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Firedamp is any
flammable A combustible material is a material that can burn (i.e., sustain a flame) in air under certain conditions. A material is flammable if it ignites easily at ambient temperatures. In other words, a combustible material ignites with some effort ...
gas Gas is a state of matter that has neither a fixed volume nor a fixed shape and is a compressible fluid. A ''pure gas'' is made up of individual atoms (e.g. a noble gas like neon) or molecules of either a single type of atom ( elements such as ...
found in
coal mines Coal mining is the process of resource extraction, extracting coal from the ground or from a mine. Coal is valued for its Energy value of coal, energy content and since the 1880s has been widely used to Electricity generation, generate electr ...
, typically
coalbed methane ''Coalbed methane'' (CBM or coal-bed methane), coalbed gas, or coal seam gas (CSG) is a form of natural gas extracted from coal beds. In recent decades it has become an important source of energy in United States, Canada, Australia, and other co ...
. It is particularly found in areas where the coal is
bituminous Bitumen ( , ) is an immensely viscous constituent of petroleum. Depending on its exact composition, it can be a sticky, black liquid or an apparently solid mass that behaves as a liquid over very large time scales. In American English, the m ...
. The gas accumulates in pockets in the coal and adjacent strata and, when they are penetrated, the release of the gas can cause explosions. Historically, if such a pocket was highly pressurized, it was termed a "bag of foulness".


Name

Damp is the collective name given to all gases (other than air) found in coal mines in Great Britain and North America. As well as firedamp, other damps include ''
blackdamp Blackdamp (also known as stythe or choke damp), sometimes found in enclosed environments such as mines, sewers, wells, tunnels and ships' holds, is an asphyxiant, reducing the available oxygen content of air to a level incapable of sustaining huma ...
'' (nonbreathable mixture of
carbon dioxide Carbon dioxide is a chemical compound with the chemical formula . It is made up of molecules that each have one carbon atom covalent bond, covalently double bonded to two oxygen atoms. It is found in a gas state at room temperature and at norma ...
, water vapour and other gases); whitedamp (carbon monoxide and other gases produced by combustion); poisonous, explosive ''
stinkdamp Hydrogen sulfide is a chemical compound with the formula . It is a colorless chalcogen-hydride gas, and is toxic, corrosive, and flammable. Trace amounts in ambient atmosphere have a characteristic foul odor of rotten eggs. Swedish chemist Car ...
'' (
hydrogen sulfide Hydrogen sulfide is a chemical compound with the formula . It is a colorless chalcogen-hydride gas, and is toxic, corrosive, and flammable. Trace amounts in ambient atmosphere have a characteristic foul odor of rotten eggs. Swedish chemist ...
), with its characteristic rotten-egg odour; and the insidiously lethal ''
afterdamp Afterdamp is the toxic mixture of gases left in a mine following an explosion caused by methane-rich firedamp, which itself can initiate a much larger explosion of coal dust. The term is etymologically and practically related to other terms for ...
'' (
carbon monoxide Carbon monoxide (chemical formula CO) is a poisonous, flammable gas that is colorless, odorless, tasteless, and slightly less dense than air. Carbon monoxide consists of one carbon atom and one oxygen atom connected by a triple bond. It is the si ...
and other gases) which are produced following explosions of firedamp or coal dust.


Etymology

Often hyphenated as fire-damp, this term for a flammable type of underground mine gas in first part derives via the Old English ''fyr'', and from the proto-Germanic ''fūr'' for "fire" (the origin of the same word in Dutch and German, with similar original spellings in Old Saxon, Frisian, and Norse, as well as Middle Dutch and Old High German). In the second part, the meaning of "damp" (most commonly understood to imply humidity) presents evidence of having been separated from that newer, irrelevant meaning at least by the first decade of the 18th century, where the original relevant meaning of "vapor" also derives from a Proto-Germanic origin, ''dampaz'', which gave rise to its immediate English predecessor, the Middle Low German ''damp'' (with no record of an Old English intermediary). As with the derivation of the first, the proto-Germanic ''dampaz'' gave rise to many other cognates, including the Old High German ''damph'', the Old Norse ''dampi'', and the modern German ''Dampf'', the last of which still translates as "vapor".


