Fukuchilite, , is a
copper
Copper is a chemical element; it has symbol Cu (from Latin ) and atomic number 29. It is a soft, malleable, and ductile metal with very high thermal and electrical conductivity. A freshly exposed surface of pure copper has a pinkish-orang ...
iron
Iron is a chemical element; it has symbol Fe () and atomic number 26. It is a metal that belongs to the first transition series and group 8 of the periodic table. It is, by mass, the most common element on Earth, forming much of Earth's o ...
sulfide
Sulfide (also sulphide in British English) is an inorganic anion of sulfur with the chemical formula S2− or a compound containing one or more S2− ions. Solutions of sulfide salts are corrosive. ''Sulfide'' also refers to large families o ...
named after the Japanese
mineralogist
Mineralogy is a subject of geology specializing in the scientific study of the chemistry, crystal structure, and physical (including optical mineralogy, optical) properties of minerals and mineralized artifact (archaeology), artifacts. Specific s ...
Nobuyo Fukuchi (1877–1934), that occurs in ore bodies of
gypsum
Gypsum is a soft sulfate mineral composed of calcium sulfate Hydrate, dihydrate, with the chemical formula . It is widely mined and is used as a fertilizer and as the main constituent in many forms of plaster, drywall and blackboard or sidewalk ...
-
anhydrite
Anhydrite, or anhydrous calcium sulfate, is a mineral with the chemical formula CaSO4. It is in the orthorhombic crystal system, with three directions of perfect cleavage parallel to the three planes of symmetry. It is not isomorphous with the ...
at the intersection points of small masses of
barite
Baryte, barite or barytes ( or ) is a mineral consisting of barium sulfate (Ba S O4). Baryte is generally white or colorless, and is the main source of the element barium. The ''baryte group'' consists of baryte, celestine (strontium sulfate), ...
,
covellite
Covellite (also known as covelline) is a rare copper sulfide mineral with the formula CuS. This indigo blue mineral is commonly a secondary mineral in limited abundance and although it is not an important ore of copper itself, it is well known ...
,
gypsum
Gypsum is a soft sulfate mineral composed of calcium sulfate Hydrate, dihydrate, with the chemical formula . It is widely mined and is used as a fertilizer and as the main constituent in many forms of plaster, drywall and blackboard or sidewalk ...
and
pyrite
The mineral pyrite ( ), or iron pyrite, also known as fool's gold, is an iron sulfide with the chemical formula Fe S2 (iron (II) disulfide). Pyrite is the most abundant sulfide mineral.
Pyrite's metallic luster and pale brass-yellow hue ...
, and is mostly found in the
Hanawa mine in the
Akita prefecture
is a Prefectures of Japan, prefecture of Japan located in the Tōhoku region of Honshu.Nussbaum, Louis-Frédéric. (2005). "Provinces and prefectures" in ; "Tōhoku" in . Its population is estimated 915,691 as of 1 August 2023 and its geographi ...
of
Honshū
, historically known as , is the largest of the four main islands of Japan. It lies between the Pacific Ocean (east) and the Sea of Japan (west). It is the seventh-largest island in the world, and the second-most populous after the Indonesian ...
,
Japan
Japan is an island country in East Asia. Located in the Pacific Ocean off the northeast coast of the Asia, Asian mainland, it is bordered on the west by the Sea of Japan and extends from the Sea of Okhotsk in the north to the East China Sea ...
where it was first discovered in 1969. It occurs in masses within the third geologic unit of the
Kuroko type deposits within the mine.
As a copper, iron sulfide, it is placed in the same group as
bornite
Bornite, also known as peacock ore, is a sulfide mineral with chemical composition that crystallizes in the orthorhombic system (pseudo-cubic). It is an important copper ore.
Appearance
Bornite has a brown to copper-red color on fresh surfa ...
and
chalcopyrite
Chalcopyrite ( ) is a copper iron sulfide mineral and the most abundant copper ore mineral. It has the chemical formula CuFeS2 and crystallizes in the tetragonal system. It has a brassy to golden yellow color and a Mohs scale, hardness of 3.5 to 4 ...
, and most fukuchilite locations are found in relatively close proximity to these minerals. Fukuchilite was found to have a reflection color very similar to bornite and bright pinkish brown in air, while being a purplish brown in oil. Also, it was found to have a reactivity lower than pyrite, but distinctly higher than bornite. It has a
Mohs hardness
The Mohs scale ( ) of mineral hardness is a qualitative ordinal scale, from 1 to 10, characterizing scratch resistance of mineral
In geology and mineralogy, a mineral or mineral species is, broadly speaking, a solid substance with a fair ...
of 4–6, a
specific gravity
Relative density, also called specific gravity, is a dimensionless quantity defined as the ratio of the density (mass of a unit volume) of a substance to the density of a given reference material. Specific gravity for solids and liquids is nea ...
of 4.9, and a sub metallic luster, composed of 11.1% iron, 37.9% copper, and 51.00% of sulfur.
[Bayliss, Peter. "Crystal Chemistry of Some Minerals Within the Pyrite Group." American Mineralogist 74 (1989): 1168-1176]
It is in the
isotropic
In physics and geometry, isotropy () is uniformity in all orientations. Precise definitions depend on the subject area. Exceptions, or inequalities, are frequently indicated by the prefix ' or ', hence '' anisotropy''. ''Anisotropy'' is also ...
cubic crystal system
In crystallography, the cubic (or isometric) crystal system is a crystal system where the unit cell is in the shape of a cube. This is one of the most common and simplest shapes found in crystals and minerals.
There are three main varieties o ...
with symmetry: (2/m), space group P a3. Much relating to the structure of the mineral is still under debate, and some believe that fukuchilite might actually be a form of
villamaninite ,
Villamaninite Mineral Data
/ref> but fukuchilite currently still holds its mineral status as there is currently not enough evidence to discredit an already accepted and titled mineral.[
]
References
* Terakado, Yasutaka, and Richard J. Walker. "Nd, Sr and Pb Isotopic and REE Geochemical Study of Some Miocene Submarine Hydrothermal Deposits (Kuroko Deposits) in Japan." Contributions to Mineralogy and Petrology 149 (2005): 388-399
{{Refend
Copper minerals
Iron minerals
Pyrite group
Cubic minerals
Minerals in space group 205