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Fluorsid S.p.A. is an Italian company active in the
chemical A chemical substance is a unique form of matter with constant chemical composition and characteristic properties. Chemical substances may take the form of a single element or chemical compounds. If two or more chemical substances can be combin ...
industry, precisely involved in the production and sales of inorganic fluorine derivatives. The historic production site is located in Macchiareddu, in the industrial area of
Cagliari Cagliari (, , ; ; ; Latin: ''Caralis'') is an Comune, Italian municipality and the capital and largest city of the island of Sardinia, an Regions of Italy#Autonomous regions with special statute, autonomous region of Italy. It has about 146,62 ...
, in
Sardinia Sardinia ( ; ; ) is the Mediterranean islands#By area, second-largest island in the Mediterranean Sea, after Sicily, and one of the Regions of Italy, twenty regions of Italy. It is located west of the Italian Peninsula, north of Tunisia an ...
, while other plants and offices are located in the Italian peninsula and in
Norway Norway, officially the Kingdom of Norway, is a Nordic countries, Nordic country located on the Scandinavian Peninsula in Northern Europe. The remote Arctic island of Jan Mayen and the archipelago of Svalbard also form part of the Kingdom of ...
. The company also has a logistics site in
Bahrain Bahrain, officially the Kingdom of Bahrain, is an island country in West Asia. Situated on the Persian Gulf, it comprises a small archipelago of 50 natural islands and an additional 33 artificial islands, centered on Bahrain Island, which mak ...
.


