Forge Welding
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Forge welding (FOW), also called fire welding, is a solid-state
welding Welding is a fabrication (metal), fabrication process that joins materials, usually metals or thermoplastics, primarily by using high temperature to melting, melt the parts together and allow them to cool, causing Fusion welding, fusion. Co ...
process that joins two pieces of
metal A metal () is a material that, when polished or fractured, shows a lustrous appearance, and conducts electrical resistivity and conductivity, electricity and thermal conductivity, heat relatively well. These properties are all associated wit ...
by heating them to a high temperature and then
hammer A hammer is a tool, most often a hand tool, consisting of a weighted "head" fixed to a long handle that is swung to deliver an impact to a small area of an object. This can be, for example, to drive nail (fastener), nails into wood, to sh ...
ing them together. It may also consist of heating and forcing the metals together with presses or other means, creating enough pressure to cause
plastic deformation In engineering, deformation (the change in size or shape of an object) may be ''elastic'' or ''plastic''. If the deformation is negligible, the object is said to be ''rigid''. Main concepts Occurrence of deformation in engineering application ...
at the weld surfaces. The process, although challenging, has been a method of joining metals used since ancient times and is a staple of traditional
blacksmith A blacksmith is a metalsmith who creates objects primarily from wrought iron or steel, but sometimes from #Other metals, other metals, by forging the metal, using tools to hammer, bend, and cut (cf. tinsmith). Blacksmiths produce objects such ...
ing. Forge welding is versatile, being able to join a host of similar and dissimilar metals. With the invention of electrical welding and
gas welding Principle of burn cutting Oxy-fuel welding (commonly called oxyacetylene welding, oxy welding, or gas welding in the United States) and oxy-fuel cutting are processes that use fuel gases (or liquid fuels such as gasoline or petrol, diesel, bio ...
methods during the
Industrial Revolution The Industrial Revolution, sometimes divided into the First Industrial Revolution and Second Industrial Revolution, was a transitional period of the global economy toward more widespread, efficient and stable manufacturing processes, succee ...
, manual forge-welding has been largely replaced, although automated forge-welding is a common manufacturing process.


Introduction

Forge welding is a process of joining metals by heating them beyond a certain threshold and forcing them together with enough pressure to cause deformation of the weld surfaces, creating a
metallic bond Metallic bonding is a type of chemical bonding that arises from the electrostatic attractive force between conduction electrons (in the form of an electron cloud of delocalized electrons) and positively charged metal ions. It may be descr ...
between the atoms of the metals. The pressure required varies, depending on the temperature,
strength Strength may refer to: Personal trait *Physical strength, as in people or animals *Character strengths like those listed in the Values in Action Inventory *The exercise of willpower Physics * Mechanical strength, the ability to withstand ...
, and
hardness In materials science, hardness (antonym: softness) is a measure of the resistance to plastic deformation, such as an indentation (over an area) or a scratch (linear), induced mechanically either by Pressing (metalworking), pressing or abrasion ...
of the
alloy An alloy is a mixture of chemical elements of which in most cases at least one is a metal, metallic element, although it is also sometimes used for mixtures of elements; herein only metallic alloys are described. Metallic alloys often have prop ...
. Forge welding is the oldest welding technique, and has been used since ancient times. Welding processes can generally be grouped into two categories: fusion and
diffusion Diffusion is the net movement of anything (for example, atoms, ions, molecules, energy) generally from a region of higher concentration to a region of lower concentration. Diffusion is driven by a gradient in Gibbs free energy or chemical p ...
welding.
Fusion welding Fusion welding is a generic term for welding processes that rely on melting to join materials of similar compositions and melting points. Due to the high-temperature phase transitions inherent to these processes, a heat-affected zone is created ...
involves localized melting of the metals at the weld interfaces, and is common in electric or gas welding techniques. This requires temperatures much higher than the
melting point The melting point (or, rarely, liquefaction point) of a substance is the temperature at which it changes state of matter, state from solid to liquid. At the melting point the solid and liquid phase (matter), phase exist in Thermodynamic equilib ...
of the metal in order to cause localized melting before the heat can thermally conduct away from the weld, and often a filler metal is used to keep the weld from segregating due to the high
surface tension Surface tension is the tendency of liquid surfaces at rest to shrink into the minimum surface area possible. Surface tension (physics), tension is what allows objects with a higher density than water such as razor blades and insects (e.g. Ge ...
. Diffusion welding consists of joining the metals without melting them, welding the surfaces together while in the solid state. In diffusion welding, the heat source is often lower than the melting point of the metal, allowing more even heat-distribution thus reducing
thermal stress In mechanics and thermodynamics, thermal stress is mechanical stress created by any change in temperature Temperature is a physical quantity that quantitatively expresses the attribute of hotness or coldness. Temperature is measurement, m ...
es at the weld. In this method a filler metal is typically not used, but the weld occurs directly between the metals at the weld interface. This includes methods such as
cold welding Cold welding or contact welding is a solid-state welding process in which joining takes place without fusion or heating at the interface of the two parts to be welded. Unlike in fusion welding, no liquid or molten phase is present in the join ...
, explosion welding, and forge welding. Unlike other diffusion methods, in forge welding the metals are heated to a high temperature before forcing them together, usually resulting in greater plasticity at the weld surfaces. This generally makes forge welding more versatile than cold-diffusion techniques, which are usually performed on soft metals like copper or aluminum. In forge welding, the entire welding areas are heated evenly. Forge welding can be used for a much wider range of harder metals and alloys, like steel and titanium.


