Gasoline additives may increase
gasoline
Gasoline ( North American English) or petrol ( Commonwealth English) is a petrochemical product characterized as a transparent, yellowish, and flammable liquid normally used as a fuel for spark-ignited internal combustion engines. When for ...
's
octane rating
An octane rating, or octane number, is a standard measure of a liquid fuel, fuel's ability to withstand Compression ratio, compression in an internal combustion engine without causing engine knocking. The higher the octane number, the more compres ...
, thus allowing the use of higher
compression ratio
The compression ratio is the ratio between the maximum and minimum volume during the compression stage of the power cycle in a piston or Wankel engine.
A fundamental specification for such engines, it can be measured in two different ways. Th ...
s for greater efficiency and power, or act as
corrosion inhibitor
A corrosion inhibitor or anti-corrosive is a chemical compound added to a liquid or gas to decrease the corrosion rate of a metal that comes into contact with the fluid. The effectiveness of a corrosion inhibitor depends on fluid composition and ...
s or
lubricant
A lubricant (sometimes shortened to lube) is a substance that helps to reduce friction between surfaces in mutual contact, which ultimately reduces the heat generated when the surfaces move. It may also have the function of transmitting forces, ...
s. Other additives include
metal deactivators,
oxygenates and
antioxidant
Antioxidants are Chemical compound, compounds that inhibit Redox, oxidation, a chemical reaction that can produce Radical (chemistry), free radicals. Autoxidation leads to degradation of organic compounds, including living matter. Antioxidants ...
s.
Some additives are harmful and are regulated or banned in some countries.
Fictional additives
*
Sugar
Sugar is the generic name for sweet-tasting, soluble carbohydrates, many of which are used in food. Simple sugars, also called monosaccharides, include glucose
Glucose is a sugar with the Chemical formula#Molecular formula, molecul ...
, as seen in ''
The Passionate Stranger'' (1957) and
popularly believed to damage the engine.
Additives
*
Oxygenates
**
Alcohol
Alcohol may refer to:
Common uses
* Alcohol (chemistry), a class of compounds
* Ethanol, one of several alcohols, commonly known as alcohol in everyday life
** Alcohol (drug), intoxicant found in alcoholic beverages
** Alcoholic beverage, an alco ...
s:
***
Methanol
Methanol (also called methyl alcohol and wood spirit, amongst other names) is an organic chemical compound and the simplest aliphatic Alcohol (chemistry), alcohol, with the chemical formula (a methyl group linked to a hydroxyl group, often ab ...
(MeOH)
***
Ethanol
Ethanol (also called ethyl alcohol, grain alcohol, drinking alcohol, or simply alcohol) is an organic compound with the chemical formula . It is an Alcohol (chemistry), alcohol, with its formula also written as , or EtOH, where Et is the ps ...
(EtOH); see also
common ethanol fuel mixtures
Several common ethanol fuel mixtures are in use around the world. The use of pure anhydrous, hydrous or anhydrous ethanol in internal combustion engines (ICEs) is only possible if the engines are designed or modified for that purpose, and used o ...
***
Isopropyl alcohol
Isopropyl alcohol (IUPAC name propan-2-ol and also called isopropanol or 2-propanol) is a colorless, flammable, organic compound with a pungent alcoholic odor.
Isopropyl alcohol, an organic polar molecule, is miscible in water, ethanol, an ...
(IPA)
***
''n''-butanol (BuOH)
*** Gasoline grade
''t''-butanol (GTBA)
**
Ether
In organic chemistry, ethers are a class of compounds that contain an ether group, a single oxygen atom bonded to two separate carbon atoms, each part of an organyl group (e.g., alkyl or aryl). They have the general formula , where R and R� ...
s:
***
Methyl tert-butyl ether
Methyl ''tert''-butyl ether (MTBE), also known as ''tert''-butyl methyl ether, is an organic compound with a structural formula (CH3)3COCH3. MTBE is a volatile, flammable, and colorless liquid that is sparingly soluble in water. Primarily used a ...
(MTBE), now outlawed in many states of the
U.S.