History

Historically, since the
Neolithic The Neolithic or New Stone Age (from Ancient Greek, Greek 'new' and 'stone') is an archaeological period, the final division of the Stone Age in Mesopotamia, Asia, Europe and Africa (c. 10,000 BCE to c. 2,000 BCE). It saw the Neolithic Revo ...
era, the populations that have inhabited Sardinia have always exploited the mineral wealths and varieties present in its subsoil. These mining activities grew considerably between the nineteenth and twentieth centuries: in 1850 there were more than 250 mining concessions. This period was dominated by the extraction of lead and
zinc Zinc is a chemical element; it has symbol Zn and atomic number 30. It is a slightly brittle metal at room temperature and has a shiny-greyish appearance when oxidation is removed. It is the first element in group 12 (IIB) of the periodic tabl ...
which made the fortune of Arburese,
Iglesiente The Iglesiente is a traditional and geographical subdivision of Sardinia, Italy. It encompasses the northern province of Carbonia-Iglesias and the south-western one of the province of Medio Campidano, and its main center is Iglesias. Language ...
and the Barony of
Siniscola Siniscola (; ) is a (municipality) in the province of Nuoro in the Italian region Sardinia, located about northeast of Cagliari and about northeast of Nuoro Nuoro ( ; ) is a city and (municipality) in central-eastern Sardinia, Italy, situat ...
regions. The sector, however, went into crisis after the Second World War and many of these mines were closed or downsized. On the contrary, however, in the same period there has been a boom in the
fluorine Fluorine is a chemical element; it has Chemical symbol, symbol F and atomic number 9. It is the lightest halogen and exists at Standard temperature and pressure, standard conditions as pale yellow Diatomic molecule, diatomic gas. Fluorine is extre ...
and
barium Barium is a chemical element; it has symbol Ba and atomic number 56. It is the fifth element in group 2 and is a soft, silvery alkaline earth metal. Because of its high chemical reactivity, barium is never found in nature as a free element. Th ...
extraction sector, especially in Gerrei area. Therefore, many entrepreneurs, supported by the Autonomous Region of Sardinia through the ''Sardinian Mining Authority'' (it. ''Ente Minerario Sardo''), chose to invest in this new business. Among these figures there was also Count Enrico Giulini, who already obtained the first mining concessions in 1953 and a few years later, on 17 April 1969, he founded ''Fluorsid'' based in the ''Genna Tres Montis'' mine, in the municipality of Silius. The company was specialized in the production of synthetic
cryolite Cryolite ( Na3 Al F6, sodium hexafluoroaluminate) is a rare mineral identified with the once-large deposit at Ivittuut on the west coast of Greenland, mined commercially until 1987. It is used in the reduction ("smelting") of aluminium, in pest ...
and aluminum fluoride. It immediately built, in Macchiareddu, a drying and bagging plant for
fluorspar Fluorite (also called fluorspar) is the mineral form of calcium fluoride, CaF2. It belongs to the halide minerals. It crystallizes in isometric cubic habit, although octahedral and more complex isometric forms are not uncommon. The Mohs scal ...
as well as one for briquetting the
fluorite Fluorite (also called fluorspar) is the mineral form of calcium fluoride, CaF2. It belongs to the halide minerals. It crystallizes in isometric cubic habit, although octahedral and more complex isometric forms are not uncommon. The Mohs scal ...
for steel and wet process, implemented in 1972. This process will be used until 1988, when it was decided to switch to dry production. At the end of the 1980s, however, the problem of the enlargement of the
ozone hole Ozone depletion consists of two related events observed since the late 1970s: a lowered total amount of ozone in Earth, Earth's upper atmosphere, and a much larger springtime decrease in stratospheric ozone (the ozone layer) around Earth's polar ...
emerged:
chlorofluorocarbon Chlorofluorocarbons (CFCs) and hydrochlorofluorocarbons (HCFCs) are fully or partly Halogenation, halogenated hydrocarbons that contain carbon (C), hydrogen (H), chlorine (Cl), and fluorine (F). They are produced as volatility (chemistry), volat ...
s were considered the main culprits and some of these compounds were banned by the 1987
Montreal Protocol The Montreal Protocol on Substances That Deplete the Ozone Layer is an international treaty designed to protect the ozone layer by phasing out the production of numerous substances that are responsible for ozone depletion. It was agreed on 16 ...
. This led to a strong crisis in the chemical industry linked to the production of fluorides (in particular
hydrofluoric acid Hydrofluoric acid is a solution of hydrogen fluoride (HF) in water. Solutions of HF are colorless, acidic and highly corrosive. A common concentration is 49% (48–52%) but there are also stronger solutions (e.g. 70%) and pure HF has a boiling p ...