History

The history of joining metals goes back to the
Bronze Age The Bronze Age () was a historical period characterised principally by the use of bronze tools and the development of complex urban societies, as well as the adoption of writing in some areas. The Bronze Age is the middle principal period of ...
, where bronzes of different hardness were often joined by casting-in. This method consisted of placing a solid part into a molten metal contained in a mold and allowing it to solidify without actually melting both metals, such as the blade of a sword into a handle or the tang of an arrowhead into the tip.
Brazing Brazing is a metal-joining process in which two or more metal items are joined by melting and flowing a filler metal into the joint, with the filler metal having a lower melting point than the adjoining metal. Brazing differs from welding in ...
and
soldering Soldering (; ) is a process of joining two metal surfaces together using a filler metal called solder. The soldering process involves heating the surfaces to be joined and melting the solder, which is then allowed to cool and solidify, creatin ...
were also common during the Bronze Age. The act of welding (joining two solid parts through diffusion) began with iron. The first welding process was forge welding, which started when humans learned to smelt iron from
iron ore Iron ores are rocks and minerals from which metallic iron can be economically extracted. The ores are usually rich in iron oxides and vary in color from dark grey, bright yellow, or deep purple to rusty red. The iron is usually found in the f ...
; most likely in
Anatolia Anatolia (), also known as Asia Minor, is a peninsula in West Asia that makes up the majority of the land area of Turkey. It is the westernmost protrusion of Asia and is geographically bounded by the Mediterranean Sea to the south, the Aegean ...
(Turkey) around 1800 BC. Ancient people could not create temperatures high enough to melt iron fully, so the
bloomery A bloomery is a type of metallurgical furnace once used widely for smelting iron from its iron oxides, oxides. The bloomery was the earliest form of smelter capable of smelting iron. Bloomeries produce a porous mass of iron and slag called ...
process that was used for smelting iron produced a lump (bloom) of iron grains
sintered Sintering or frittage is the process of compacting and forming a solid mass of material by pressure or heat without melting it to the point of liquefaction. Sintering happens as part of a manufacturing process used with metals, ceramics, pla ...
together with small amounts of
slag The general term slag may be a by-product or co-product of smelting (pyrometallurgical) ores and recycled metals depending on the type of material being produced. Slag is mainly a mixture of metal oxides and silicon dioxide. Broadly, it can be c ...
and other impurities, referred to as sponge iron because of its
porosity Porosity or void fraction is a measure of the void (i.e. "empty") spaces in a material, and is a fraction of the volume of voids over the total volume, between 0 and 1, or as a percentage between 0% and 100%. Strictly speaking, some tests measure ...
. After smelting, the sponge iron needed to be heated above the welding temperature and hammered, or "wrought." This squeezed out air pockets and melted slag, bringing the iron grains into close contact to form a solid block (billet). Many items made of
wrought iron Wrought iron is an iron alloy with a very low carbon content (less than 0.05%) in contrast to that of cast iron (2.1% to 4.5%), or 0.25 for low carbon "mild" steel. Wrought iron is manufactured by heating and melting high carbon cast iron in an ...
have been found by archeologists, that show evidence of forge welding, which date from before 1000 BC. Because iron was typically made in small amounts, any large object, such as the Delhi Pillar, needed to be forge welded out of smaller billets. Forge welding grew from a trial-and-error method, becoming more refined over the centuries. Due to the poor quality of ancient metals, it was commonly employed in making composite steels, by joining high-carbon steels, that would resist deformation but break easily, with low-carbon steels, which resist fracture but bend too easily, creating an object with greater
toughness In materials science and metallurgy, toughness is the ability of a material to absorb energy and plastically deform without fracturing.strength Strength may refer to: Personal trait *Physical strength, as in people or animals *Character strengths like those listed in the Values in Action Inventory *The exercise of willpower Physics * Mechanical strength, the ability to withstand ...
than could be produced with a single alloy. This method of pattern welding first appeared around 700 BC, and was primarily used for making weapons such as swords; the most widely known examples being Damascene, Japanese and Merovingian. ''The History of Hardening'' by Hans Berns -- Harterei Gerster AG 2013 Page 48--49 This process was also common in the manufacture of tools, from wrought-iron
plow A plough or (Differences between American and British spellings, US) plow (both pronounced ) is a farm tool for loosening or turning the soil before sowing seed or planting. Ploughs were traditionally drawn by oxen and horses but modern ploughs ...
s with steel edges to iron
chisel A chisel is a hand tool with a characteristic Wedge, wedge-shaped cutting edge on the end of its blade. A chisel is useful for carving or cutting a hard material such as woodworking, wood, lapidary, stone, or metalworking, metal. Using a chi ...
s with steel cutting surfaces.


