type IV fulgurites * ''phytofulgurite'' – a proposed class of objects resulting from partial to total alteration of biomass (e.g. grasses, lichens, moss, wood) by lightning, described as "natural glasses formed by cloud-to-ground lightning." These were excluded from the classification scheme because they are not glasses, so classifying them as a subset of fulgurites is debatable.


Significance

The presence of fulgurites in an area can be used to estimate the frequency of lightning over a period of time, which can help to understand past regional climates.
Paleolightning Paleolightning refers to the remnants of ancient lightning activity studied in fields such as historical geology, geoarchaeology, and fulminology. Paleolightning provides tangible evidence for the study of lightning activity in Earth's past and th ...
is the study of various indicators of past lightning strikes, primarily in the form of fulgurites and lightning-induced remanent magnetization signatures. Many high-pressure, high-temperature materials have been observed in fulgurites. Many of these minerals and compounds are also known to be formed in extreme environments such as
nuclear weapon A nuclear weapon is an explosive device that derives its destructive force from nuclear reactions, either fission (fission or atomic bomb) or a combination of fission and fusion reactions (thermonuclear weapon), producing a nuclear exp ...
tests,
hypervelocity impact Hypervelocity is very high velocity, approximately over 3,000 meters per second (11,000 km/h, 6,700 mph, 10,000 ft/s, or Mach 8.8). In particular, hypervelocity is velocity so high that the strength of materials upon impact is v ...
s, and interstellar space. Shocked quartz was first described in fulgurites in 1980. Other materials, including highly reduced silicon-metal alloys (
silicides A silicide is a type of chemical compound that combines silicon and a usually more electropositive element. Silicon is more electropositive than carbon. In terms of their physical properties, silicides are structurally closer to borides than to c ...
), the
fullerene A fullerene is an allotropes of carbon, allotrope of carbon whose molecules consist of carbon atoms connected by single and double bonds so as to form a closed or partially closed mesh, with fused rings of five to six atoms. The molecules may ...
allotropes Allotropy or allotropism () is the property of some chemical elements to exist in two or more different forms, in the same physical state, known as allotropes of the elements. Allotropes are different structural modifications of an element: th ...
C60 (
buckminsterfullerene Buckminsterfullerene is a type of fullerene with the formula . It has a cage-like fused-ring structure ( truncated icosahedron) made of twenty hexagons and twelve pentagons, and resembles a football. Each of its 60 carbon atoms is bonded to i ...
s) and C70, as well as high-pressure polymorphs of SiO2, have since been identified in fulgurites. Reduced
phosphides In chemistry, a phosphide is a compound containing the ion or its equivalent. Many different phosphides are known, with widely differing structures. Most commonly encountered on the binary phosphides, i.e. those materials consisting only of pho ...
have been identified in fulgurites, in the form of
schreibersite Schreibersite is generally a rare iron nickel phosphide mineral, , though common in iron-nickel meteorites. It has been found on Disko Island in Greenland and Illinois. Another name used for the mineral is rhabdite. It forms tetragonal crystals ...
( and ), and titanium(III) phosphide. These reduced compounds are otherwise rare on Earth due to the presence of oxygen in Earth's atmosphere, which creates oxidizing surface conditions.


History

Fulgurite tubes have been mentioned already by Persian polymaths
Avicenna Ibn Sina ( – 22 June 1037), commonly known in the West as Avicenna ( ), was a preeminent philosopher and physician of the Muslim world, flourishing during the Islamic Golden Age, serving in the courts of various Iranian peoples, Iranian ...
and
Al-Biruni Abu Rayhan Muhammad ibn Ahmad al-Biruni (; ; 973after 1050), known as al-Biruni, was a Khwarazmian Iranian scholar and polymath during the Islamic Golden Age. He has been called variously "Father of Comparative Religion", "Father of modern ...
in the 11th century, without knowing their true origination. Over the following centuries fulgurites have been described but missinterpreted as a result of subterrestrial fires, falsely attributing curative powers to them, e.g. by Leonhard David Hermann 1711 in his ''Maslographia''. Other famous natural scientists, among them
Charles Darwin Charles Robert Darwin ( ; 12 February 1809 – 19 April 1882) was an English Natural history#Before 1900, naturalist, geologist, and biologist, widely known for his contributions to evolutionary biology. His proposition that all speci ...
,
Horace Bénédict de Saussure Horace Bénédict de Saussure (; 17 February 1740 – 22 January 1799) was a Genevan geologist, meteorologist, physicist, mountaineer and Alpine explorer, often called the founder of alpinism and modern meteorology, and considered to be the f ...
and
Alexander von Humboldt Friedrich Wilhelm Heinrich Alexander von Humboldt (14 September 1769 – 6 May 1859) was a German polymath, geographer, natural history, naturalist, List of explorers, explorer, and proponent of Romanticism, Romantic philosophy and Romanticism ...
gave attention to fulgurites, among whom only Darwin noted a connection to lightning, elaborating the "measure or bore of lightning" that must have caused them, and referring to experiments carried out in Paris by M. Hachette and M. Beudant that succeeded in creating similar fulgurites upon passing strong shocks of galvanism through finely-powdered glass. In 1805 the true process of forming fulgurites by lightning strikes to the ground was identified by agriculturist Hentzen and mineralogist and mining engineer Johann Karl Wilhelm Voigt. In 1817 mineralogist and mining engineer Karl Gustav Fiedler published and comprehensively documented the phenomenon in the ''
Annalen der Physik ''Annalen der Physik'' (English: ''Annals of Physics'') is one of the oldest scientific journals on physics; it has been published since 1799. The journal publishes original, peer-reviewed papers on experimental, theoretical, applied, and mathem ...
''.


See also

* Electromechanical disintegration *
Impactite Impactite is rock created or modified by one or more impacts of a meteorite. Impactites are considered metamorphic rock, because their source materials were modified by the heat and pressure of the impact. On Earth, impactites consist primarily ...
*
Tektite Tektites () are gravel-sized bodies composed of black, green, brown or grey natural glass formed from terrestrial debris ejected during meteorite impacts. The term was coined by Austrian geologist Franz Eduard Suess (1867–1941), son of Eduar ...
*
Trinitite Trinitite, also known as atomsite or Alamogordo glass, is the glassy residue left on the desert floor after the plutonium-based Trinity (nuclear test), Trinity nuclear bomb test on July 16, 1945, near Alamogordo, New Mexico. The glass is primaril ...


References


External links


H. J. Melosh, "Impact geologists, beware!"
(). ''Geophysical Research Letters'', Volume 44, Issue 17, pp. 8873–8874, 2017
Petrified Lightning
by Peter E. Viemeister (PDF)

with artist
Allan McCollum Allan McCollum (born 4 August 1944) is a contemporary American artist who lives and works in New York City. In 1975, his work was included in the Whitney Biennial, and he moved to New York City the same year. In the late 1970s, he became especial ...
along with an historical archive of 66 versions of booklets included in Allan McCollum's exhibition, ''The Event: Petrified Lightning from Central Florida''
Mindat with location data


''American Mineralogist'', Volume 10, pages 152–155, 1925

29th Annual Conference of the Glass Art Society, Tampa, Florida, 1999 {{Authority control Geochemistry Glass in nature Lightning Metamorphic rocks Mineralogy Paleoclimatology