Freon ( ) is a registered
trademark
A trademark (also written trade mark or trade-mark) is a type of intellectual property consisting of a recognizable sign, design, or expression that identifies products or services from a particular source and distinguishes them from oth ...
of
the Chemours Company
Chemours (, ) is an American chemical company that was founded in July 2015 as a spin-off from DuPont
DuPont de Nemours, Inc., commonly shortened to DuPont, is an American multinational chemical company first formed in 1802 by French-Amer ...
and generic descriptor for a number of
halocarbon products. They are stable, nonflammable, low toxicity
gases or liquids which have generally been used as
refrigerants
A refrigerant is a working fluid used in the refrigeration cycle of air conditioning systems and heat pumps where in most cases they undergo a repeated phase transition from a liquid to a gas and back again. Refrigerants are heavily regulated ...
and as
aerosol propellant
Aerosol spray is a type of dispensing system which creates an aerosol mist of liquid particles. It comprises a can or bottle that contains a payload, and a propellant under pressure. When the container's valve is opened, the payload is forced out ...
s. These include the
chlorofluorocarbon
Chlorofluorocarbons (CFCs) and hydrochlorofluorocarbons (HCFCs) are fully or partly halogenated hydrocarbons that contain carbon (C), hydrogen (H), chlorine (Cl), and fluorine (F), produced as volatile derivatives of methane, ethane, and pro ...
s (CFCs) that cause
ozone depletion and HCFCs (such as
chlorodifluoromethane). Not all refrigerants of this type are labelled as "Freon" since Freon is a brand name for the refrigerants
R-12,
R-13B1,
R-22,
R-410A, R-502, and R-503 manufactured by The Chemours Company. Freon emits a strong chemical smell similar to
acetone
Acetone (2-propanone or dimethyl ketone), is an organic compound with the formula . It is the simplest and smallest ketone (). It is a colorless, highly volatile and flammable liquid with a characteristic pungent odour.
Acetone is miscible wi ...
, a
nail polish remover
Nail polish (also known as nail varnish or nail enamel) is a lacquer that can be applied to the human fingernail or toenails to decorate and protect the nail plates. The formula has been revised repeatedly to enhance its decorative properties ...
component.
History
The first CFCs were synthesized by
Frédéric Swarts
Frédéric Swarts (2 September 1866 – 6 September 1940) was a Belgian chemist
A chemist (from Greek ''chēm(ía)'' alchemy; replacing ''chymist'' from Medieval Latin ''alchemist'') is a scientist trained in the study of chemistry. Chemist ...
in the 1890s. In the late 1920s, a research team was formed by
Charles Franklin Kettering
Charles Franklin Kettering (August 29, 1876 – November 25, 1958) sometimes known as Charles Fredrick Kettering was an American inventor, engineer, businessman, and the holder of 186 patents.
For the list of patents issued to Kettering, see, Le ...
in
General Motors to find a replacement for the dangerous refrigerants then in use, such as
ammonia
Ammonia is an inorganic compound of nitrogen and hydrogen with the formula . A stable binary hydride, and the simplest pnictogen hydride, ammonia is a colourless gas with a distinct pungent smell. Biologically, it is a common nitrogeno ...
. The team was headed by
Thomas Midgley, Jr.
In 1928, they improved the synthesis of CFCs and demonstrated their usefulness for such a purpose and their stability and nontoxicity. Kettering patented a refrigerating apparatus to use the gas; this was issued to
Frigidaire, a wholly owned subsidiary of
General Motors.
In 1930, General Motors and
DuPont formed
Kinetic Chemicals
Polytetrafluoroethylene (PTFE) is a synthetic fluoropolymer of tetrafluoroethylene that has numerous applications. It is one of the best-known and widely applied PFAS. The commonly known brand name of PTFE-based composition is Teflon by Chemour ...
to produce Freon. Their product was
dichlorodifluoromethane
Dichlorodifluoromethane (R-12) is a colorless gas usually sold under the brand name Freon-12, and a chlorofluorocarbon halomethane (CFC) used as a refrigerant and aerosol spray propellant. Complying with the Montreal Protocol, its manufacture w ...
and is now designated "Freon-12", "R-12", or "CFC-12". The number after the R is a
refrigerant class number developed by DuPont to systematically identify single halogenated hydrocarbons, as well as other refrigerants besides halocarbons.
Most uses of CFCs are now banned or severely restricted by the
Montreal Protocol
The Montreal Protocol is an international treaty
A treaty is a formal, legally binding written agreement between actors in international law. It is usually made by and between sovereign states, but can include international organization ...
of August 1987, as they have been shown to be responsible for
ozone depletion. Brands of freon containing
hydrofluorocarbons (HFCs) instead have replaced many uses, but they, too, are under strict control under the
Kyoto Protocol
The Kyoto Protocol was an international treaty which extended the 1992 United Nations Framework Convention on Climate Change (UNFCCC) that commits state parties to reduce greenhouse gas emissions, based on the scientific consensus that (par ...
, as they are deemed "super-greenhouse effect" gases.
See also
*
Chlorodifluoromethane (R-22 or HCFC-22), a type of Freon.
*
Dichlorodifluoromethane
Dichlorodifluoromethane (R-12) is a colorless gas usually sold under the brand name Freon-12, and a chlorofluorocarbon halomethane (CFC) used as a refrigerant and aerosol spray propellant. Complying with the Montreal Protocol, its manufacture w ...
(R-12 or CFC-12), the most commonly used Freon brand refrigerant prior to its ban in many countries in 1996 and total ban in 2010.
*
1,1,1,2-Tetrafluoroethane
1,1,1,2-Tetrafluoroethane (also known as norflurane (INN), R-134a, Freon 134a, Forane 134a, Genetron 134a, Green Gas, Florasol 134a, Suva 134a, or HFC-134a) is a hydrofluorocarbon (HFC) and haloalkane refrigerant with thermodynamic properties ...
(R-134a or HCFC-134a), one of the main replacements for the formerly widespread R-12.
*
Opteon halogenated
olefins now replacing Freons in many applications.
References
Refrigerants
Chemours
DuPont products
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