Materials

Many metals can be forge welded, with the most common being both high and low-
carbon steel Carbon steel is a steel with carbon content from about 0.05 up to 2.1 percent by weight. The definition of carbon steel from the American Iron and Steel Institute (AISI) states: * no minimum content is specified or required for chromium, cobalt ...
s.
Iron Iron is a chemical element; it has symbol Fe () and atomic number 26. It is a metal that belongs to the first transition series and group 8 of the periodic table. It is, by mass, the most common element on Earth, forming much of Earth's o ...
and even some hypoeutectic
cast-iron Cast iron is a class of iron–carbon alloys with a carbon content of more than 2% and silicon content around 1–3%. Its usefulness derives from its relatively low melting temperature. The alloying elements determine the form in which its car ...
s can be forge welded. Some
aluminum alloy An aluminium alloy ( UK/IUPAC) or aluminum alloy ( NA; see spelling differences) is an alloy in which aluminium (Al) is the predominant metal. The typical alloying elements are copper, magnesium, manganese, silicon, tin, nickel and zinc. There ...
s can also be forge welded. Metals such as
copper Copper is a chemical element; it has symbol Cu (from Latin ) and atomic number 29. It is a soft, malleable, and ductile metal with very high thermal and electrical conductivity. A freshly exposed surface of pure copper has a pinkish-orang ...
,
bronze Bronze is an alloy consisting primarily of copper, commonly with about 12–12.5% tin and often with the addition of other metals (including aluminium, manganese, nickel, or zinc) and sometimes non-metals (such as phosphorus) or metalloid ...
and
brass Brass is an alloy of copper and zinc, in proportions which can be varied to achieve different colours and mechanical, electrical, acoustic and chemical properties, but copper typically has the larger proportion, generally copper and zinc. I ...
do not forge weld readily. Although it is possible to forge weld copper-based
alloy An alloy is a mixture of chemical elements of which in most cases at least one is a metal, metallic element, although it is also sometimes used for mixtures of elements; herein only metallic alloys are described. Metallic alloys often have prop ...
s, it is often with great difficulty due to copper's tendency to absorb oxygen during the heating. Copper and its alloys are usually better joined with
cold welding Cold welding or contact welding is a solid-state welding process in which joining takes place without fusion or heating at the interface of the two parts to be welded. Unlike in fusion welding, no liquid or molten phase is present in the join ...
, explosion welding, or other pressure-welding techniques. With iron or steel, the presence of even small amounts of copper severely reduces the alloy's ability to forge weld.
Titanium Titanium is a chemical element; it has symbol Ti and atomic number 22. Found in nature only as an oxide, it can be reduced to produce a lustrous transition metal with a silver color, low density, and high strength, resistant to corrosion in ...
alloys are commonly forge welded. Because of titanium's tendency to absorb oxygen when molten, the solid-state, diffusion bond of a forge weld is often stronger than a fusion weld in which the metal is liquefied. Forge welding between similar materials is caused by solid-state diffusion. This results in a weld that consists of only the welded materials without any fillers or bridging materials. Forge welding between dissimilar materials is caused by the formation of a lower melting temperature eutectic between the materials. Due to this the weld is often stronger than the individual metals.


Processes

The most well-known and oldest forge-welding process is the manual-hammering method. Manual hammering is done by heating the metal to the proper temperature, coating with flux, overlapping the weld surfaces, and then striking the joint repeatedly with a hand-held
