Fugitive emissions are
leak
A leak is a way (usually an opening) for fluid to escape a container or fluid-containing system, such as a Water tank, tank or a Ship, ship's Hull (watercraft), hull, through which the contents of the container can escape or outside matter can e ...
s and other irregular releases of gases or
vapor
In physics, a vapor (American English) or vapour (Commonwealth English; American and British English spelling differences#-our, -or, see spelling differences) is a substance in the gas phase at a temperature lower than its critical temperature,R ...
s from a pressurized containment – such as appliances, storage tanks, pipelines, wells, or other pieces of equipment – mostly from industrial activities. In addition to the economic cost of lost commodities, fugitive emissions contribute to local air pollution and may cause further environmental harm. Common industrial gases include
refrigerant
A refrigerant is a working fluid used in the cooling, heating, or reverse cooling/heating cycles of air conditioning systems and heat pumps, where they undergo a repeated phase transition from a liquid to a gas and back again. Refrigerants are ...
s and
natural gas
Natural gas (also fossil gas, methane gas, and gas) is a naturally occurring compound of gaseous hydrocarbons, primarily methane (95%), small amounts of higher alkanes, and traces of carbon dioxide and nitrogen, hydrogen sulfide and helium ...
, while less common examples are
perfluorocarbons,
sulfur hexafluoride, and
nitrogen trifluoride.
Most occurrences of fugitive emissions are small, of no immediate impact, and difficult to detect. Nevertheless due to rapidly expanding activity, even the most strictly regulated gases have accumulated outside of industrial workings to reach measurable levels globally. Fugitive emissions include many poorly understood pathways by which the most potent and long-lived
ozone depleting substances and
greenhouse gases
Greenhouse gases (GHGs) are the gases in the atmosphere that raise the surface temperature of planets such as the Earth. Unlike other gases, greenhouse gases absorb the radiations that a planet emits, resulting in the greenhouse effect. T ...
enter Earth's atmosphere.
In particular, the build-up of a variety of man-made
halogenated gases over the past several decades contributes more than 10% of the
radiative forcing which drives global
climate change
Present-day climate change includes both global warming—the ongoing increase in Global surface temperature, global average temperature—and its wider effects on Earth's climate system. Climate variability and change, Climate change in ...
as of year 2020. Moreover, the ongoing banking of small to large quantities of these gases within consumer appliances, industrial systems, and abandoned equipment throughout the world has all but guaranteed their future emissions for many years to come. Fugitive emissions of
CFCs and
HCFCs from legacy equipment and process uses have continued to hinder recovery of the
stratospheric ozone layer in the years since most production was banned in accordance with the international
Montreal Protocol
The Montreal Protocol on Substances That Deplete the Ozone Layer is an international treaty designed to protect the ozone layer by phasing out the production of numerous substances that are responsible for ozone depletion. It was agreed on 16 ...
.
Similar legacy issues continue to be created at ever-increasing scale with the mining of fossil
hydrocarbons
In organic chemistry, a hydrocarbon is an organic compound consisting entirely of hydrogen and carbon. Hydrocarbons are examples of group 14 hydrides. Hydrocarbons are generally colourless and hydrophobic; their odor is usually faint, and may b ...
, including
gas venting
Gas venting, more specifically known as natural-gas venting or methane venting, is the intentional and controlled release of gases containing alkane hydrocarbons - predominately methane - into Earth's atmosphere.
It is a widely used method for ...
and
fugitive gas emissions from coal mines, oil wells, and gas wells.
Economically depleted mines and wells may be
abandoned or poorly sealed, while properly
decommissioned facilities may experience emission increases following equipment failures or earth disturbances.
Satellite monitoring systems are beginning to be developed and deployed to aid identification of the largest emitters, sometimes known as super-emitters.
Emissions inventory
A detailed inventory of
greenhouse gas emissions
Greenhouse gas (GHG) emissions from human activities intensify the greenhouse effect. This contributes to climate change. Carbon dioxide (), from burning fossil fuels such as coal, petroleum, oil, and natural gas, is the main cause of climate chan ...
from upstream
oil and gas
A fossil fuel is a flammable carbon compound- or hydrocarbon-containing material formed naturally in the Earth's crust from the buried remains of prehistoric organisms (animals, plants or microplanktons), a process that occurs within geologi ...
activities in Canada for the year 2000 estimated that fugitive equipment leaks had a
global warming potential
Global warming potential (GWP) is a measure of how much heat a greenhouse gas traps in the atmosphere over a specific time period, relative to carbon dioxide (). It is expressed as a multiple of warming caused by the same mass of carbon dioxide ( ...
equivalent to the release of 17 million metric tonnes of
carbon dioxide
Carbon dioxide is a chemical compound with the chemical formula . It is made up of molecules that each have one carbon atom covalent bond, covalently double bonded to two oxygen atoms. It is found in a gas state at room temperature and at norma ...