The United States of America (USA), also known as the United States (U.S.) or America, is a country primarily located in North America. It is a federal republic of 50 states and a federal capital district, Washington, D.C. The 48 contiguous ...
for road use because of
water contamination.
***
Tertiary amyl methyl ether (TAME)
***
Tertiary hexyl methyl ether (THEME)
***
Ethyl tertiary butyl ether (ETBE)
***
Tertiary amyl ethyl ether (TAEE)
***
Diisopropyl ether
Diisopropyl ether is a secondary ether that is used as a solvent. It is a colorless liquid that is slightly soluble in water, but miscible with organic solvents. It is used as an extractant and an oxygenate gasoline additive. It is obtained i ...
(DIPE)
*
Antioxidant
Antioxidants are Chemical compound, compounds that inhibit Redox, oxidation, a chemical reaction that can produce Radical (chemistry), free radicals. Autoxidation leads to degradation of organic compounds, including living matter. Antioxidants ...
s, stabilizers
**
Butylated hydroxyanisole (BHA)
**
Butylated hydroxytoluene
Butylated hydroxytoluene (BHT), also known as dibutylhydroxytoluene, is a lipophilic organic compound, chemically a derivative of phenol, that is useful for its antioxidant properties. BHT is widely used to prevent free radical-mediated oxidation ...
(BHT)
**
2-tert-Butylphenol
**
3-tert-Butylphenol
**
4-tert-Butylphenol
**
2,4-Dimethyl-6-tert-butylphenol
**
2,6-Di-tert-butylphenol (2,6-DTBP)
**
2,4,6-Tri-tert-butylphenol (2,4,6-TTBP)
**
tert-Butylhydroquinone
''tert''-Butylhydroquinone (TBHQ, tertiary butylhydroquinone, tBHQ) is a synthetic aromatic organic compound which is a type of phenol. It is a derivative of hydroquinone, substituted with a ''tert''- butyl group.
Applications
Food preserva ...
(TBHQ)
**
p-Phenylenediamine
**
N,N'-Di-2-butyl-1,4-phenylenediamine
**
Ethylenediamine
Ethylenediamine (abbreviated as en when a ligand) is the organic compound with the formula C2H4(NH2)2. This colorless liquid with an ammonia-like odor is a basic amine. It is a widely used building block in chemical synthesis, with approximately ...
*
Detergent
A detergent is a surfactant or a mixture of surfactants with Cleanliness, cleansing properties when in Concentration, dilute Solution (chemistry), solutions. There are a large variety of detergents. A common family is the alkylbenzene sulfonate ...
s; see also
Top Tier Detergent Gasoline
**
Amine
In chemistry, amines (, ) are organic compounds that contain carbon-nitrogen bonds. Amines are formed when one or more hydrogen atoms in ammonia are replaced by alkyl or aryl groups. The nitrogen atom in an amine possesses a lone pair of elec ...
s aka "nitrogen enriched"
***
Polybuteneamine (PBA)
***
Polyetheramine (PEA); see also
Techron
Techron is a patented list of gasoline additives, fuel additive developed by Chevron Corporation and sold in its fuel operations (including Texaco and Caltex). It contains polyether amine (PEA) and polybutene amine (PBA), which are detergent addit ...
***
Polyisobutyleneamine (PIBA)
*
Antiknock agent
An antiknock agent (also: knock inhibitor) is a gasoline additive used to reduce engine knocking and increase the fuel's octane rating by raising the temperature and pressure at which auto-ignition occurs. The mixture known as gasoline or petrol, ...
s
**
Tetraethyllead
Tetraethyllead (commonly styled tetraethyl lead), abbreviated TEL, is an organolead compound with the formula lead, Pb(ethyl group, C2H5)4. It was widely used as a fuel additive for much of the 20th century, first being mixed with gasoline begi ...
(TEL), now
banned almost everywhere for
causing brain damage.
**
Methylcyclopentadienyl manganese tricarbonyl (MMT) is a neurotoxic substance and is fatal if swallowed/inhaled and causes
manganism.