hammer A hammer is a tool, most often a hand tool, consisting of a weighted "head" fixed to a long handle that is swung to deliver an impact to a small area of an object. This can be, for example, to drive nail (fastener), nails into wood, to sh ...
. The joint is often formed to allow space for the
flux Flux describes any effect that appears to pass or travel (whether it actually moves or not) through a surface or substance. Flux is a concept in applied mathematics and vector calculus which has many applications in physics. For transport phe ...
to flow out, by beveling or rounding the surfaces slightly, and hammered in a successively outward fashion to squeeze the flux out. The hammer blows are typically not as hard as those used for shaping, preventing the flux from being blasted out of the joint at the first blow. When mechanical hammers were developed, forge welding could be accomplished by heating the metal, and then placing it between the mechanized hammer and the anvil. Originally powered by
waterwheel A water wheel is a machine for converting the kinetic energy of flowing or falling water into useful forms of power, often in a watermill. A water wheel consists of a large wheel (usually constructed from wood or metal), with numerous blade ...
s, modern mechanical-hammers can also be operated by compressed air, electricity, steam, gas engines, and many other ways. Another method is forge welding with a die, whereby the pieces of metal are heated and then forced into a die which both provides the pressure for the weld and keeps the joint at the finished shape. Roll welding is another forge welding process, where the heated metals are overlapped and passed through rollers at high pressures to create the weld. Modern forge-welding is often automated, using computers, machines, and sophisticated
hydraulic press A hydraulic press is a machine press using a hydraulic cylinder to generate a compressive force. It uses the hydraulic equivalent of a mechanical lever, and was also known as a Bramah press after the inventor, Joseph Bramah, of England. He inven ...
es to produce a variety of products from a number of various alloys. For example, steel pipe is often forge-welded during the manufacturing process. Flat stock is heated and fed through specially-shaped rollers that both form the steel into a tube and simultaneously provide the pressure to weld the edges into a continuous seam. Diffusion bonding is a common method for forge welding titanium alloys in the aerospace industry. In this process the metal is heated while in a press or die. Beyond a specific critical-temperature, which varies depending on the alloy, the impurities burn out and the surfaces are forced together. Other methods include
flash welding Flash welding is a type of resistance welding that does not use any filler metals. The pieces of metal to be welded are set apart at a predetermined distance based on material thickness, material composition, and desired Material properties, prope ...
and percussion welding. These are resistance forge-welding techniques where the press or die is electrified, passing high current through the alloy to create the heat for the weld. Shielded active-gas forge-welding is a process of forge welding in an oxygen-reactive environment, to burn out oxides, using
hydrogen Hydrogen is a chemical element; it has chemical symbol, symbol H and atomic number 1. It is the lightest and abundance of the chemical elements, most abundant chemical element in the universe, constituting about 75% of all baryon, normal matter ...
gas and
induction heating Induction heating is the process of heating electrically conductive materials, namely metals or semi-conductors, by electromagnetic induction, through heat transfer passing through an inductor that creates an electromagnetic field within the coi ...
.