), for which the Silìus mine also entered into crisis. The Autonomous Region of Sardinia therefore decided to separate the mining sector from the production and commercial side, taking charge of the first aspect and contributing to 80% of the capital of the mines in Gerrei. Since 1990, Fluorsid left Silius and its business focused in the production and marketing of fluoroderivatives purchasing the raw material from other mines in the world, such as in South Africa,
Morocco Morocco, officially the Kingdom of Morocco, is a country in the Maghreb region of North Africa. It has coastlines on the Mediterranean Sea to the north and the Atlantic Ocean to the west, and has land borders with Algeria to Algeria–Morocc ...
and China. In 2006, 100% of the raw materials were imported. However, Sardinia had not been abandoned, on the contrary the industrial site of Macchiareddu was expanded, in the industrial area of
Assemini Assemini (; ) is a ''comune'' (municipality) in the Metropolitan City of Cagliari in the Italian region Sardinia, located about northwest of Cagliari in the plain of the Cixerri, Flumini Mannu and Sa Nuxedda rivers. It has 25,577 inhabitant ...
, near
Cagliari Cagliari (, , ; ; ; Latin: ''Caralis'') is an Comune, Italian municipality and the capital and largest city of the island of Sardinia, an Regions of Italy#Autonomous regions with special statute, autonomous region of Italy. It has about 146,62 ...
: in 2002 the
sulfuric acid Sulfuric acid (American spelling and the preferred IUPAC name) or sulphuric acid (English in the Commonwealth of Nations, Commonwealth spelling), known in antiquity as oil of vitriol, is a mineral acid composed of the elements sulfur, oxygen, ...
plant was started up with the production of steam by electricity and at the same time in the new Millennium the company began to grow at worldwide level and acquire other companies in the sector, also thanks to the arrival in 2005 of Tommaso Giulini, son of the founder, Count Carlo Enrico Giulini, who inherited the head of the company in 2005. With the closure of the Sardinian mines, in fact, the goal was to take advantage of the energy produced on site and, at the same time, increase production capacity, focus on innovative technologies and diversify production by focusing on the aluminum sector to seek new outlets in the Arab and Persian Gulf markets. In fact, in 2010 ''ICIB'' was acquired, at the time the Italian leader in the market of
hydrofluoric acid Hydrofluoric acid is a solution of hydrogen fluoride (HF) in water. Solutions of HF are colorless, acidic and highly corrosive. A common concentration is 49% (48–52%) but there are also stronger solutions (e.g. 70%) and pure HF has a boiling p ...
in solution and synthetic
anhydride An acid anhydride is a type of chemical compound derived by the removal of water molecules from an acid (chemistry), acid. In organic chemistry, organic acid anhydrides contain the functional group . Organic acid anhydrides often form when one ...
. In 2016, with an investment of 12.5 million euros, Fluorsid acquired the Norwegian company ''Noralf,'' the second largest European plant for production of aluminum fluoride. The following year, on the other hand, it acquired 50% of ''Simplis Logistics'', the logistics platform in
Bahrain Bahrain, officially the Kingdom of Bahrain, is an island country in West Asia. Situated on the Persian Gulf, it comprises a small archipelago of 50 natural islands and an additional 33 artificial islands, centered on Bahrain Island, which mak ...
for trade in Asian markets. In Italy, in 2018, the chemical company ''Alkeemia'' was acquired together with its former Solvay plant in
Porto Marghera Marghera is a ''municipalità'' (borough) of the ''comune'' of Venice, Italy. It includes the industrial area known as Porto Marghera (English: Marghera Port) or Venezia Porto Marghera. Etymology The name Marghera is said in popular myth to come ...
for the production of anhydrous
hydrofluoric acid Hydrofluoric acid is a solution of hydrogen fluoride (HF) in water. Solutions of HF are colorless, acidic and highly corrosive. A common concentration is 49% (48–52%) but there are also stronger solutions (e.g. 70%) and pure HF has a boiling p ...
, and in 2021 was created ''Fluorsid Deutschland'', a German section born with the acquisition of 50% of ''CF Carbons'', manufacturer of
Chlorodifluoromethane Chlorodifluoromethane or difluoromonochloromethane is a hydrochlorofluorocarbon (HCFC). This colorless gas is better known as HCFC-22, or R-22, or . It was commonly used as a propellant and refrigerant. These applications were phased out under ...
, called also R22, in
Frankfurt Frankfurt am Main () is the most populous city in the States of Germany, German state of Hesse. Its 773,068 inhabitants as of 2022 make it the List of cities in Germany by population, fifth-most populous city in Germany. Located in the forela ...
. However in October of the same year, Fluorsid sold both the subsidiary Alkeemia, including the related assets, namely the Porto Marghera plant, and the investment in Germany to a fund managed by the English investment company ''Blantyre Capital Limited''. Since 2019 all the subsidiaries of the Fluorsid Group have been unified and controlled under the Fluorsid brand.