**
Ferrocene
Ferrocene is an organometallic chemistry, organometallic compound with the formula . The molecule is a Cyclopentadienyl complex, complex consisting of two Cyclopentadienyl anion, cyclopentadienyl rings sandwiching a central iron atom. It is an o ...
**
Dimethyl methylphosphonate
**
Toluene
Toluene (), also known as toluol (), is a substituted aromatic hydrocarbon with the chemical formula , often abbreviated as , where Ph stands for the phenyl group. It is a colorless, water
Water is an inorganic compound with the c ...
**
Isooctane
**
Triptane
* Lead
scavengers
Scavengers are animals that consume dead organisms that have died from causes other than predation or have been killed by other predators. While scavenging generally refers to carnivores feeding on carrion, it is also a herbivorous feeding ...
(for leaded gasoline)
**
Tricresyl phosphate (TCP) (also an
AW additive and
EP additive)
**
1,2-Dibromoethane
1,2-Dibromoethane, also known as ethylene dibromide (EDB), is an organobromine compound with the chemical formula . Although trace amounts occur naturally in the ocean, where it is probably formed by algae and kelp, substantial amounts are produc ...
**
1,2-Dichloroethane
The chemical compound 1,2-dichloroethane, commonly known as ethylene dichloride (EDC), is a chlorinated hydrocarbon. It is a colourless liquid with a chloroform-like odour. The most common use of 1,2-dichloroethane is in the production of vinyl ...
*
Fuel dyes, most common:
**
Solvent Red 24
**
Solvent Red 26
**
Solvent Yellow 124
**
Solvent Blue 35
* Fuel additives in general
**
Ether
In organic chemistry, ethers are a class of compounds that contain an ether group, a single oxygen atom bonded to two separate carbon atoms, each part of an organyl group (e.g., alkyl or aryl). They have the general formula , where R and R� ...
and other flammable hydrocarbons have been used extensively as
starting fluid for many difficult-to-start engines, especially
diesel engine
The diesel engine, named after the German engineer Rudolf Diesel, is an internal combustion engine in which Combustion, ignition of diesel fuel is caused by the elevated temperature of the air in the cylinder due to Mechanics, mechanical Compr ...
s
**
Nitromethane
Nitromethane, sometimes shortened to simply "nitro", is an organic compound with the chemical formula . It is the simplest organic nitro compound. It is a polar liquid commonly used as a solvent in a variety of industrial applications such as in ...
, or "nitro", is a high-performance racing fuel
**
Acetone
Acetone (2-propanone or dimethyl ketone) is an organic compound with the chemical formula, formula . It is the simplest and smallest ketone (). It is a colorless, highly Volatile organic compound, volatile, and flammable liquid with a charact ...
is a
vaporization
Vaporization (or vapo(u)risation) of an element or compound is a phase transition from the liquid phase to vapor. There are two types of vaporization: evaporation and boiling. Evaporation is a surface phenomenon, whereas boiling is a bulk phenome ...
additive, mainly used with
methanol
Methanol (also called methyl alcohol and wood spirit, amongst other names) is an organic chemical compound and the simplest aliphatic Alcohol (chemistry), alcohol, with the chemical formula (a methyl group linked to a hydroxyl group, often ab ...
racing fuel
**
Butyl rubber
Butyl rubber, sometimes just called butyl, is a synthetic rubber, a copolymer of isobutylene with isoprene. The abbreviation IIR stands for isobutylene isoprene rubber. Polyisobutylene, also known as "PIB" or polyisobutene, (C4H8)n, is the homop ...
(as polyisobutylene succinimide,
detergent
A detergent is a surfactant or a mixture of surfactants with Cleanliness, cleansing properties when in Concentration, dilute Solution (chemistry), solutions. There are a large variety of detergents. A common family is the alkylbenzene sulfonate ...
to prevent fouling of
diesel fuel injectors)
** Ferrous
picrate, used in diesel fuel to increase fuel conversion efficiency and reduce emissions
**
Two-stroke oil, for lubrication of
small engines reliant on crankcase compression
** Upper cylinder lubricant, extensively advertised but of unproven value
Racing formulations
*
Nitromethane
Nitromethane, sometimes shortened to simply "nitro", is an organic compound with the chemical formula . It is the simplest organic nitro compound. It is a polar liquid commonly used as a solvent in a variety of industrial applications such as in ...
can increase the
cetane number of diesel fuel, improving its combustion properties
*
Nitrous oxide
Nitrous oxide (dinitrogen oxide or dinitrogen monoxide), commonly known as laughing gas, nitrous, or factitious air, among others, is a chemical compound, an Nitrogen oxide, oxide of nitrogen with the Chemical formula, formula . At room te ...