Temperature

Iron, different steels, and even
cast-iron Cast iron is a class of iron–carbon alloys with a carbon content of more than 2% and silicon content around 1–3%. Its usefulness derives from its relatively low melting temperature. The alloying elements determine the form in which its car ...
can be welded to each other, provided that their carbon content is close enough that the welding ranges overlap. Pure iron can be welded when nearly white hot; between and . Steel with a carbon content of 2.0% can be welded when orangish-yellow, between and . Common steel, between 0.2 and 0.8% carbon, is typically welded at a bright yellow heat. A primary requirement for forge welding is that both weld surfaces need to be heated to the same temperature and welded before they cool too much. When steel reaches the proper temperature, it begins to weld very readily, so a thin rod or nail heated to the same temperature will tend to stick at first contact, requiring it to be bent or twisted loose. Care must be taken to avoid overheating the metal to the point that it gives off sparks from rapid oxidation (burning), or else the weld will be poor and brittle.


Decarburization

When steel is heated to an austenizing temperature, the carbon begins to diffuse through the iron. The higher the temperature; the greater the rate of diffusion. At such high temperatures, carbon readily combines with oxygen to form
carbon dioxide Carbon dioxide is a chemical compound with the chemical formula . It is made up of molecules that each have one carbon atom covalent bond, covalently double bonded to two oxygen atoms. It is found in a gas state at room temperature and at norma ...
, so the carbon can easily diffuse out of the steel and into the surrounding air. By the end of a blacksmithing job, the steel will be of a lower carbon content than it was prior to heating. Therefore, most blacksmithing operations are done as quickly as possible to reduce decarburization, preventing the steel from becoming too soft. To produce the right amount of hardness in the finished product, the smith generally begins with steel that has a carbon content that is higher than desired. In ancient times, forging often began with steel that had a carbon content much too high for normal use. Most ancient forge-welding began with hypereutectoid steel, containing a carbon content sometimes well above 1.0%. Hypereutectoid steels are typically too brittle to be useful in a finished product, but by the end of forging the steel typically had a high carbon-content ranging from 0.8% (eutectoid tool-steel) to 0.5% (hypoeutectoid spring-steel).


Applications

Forge welding has been used throughout its history for making most any items out of steel and iron. It has been used in everything from the manufacture of tools, farming implements, and cookware to the manufacture of fences, gates, and prison cells. In the early Industrial Revolution, it was commonly used in the manufacture of boilers and pressure vessels, until the introduction of fusion-welding. It was commonly used through the Middle Ages for producing armor and weapons. One of the most famous applications of forge welding involves the production of pattern-welded blades. During this process a smith repeatedly draws out a
billet In European militaries, a billet is a living-quarters to which a soldier is assigned to sleep. In American usage, it refers to a specific personnel position, assignment, or duty station to which a soldier can be assigned. Historically, a billet w ...
of steel, folds it back and welds it upon itself. Another application was the manufacture of shotgun barrels. Metal wire was spooled onto a
mandrel A mandrel, mandril, or arbor is a tapered tool against which material can be forged, pressed, stretched or shaped (e.g., a ring mandrel - also called a triblet - used by jewellers to increase the diameter of a wedding ring), or a flanged or t ...
, and then forged into a barrel that was thin, uniform, and strong. In some cases the forge-welded objects are acid- etched to expose the underlying pattern of metal, which is unique to each item and provides aesthetic appeal. Despite its diversity, forge welding had many limitations. A primary limitation was the size of objects that could be forge welded. Larger objects required a bigger heat source, and size reduced the ability to manually weld it together before it cooled too much. Welding large items like steel plate or girders was typically not possible, or at least highly impractical, until the invention of fusion welding, requiring them to be riveted instead. In some cases, fusion welding produced a much stronger weld, such as in the construction of boilers.