, or 12 percent of all greenhouse gases emitted by the sector, while another report put fugitive emissions at 5.2% of world greenhouse emissions in 2013. Venting of natural gas,
flaring, accidental releases and storage losses accounted for an additional 38 percent.
Fugitive emissions present other risks and hazards. Emissions of
volatile organic compound
Volatile organic compounds (VOCs) are organic compounds that have a high vapor pressure at room temperature. They are common and exist in a variety of settings and products, not limited to Indoor mold, house mold, Upholstery, upholstered furnitur ...
s such as
benzene
Benzene is an Organic compound, organic chemical compound with the Chemical formula#Molecular formula, molecular formula C6H6. The benzene molecule is composed of six carbon atoms joined in a planar hexagonal Ring (chemistry), ring with one hyd ...
from
oil refineries
An oil refinery or petroleum refinery is an industrial process plant where petroleum (crude oil) is transformed and refined into products such as gasoline (petrol), diesel fuel, asphalt base, fuel oils, heating oil, kerosene, liquefied pet ...
and
chemical plants pose a long term health risk to workers and local communities. In situations where large amounts of flammable liquids and gases are contained under pressure, leaks also increase the risk of fire and explosion.
Pressurized equipment
Leaks from pressurized process equipment generally occur through
valve
A valve is a device or natural object that regulates, directs or controls the flow of a fluid (gases, liquids, fluidized solids, or Slurry, slurries) by opening, closing, or partially obstructing various passageways. Valves are technically Pip ...
s,
pipe connections,
mechanical seals, or related equipment. Fugitive emissions also occur at evaporative sources such as
waste water treatment ponds and
storage tanks. Because of the huge number of potential leak sources at large industrial facilities and the difficulties in detecting and repairing some leaks, fugitive emissions can be a significant proportion of total emissions. Though the quantities of leaked gases may be small, gases that have serious health or environmental impacts can cause a significant problem.
Fenceline monitoring
Fenceline monitoring techniques involve the use of samplers and detectors positioned at the fenceline of a facility. Several types of devices are used to provide data on a facility's fugitive emissions, including passive samplers with
sorbent tubes, and "SPod" sensors that provide real-time data.
Detection and repair
To minimize and control leaks at process facilities operators carry out regular leak detection and repair activities. Routine inspections of process equipment with
gas detectors can be used to identify leaks and estimate the leak rate in order to decide on appropriate corrective action. Proper
routine maintenance of equipment reduces the likelihood of leaks.
Because of the technical difficulties and costs of detecting and quantifying actual fugitive emissions at a site or facility, and the variability and intermittent nature of emission flow rates, bottom-up estimates based on standard
emission factors are generally used for annual reporting purposes.
New technologies
New technologies are under development that could revolutionize the detection and monitoring of fugitive emissions. One technology, known as differential absorption
lidar
Lidar (, also LIDAR, an acronym of "light detection and ranging" or "laser imaging, detection, and ranging") is a method for determining ranging, ranges by targeting an object or a surface with a laser and measuring the time for the reflected li ...
(DIAL), can be used to remotely measure concentration profiles of hydrocarbons in the atmosphere up to several hundred meters from a facility. DIAL has been used for refinery surveys in Europe for over 15 years. A pilot study carried out in 2005 using DIAL found that actual emissions at a refinery were fifteen times higher than those previously reported using the emission factor approach. The fugitive emissions were equivalent to 0.17% of the refinery throughput.
Portable gas leak imaging cameras are also a new technology that can be used to improve leak detection and repair, leading to reduced fugitive emissions. The cameras use infrared imaging technology to produce video images in which invisible gases escaping from leak sources can be clearly identified.
Types
Natural gas
See also
*
Gas flare
A gas flare, alternatively known as a flare stack, flare boom, ground flare, or flare pit, is a gas combustion device used in places such as petroleum refineries, chemical plants and natural gas processing plants, oil or gas extraction sites ha ...
*
Greenhouse gas
Greenhouse gases (GHGs) are the gases in the atmosphere that raise the surface temperature of planets such as the Earth. Unlike other gases, greenhouse gases absorb the radiations that a planet emits, resulting in the greenhouse effect. T ...
*
Volatile organic compound
Volatile organic compounds (VOCs) are organic compounds that have a high vapor pressure at room temperature. They are common and exist in a variety of settings and products, not limited to Indoor mold, house mold, Upholstery, upholstered furnitur ...
*
Fugitive gas emissions
References
Works cited
* {{citation , year=2013 , author=IPCC AR5 WG1 , editor=Stocker, T.F. , title=Climate Change 2013: The Physical Science Basis. Working Group 1 (WG1) Contribution to the Intergovernmental Panel on Climate Change (IPCC) 5th Assessment Report (AR5) , url=http://archive.ipcc.ch/report/ar5/wg1/ , publisher=Cambridge University Press , display-editors=etal
Climate Change 2013 Working Group 1 website.
External links
2006 IPCC Guidelines for National Greenhouse Gas Inventories(see Section 4.2).
Air pollution
Greenhouse gas emissions