, or simply ''
nitrous'', is an
oxidizer
An oxidizing agent (also known as an oxidant, oxidizer, electron recipient, or electron acceptor) is a substance in a redox chemical reaction that gains or " accepts"/"receives" an electron from a (called the , , or ''electron donor''). In ot ...
used in many forms of
motorsports
Motorsport or motor sport are sporting events, competitions and related activities that primarily involve the use of automobiles, motorcycles, motorboats and powered aircraft
An aircraft engine, often referred to as an aero engine, is the po ...
such as
drag racing
Drag racing is a type of motor racing in which automobiles or motorcycles compete, usually two at a time, to be first to cross a set finish line. The race follows a short, straight course from a standing start over a measured distance, mos ...
and
street racing
Street racing is an illegal form of motor racing that occurs on a public road. Racing in the streets is considered an ancient hazard, as horse racing occurred on streets for centuries, and street racing in automobiles is likely as old as the a ...
.
Legislation
United States
Fuel additives in the
United States
The United States of America (USA), also known as the United States (U.S.) or America, is a country primarily located in North America. It is a federal republic of 50 U.S. state, states and a federal capital district, Washington, D.C. The 48 ...
are regulated unde
section 211of the
Clean Air Act (as amended in January 1995). The
Environmental Protection Agency (EPA) requires the registration of all fuel additives which are commercially distributed for use in highway motor vehicles in the
United States
The United States of America (USA), also known as the United States (U.S.) or America, is a country primarily located in North America. It is a federal republic of 50 U.S. state, states and a federal capital district, Washington, D.C. The 48 ...
, and may require testing and ban harmful additives. The EPA also regularly reviews the health and net economic benefits of Clean Air Act policies.
Benefits and Costs of the Clean Air Act: a set of scientific reviews conducted by the United States Environmental Protection Agency, U.S. Environmental Protection Agency in compliance with the act.
The act also requires deposit control additives (DCAs) be added to all petrol. This type of additive is a detergent
A detergent is a surfactant or a mixture of surfactants with Cleanliness, cleansing properties when in Concentration, dilute Solution (chemistry), solutions. There are a large variety of detergents. A common family is the alkylbenzene sulfonate ...
additive that acts as a cleansing agent in small passages in the carburetor
A carburetor (also spelled carburettor or carburetter)
is a device used by a gasoline internal combustion engine to control and mix air and fuel entering the engine. The primary method of adding fuel to the intake air is through the Ventu ...
or fuel injectors. This in turn serves to ensure a consistent air and fuel mixture that will contribute to better gas mileage.
See also
*metering pump
A metering pump moves a precise volume of liquid in a specified time period providing an accurate volumetric flow rate.
Delivery of fluids in precise adjustable flow rates is sometimes called metering. The term "metering pump" is based on the ap ...
s
*Oil additive
Oil additives are chemical compounds that improve the lubricant performance of base oil (or oil "base stock"). The manufacturer of many oils can use the same base stock for each formulation and can choose different additives for each use. Additives ...
*Greenwashing
Greenwashing (a compound word modeled on "whitewash"), also called green sheen, is a form of advertising or marketing spin that deceptively uses green PR and green marketing to persuade the public that an organization's products, goals, or ...
References
* ARRC Auto Repair Reference Center. Point 5 Technologies. Accessed via EbscoHost on November 27, 2009
EPA: List of Registered Gasoline Additives
Under 40 CFR Part 79
{{DEFAULTSORT:Gasoline Additive
Petroleum products
Chemistry-related lists