Flux

Forge welding requires the weld surfaces to be extremely clean or the metal will not join properly, if at all. Oxides tend to form on the surface while impurities like
phosphorus Phosphorus is a chemical element; it has Chemical symbol, symbol P and atomic number 15. All elemental forms of phosphorus are highly Reactivity (chemistry), reactive and are therefore never found in nature. They can nevertheless be prepared ar ...
and
sulfur Sulfur ( American spelling and the preferred IUPAC name) or sulphur ( Commonwealth spelling) is a chemical element; it has symbol S and atomic number 16. It is abundant, multivalent and nonmetallic. Under normal conditions, sulfur atoms ...
tend to migrate to the surface. Often a
flux Flux describes any effect that appears to pass or travel (whether it actually moves or not) through a surface or substance. Flux is a concept in applied mathematics and vector calculus which has many applications in physics. For transport phe ...
is used to keep the welding surfaces from
oxidizing Redox ( , , reduction–oxidation or oxidation–reduction) is a type of chemical reaction in which the oxidation states of the reactants change. Oxidation is the loss of electrons or an increase in the oxidation state, while reduction is ...
, which would produce a poor quality weld, and to extract other impurities from the metal. The flux mixes with the
oxides An oxide () is a chemical compound containing at least one oxygen atom and one other element in its chemical formula. "Oxide" itself is the dianion (anion bearing a net charge of −2) of oxygen, an O2− ion with oxygen in the oxidation state o ...
that form and lowers the melting temperature and the
viscosity Viscosity is a measure of a fluid's rate-dependent drag (physics), resistance to a change in shape or to movement of its neighboring portions relative to one another. For liquids, it corresponds to the informal concept of ''thickness''; for e ...
of the oxides. This enables the oxides to flow out of the joint when the two pieces are beaten together. A simple flux can be made from
borax The BORAX Experiments were a series of safety experiments on boiling water nuclear reactors conducted by Argonne National Laboratory in the 1950s and 1960s at the National Reactor Testing Station in eastern Idaho.
, sometimes with the addition of powdered iron-filings. The oldest flux used for forge welding was fine
silica sand Sand casting, also known as sand molded casting, is a metal casting process characterized by using sand—known as ''casting sand''—as the mold (manufacturing), mold material. The term "sand casting" can also refer to an object produced via th ...
. The iron or steel would be heated in a
reducing environment A reducing atmosphere is an atmosphere in which oxidation is prevented by the absence of oxygen and other oxidizing gases or vapours, and which may contain actively reductant gases such as hydrogen, carbon monoxide, methane and hydrogen sulfide ...
within the coals of the forge. Devoid of oxygen, the metal forms a layer of iron-oxide called
wüstite Wüstite ( Fe O, sometimes also written as Fe0.95O) is a mineral form of mostly iron(II) oxide found with meteorites and native iron. It has a grey colour with a greenish tint in reflected light. Wüstite crystallizes in the isometric-hexoc ...
on its surface. When the metal is hot enough, but below the welding temperature, the smith sprinkles some sand onto the metal. The
silicon Silicon is a chemical element; it has symbol Si and atomic number 14. It is a hard, brittle crystalline solid with a blue-grey metallic lustre, and is a tetravalent metalloid (sometimes considered a non-metal) and semiconductor. It is a membe ...
in the sand reacts with the wustite to form
fayalite Fayalite (, commonly abbreviated to Fa) is the iron-rich endmember, end-member of the olivine solid solution, solid-solution series. In common with all minerals in the olivine, olivine group, fayalite crystallizes in the orthorhombic system (spac ...