Products

The company is part of the fluorine value chain, with the production and marketing of its derivatives for the aluminum and special steels markets, through to the valorisation of the by-product GYPSOS, anhydrous calcium sulphate (better known as
anhydrite Anhydrite, or anhydrous calcium sulfate, is a mineral with the chemical formula CaSO4. It is in the orthorhombic crystal system, with three directions of perfect cleavage parallel to the three planes of symmetry. It is not isomorphous with the ...
), for the construction and cement industries. The production of
sulfuric acid Sulfuric acid (American spelling and the preferred IUPAC name) or sulphuric acid (English in the Commonwealth of Nations, Commonwealth spelling), known in antiquity as oil of vitriol, is a mineral acid composed of the elements sulfur, oxygen, ...
serves the producers of fertilizers, synthetic detergents and pharmaceutical companies. Among the chemical products there are high density aluminum fluoride made with dry process, anhydrous
hydrofluoric acid Hydrofluoric acid is a solution of hydrogen fluoride (HF) in water. Solutions of HF are colorless, acidic and highly corrosive. A common concentration is 49% (48–52%) but there are also stronger solutions (e.g. 70%) and pure HF has a boiling p ...
in aqueous version (from 2018 to 2021 even in anidrous form in
Porto Marghera Marghera is a ''municipalità'' (borough) of the ''comune'' of Venice, Italy. It includes the industrial area known as Porto Marghera (English: Marghera Port) or Venezia Porto Marghera. Etymology The name Marghera is said in popular myth to come ...
plant, then sold),
sulfuric acid Sulfuric acid (American spelling and the preferred IUPAC name) or sulphuric acid (English in the Commonwealth of Nations, Commonwealth spelling), known in antiquity as oil of vitriol, is a mineral acid composed of the elements sulfur, oxygen, ...
from molten
sulfur Sulfur ( American spelling and the preferred IUPAC name) or sulphur ( Commonwealth spelling) is a chemical element; it has symbol S and atomic number 16. It is abundant, multivalent and nonmetallic. Under normal conditions, sulfur atoms ...
with the ''Double Contact Double Absorption'' process, synthetic
cryolite Cryolite ( Na3 Al F6, sodium hexafluoroaluminate) is a rare mineral identified with the once-large deposit at Ivittuut on the west coast of Greenland, mined commercially until 1987. It is used in the reduction ("smelting") of aluminium, in pest ...
and
calcium fluoride Calcium fluoride is the inorganic compound of the elements calcium and fluorine with the formula CaF2. It is a white solid that is practically insoluble in water. It occurs as the mineral fluorite (also called fluorspar), which is often deeply col ...
. Fluorsid produces also
calcium sulphate Calcium sulfate (or calcium sulphate) is an Inorganic compound, inorganic Salt (chemistry), salt with the chemical formula . It occurs in several Hydrate, hydrated forms; the anhydrous state (known as anhydrite) is a white crystalline solid often ...
in various forms (raw, milled or granular) and it is sold under the trade name ''Gypsos''.