, which melts just below the welding temperature. This produced a very effective flux which helped to make a strong weld.''Iron and Steel in Ancient Times'' By Vagn Fabritius Buchwald -- Det Kongelige Danske Videnskabernes Selskab 2005 Page 65 Early examples of flux used different combinations and various amounts of
iron Iron is a chemical element; it has symbol Fe () and atomic number 26. It is a metal that belongs to the first transition series and group 8 of the periodic table. It is, by mass, the most common element on Earth, forming much of Earth's o ...
fillings,
borax The BORAX Experiments were a series of safety experiments on boiling water nuclear reactors conducted by Argonne National Laboratory in the 1950s and 1960s at the National Reactor Testing Station in eastern Idaho.
,
sal ammoniac Salammoniac, also sal ammoniac or salmiac, is a rare naturally occurring mineral composed of ammonium chloride, NH4Cl. It forms colorless, white, or yellow-brown crystals in the Cubic (crystal system), isometric-hexoctahedral class. It has very ...
,
balsam Balsam is the resinous exudate (or sap) which forms on certain kinds of trees and shrubs. Balsam (from Latin ''balsamum'' "gum of the balsam tree," ultimately from a Semitic source such as ) owes its name to the biblical Balm of Gilead. Ch ...
of
copaiba Copaiba is an oleoresin obtained from the trunk of several pinnate-leaved South American leguminous trees (genus ''Copaifera''). The thick, transparent exudate varies in color from light gold to dark brown, depending on the ratio of resin to esse ...
,
cyanide In chemistry, cyanide () is an inorganic chemical compound that contains a functional group. This group, known as the cyano group, consists of a carbon atom triple-bonded to a nitrogen atom. Ionic cyanides contain the cyanide anion . This a ...
of
potash Potash ( ) includes various mined and manufactured salts that contain potassium in water- soluble form.
, and soda phosphate. The 1920 edition of ''
Scientific American ''Scientific American'', informally abbreviated ''SciAm'' or sometimes ''SA'', is an American popular science magazine. Many scientists, including Albert Einstein and Nikola Tesla, have contributed articles to it, with more than 150 Nobel Pri ...
book of facts and formulae'' indicates a frequently offered trade secret as using
copperas Iron(II) sulfate or ferrous sulfate (British English: sulphate instead of sulfate) denotes a range of salts with the formula Fe SO4·''x''H2O. These compounds exist most commonly as the heptahydrate (''x'' = 7), but several values for ...
,
saltpeter Potassium nitrate is a chemical compound with a sharp, salty, bitter taste and the chemical formula . It is a potassium salt of nitric acid. This salt consists of potassium cations and nitrate anions , and is therefore an alkali metal nitrate ...
, common
salt In common usage, salt is a mineral composed primarily of sodium chloride (NaCl). When used in food, especially in granulated form, it is more formally called table salt. In the form of a natural crystalline mineral, salt is also known as r ...
, black
oxide An oxide () is a chemical compound containing at least one oxygen atom and one other element in its chemical formula. "Oxide" itself is the dianion (anion bearing a net charge of −2) of oxygen, an O2− ion with oxygen in the oxidation st ...
of
manganese Manganese is a chemical element; it has Symbol (chemistry), symbol Mn and atomic number 25. It is a hard, brittle, silvery metal, often found in minerals in combination with iron. Manganese was first isolated in the 1770s. It is a transition m ...
, prussiate of potash, and "nice welding sand" (silicate).


See also

* Pattern welding * Friction welding * Friction stud welding


References

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