Headquarters and production plants

The administrative headquarters and the offices of the company are located in via Vegezio
Milan Milan ( , , ; ) is a city in northern Italy, regional capital of Lombardy, the largest city in Italy by urban area and the List of cities in Italy, second-most-populous city proper in Italy after Rome. The city proper has a population of nea ...
, in the Citylife district, while the production plants are scattered in several countries in Europe. The company's first plant, that is as well the registered office, is located in Macchiareddu (in the territory of
Assemini Assemini (; ) is a ''comune'' (municipality) in the Metropolitan City of Cagliari in the Italian region Sardinia, located about northwest of Cagliari in the plain of the Cixerri, Flumini Mannu and Sa Nuxedda rivers. It has 25,577 inhabitant ...
), an industrial area on the outskirts of
Cagliari Cagliari (, , ; ; ; Latin: ''Caralis'') is an Comune, Italian municipality and the capital and largest city of the island of Sardinia, an Regions of Italy#Autonomous regions with special statute, autonomous region of Italy. It has about 146,62 ...
, in
Sardinia Sardinia ( ; ; ) is the Mediterranean islands#By area, second-largest island in the Mediterranean Sea, after Sicily, and one of the Regions of Italy, twenty regions of Italy. It is located west of the Italian Peninsula, north of Tunisia an ...
. It has been built when fluorite was still extracted in Gerrei. Here aluminum fluoride, sulfuric acid, synthetic cryolite, calcium fluoride and calcium sulfate are produced under the ''Gypsos'' brand. Aluminum fluoride is produced in five parallel production lines. The last two built, in 2008 and 2013, are equipped with highly efficient double-bed reactors.
Sulfuric acid Sulfuric acid (American spelling and the preferred IUPAC name) or sulphuric acid (English in the Commonwealth of Nations, Commonwealth spelling), known in antiquity as oil of vitriol, is a mineral acid composed of the elements sulfur, oxygen, ...
is produced in two parallel plants, the first built in 2002 and the second, of the same capacity, in 2013. The raw material for both plants is molten sulfur from nearby Saras in
Sarroch Sarroch () is a ''comune'' (municipality) in the Metropolitan City of Cagliari in the Italian region of Sardinia, located about southwest of Cagliari. It has 4,970 inhabitants. Sarroch borders the following municipalities: Assemini, Capoterra, ...
's refinery, which guarantees the absence of dangerous dust. The process is highly exothermic and, thanks to a very efficient heat recovery, huge quantities of steam are generated and sent to two turbine generators of 5 and 7 MW capacity. These ones, starting from a zero-km by-product, allow the plant to be self-sufficient in terms of sulfuric acid, steam and electricity without the use of fuels, carbon dioxide emissions or other
greenhouse gas Greenhouse gases (GHGs) are the gases in the atmosphere that raise the surface temperature of planets such as the Earth. Unlike other gases, greenhouse gases absorb the radiations that a planet emits, resulting in the greenhouse effect. T ...
es. In 2010 the group acquired ''ICIB'', which had been the main producer of hydrofluoric acid since 1949, and settled in its
Treviglio Treviglio (; ) is a town and (i.e. municipality) in the province of Bergamo, in Lombardy, Northern Italy. It lies south of the province capital, in the lower territory called . It is also part of the geographic area named , included among the r ...
plant, in
Bergamo Bergamo ( , ; ) is a city in the Alps, alpine Lombardy region of northern Italy, approximately northeast of Milan, and about from the alpine lakes Lake Como, Como and Lake Iseo, Iseo and 70 km (43 mi) from Lake Garda, Garda and Lake ...
area. With the acquisition of ''Noralf'' in 2013, it is also present in
Norway Norway, officially the Kingdom of Norway, is a Nordic countries, Nordic country located on the Scandinavian Peninsula in Northern Europe. The remote Arctic island of Jan Mayen and the archipelago of Svalbard also form part of the Kingdom of ...
in the
Odda Odda () is a list of former municipalities of Norway, former municipality in the old Hordaland counties of Norway, county, Norway. The municipality existed from 1913 until its dissolution in 2020 when it was merged into Ullensvang Municipality i ...
plant, capable of producing around 40,000 tons per year of aluminum fluoride. Finally, with the subsidiary ''Simplis Logistics'', the company operates in
Manama Manama ( ', Bahrani Arabic, Bahrani pronunciation: ) is the capital and List of cities in Bahrain, largest city of Bahrain, with an approximate population of 297,502 as of 2012. Long an important trading center in the Persian Gulf, Manama is ...
,
Bahrain Bahrain, officially the Kingdom of Bahrain, is an island country in West Asia. Situated on the Persian Gulf, it comprises a small archipelago of 50 natural islands and an additional 33 artificial islands, centered on Bahrain Island, which mak ...
, in the logistics sector and in the transport of production materials. In 2018 Fluorsid acquired from Solvay its plant in
Porto Marghera Marghera is a ''municipalità'' (borough) of the ''comune'' of Venice, Italy. It includes the industrial area known as Porto Marghera (English: Marghera Port) or Venezia Porto Marghera. Etymology The name Marghera is said in popular myth to come ...
, in the industrial area of
Venice Venice ( ; ; , formerly ) is a city in northeastern Italy and the capital of the Veneto Regions of Italy, region. It is built on a group of 118 islands that are separated by expanses of open water and by canals; portions of the city are li ...
. Indeed here there was one of the biggest productions of hydrofluoric acid, in both anhydrous and aqueous form, and of fluoroderivatives (calcium sulphate). The company therefore settled here its company branch called Fluorsid Alkeemia. The plant had an area of 125,000 square meters and every year 27,000 tons of anhydrous hydrofluoric acid and 100,000 tons of calcium sulphate were produced. In February 2021 it was selected by the Italian Ministry of Economic Development for a European Union Project of Common Interest for the development of innovative lithium battery cells and systems. In October 2021 Fluorsid sold the controlled company Alkeemia and its plant. In 2021, with the establishment of ''Fluorsid Deutschland'', the company arrived in Germany at the Höchst plant, near
Frankfurt Airport Frankfurt Airport ( ) , is Germany's busiest international airport by passenger numbers, located in Frankfurt, Germany's fifth-largest city. Its official name according to the German Aeronautical Information Publication is Frankfurt Main Airpor ...
. The plant mainly produced
chlorodifluoromethane Chlorodifluoromethane or difluoromonochloromethane is a hydrochlorofluorocarbon (HCFC). This colorless gas is better known as HCFC-22, or R-22, or . It was commonly used as a propellant and refrigerant. These applications were phased out under ...
, a raw material for many fluorine polymers such as
PTFE Polytetrafluoroethylene (PTFE) is a synthetic fluoropolymer of tetrafluoroethylene, and has numerous applications because it is chemically inert. The commonly known brand name of PTFE-based composition is Teflon by Chemours, a spin-off fro ...
and some special fluoroelastomers. The production capacity of the plant was about 24,000 MT per year and is managed through the partner ''Nouryon'', the original owner of the site. In October of the same year, together with the sale of the subsidiary Alkeemia, there has been the sale of the 50% stake in CF Carbons which ended the activities on in Germany.


Legal controversies

In May 2017 Fluorsid was implicated in an investigation for environmental disaster which also involved its top management with accusations of
conspiracy A conspiracy, also known as a plot, ploy, or scheme, is a secret plan or agreement between people (called conspirers or conspirators) for an unlawful or harmful purpose, such as murder, treason, or corruption, especially with a political motivat ...
and environmental crimes. At the end of the events, the company and the reference company were declared extraneous to the conduct, because the technical choices were not being made by the top management of Fluorsid. The agents of the Regional Forestry Corps seized two areas containing polluting materials: one of three hectares, next to the Fluorsid plant in Macchiareddu, in Sardinia, where there were piles of materials stored outdoors and one of five hectares in Terrasili, in the municipality of Assemini, for the storage of various materials. The warrant contested the presence of contamination by dispersion of harmful dust containing
fluorine Fluorine is a chemical element; it has Chemical symbol, symbol F and atomic number 9. It is the lightest halogen and exists at Standard temperature and pressure, standard conditions as pale yellow Diatomic molecule, diatomic gas. Fluorine is extre ...
, the contamination of the soil by diffusion of fluorine dust, then ending up on grazing lands, and the contamination of groundwater and livestock by heavy metals and inorganic compounds, and contamination of livestock by fluorine in Macchiareddu. The investigation closed in December 2018 bringing the number of suspects to 15, which then rose to 22 including managers of public control bodies. On 26 June 2019, the company presented an investment plan of approximately 22 million euros to modernize the area around the Macchiareddu plant and further improve compliance with environmental safety. On 25 July of the same year 11 of the 22 suspects negotiated a sentence of 23 months' detention (but with suspended sentence) and a 7,000 euro fine for pollution, environmental disaster and illegal waste disposal, while the accusation of conspiracy was canceled. On 18 December 2019 the case was definitively closed with the dismissal of the positions of the remaining 11 suspects, which involved the managers of Fluorsid (including the president of
Cagliari Calcio Cagliari Calcio, commonly referred to as Cagliari (), is an Football in Italy, Italian football club based in Cagliari, Sardinia, that plays in Serie A, the first tier of Italian football. The club currently plays home matches at the 16,416-sea ...
and of the company itself Tommaso Giulini) and its subsidiaries and managers of the Sardinian Healthcare Board (ATS) and of the Sardinian Environmental Defense Board (ARPAS). The plea deal, as well as the final setting of the accusation, confirmed the extraneousness of Fluorsid and its top management with respect to the conduct.


Governance

Fluorsid consists of five subsidiaries that report directly to the original company established in 1969. In fact, they maintain organizational charts and legal entities, but are unified from a commercial and brand point of view, with their name preceded by that of the Group, precisely Fluorsid. Management is led by the Fluorsid Board of directors to which the BoDs of the subsidiaries also refer. With regard to organizational reports, the plant managers of the subsidiaries report directly to the Fluorsid's chief executive officer. The entire Fluorsid is part of the holding called ''Fluorsid Group'', that has the full ownership of the professional
football Football is a family of team sports that involve, to varying degrees, kick (football), kicking a football (ball), ball to score a goal (sports), goal. Unqualified, football (word), the word ''football'' generally means the form of football t ...
club
Cagliari Calcio Cagliari Calcio, commonly referred to as Cagliari (), is an Football in Italy, Italian football club based in Cagliari, Sardinia, that plays in Serie A, the first tier of Italian football. The club currently plays home matches at the 16,416-sea ...
, the main sports club in
Sardinia Sardinia ( ; ; ) is the Mediterranean islands#By area, second-largest island in the Mediterranean Sea, after Sicily, and one of the Regions of Italy, twenty regions of Italy. It is located west of the Italian Peninsula, north of Tunisia an ...
, and the minority shareholdings in other companies in several sectors.


Current structure


Former assets


References


External links

* – Official Website *{{cite web, url =https://fluorsidgroup.com/, title =FluorsidGroup.com – Official Website of the holding Companies based in Sardinia Chemical companies of Italy Italian companies established in 1969 Multinational companies headquartered in Italy