Contribution to mine deaths

Firedamp is explosive at concentrations between 4% and 16%, with most explosions occurring at around 10%. It caused many deaths in coal mines before the invention of the
Geordie lamp The Geordie lamp was a safety lamp for use in flammable atmospheres, invented by George Stephenson in 1815 as a miner's lamp to prevent explosions due to firedamp in coal mines. Origin In 1815, Stephenson was the engine-wright at the Killingw ...
and
Davy lamp The Davy lamp is a safety lamp used in flammable atmospheres, invented in 1815 by Sir Humphry Davy.pyrite The mineral pyrite ( ), or iron pyrite, also known as fool's gold, is an iron sulfide with the chemical formula Fe S2 (iron (II) disulfide). Pyrite is the most abundant sulfide mineral. Pyrite's metallic luster and pale brass-yellow hue ...
s was struck with metal tools. The presence of
coal dust Coal dust is a fine-powdered form of coal which is created by the crushing, grinding, or pulverizer, pulverization of coal rock. Because of the brittle nature of coal, coal dust can be created by mining, transporting, or mechanically handling it. ...
in the air increased the risk of explosion with firedamp and could cause explosions even in the absence of firedamp. The
Tyneside Tyneside is a List of urban areas in the United Kingdom, built-up area across the banks of the River Tyne, England, River Tyne in Northern England. The population of Tyneside as published in the United Kingdom Census 2011, 2011 census was 774,891 ...
coal mines in England had the deadly combination of bituminous coal contaminated with pyrites and there was a great number of deaths in accidents caused by firedamp explosions, including 102 dead at
Wallsend Wallsend () is a town in North Tyneside, Tyne and Wear, England, at the eastern end of Hadrian's Wall. It has a population of 43,842 and lies east of Newcastle upon Tyne. History Roman Wallsend In Roman times, this was the site of the fort of ...
in 1835. The problem of firedamp in mines had been brought to the attention of the
Royal Society The Royal Society, formally The Royal Society of London for Improving Natural Knowledge, is a learned society and the United Kingdom's national academy of sciences. The society fulfils a number of roles: promoting science and its benefits, re ...
by 1677 and in 1733 James Lowther reported that as a shaft was being sunk for a new pit at Saltom near
Whitehaven Whitehaven is a town and civil parish in the Cumberland (unitary authority), Cumberland district of Cumbria, England. It is a port on the north-west coast, and lies outside the Lake District National parks of England and Wales, National Park. ...
there had been a major release when a layer of black stone had been broken through into a coal seam. Ignited with a candle, it had given a steady flame "about half a Yard in Diameter, and near two Yards high". The flame being extinguished and a wider penetration through the black stone made, reigniting of the gas gave a bigger flame, a yard in diameter and about three yards high, which was extinguished only with difficulty. The blower was panelled off from the shaft and piped to the surface, where more than two and a half years later it continued as fast as ever, filling a large bladder in a few seconds. The society members elected Sir James Fellow but were unable to come up with any solution nor improve on the assertion (eventually found to be incorrect) of Carlisle Spedding, the author of the paper, that "this sort of Vapour, or damp Air, will not take Fire except by Flame; Sparks do not affect it, and for that Reason it is frequent to use Flint and Steel in Places affected with this sort of Damp, which will give a glimmering Light, that is a great Help to the Workmen in difficult Cases." A great step forward in countering the problem of firedamp came when safety lamps, intended to provide illumination whilst being incapable of igniting firedamp, were proposed by both
George Stephenson George Stephenson (9 June 1781 – 12 August 1848) was an English civil engineer and Mechanical engineering, mechanical engineer during the Industrial Revolution. Renowned as the "Father of Railways", Stephenson was considered by the Victoria ...
and
Humphry Davy Sir Humphry Davy, 1st Baronet (17 December 177829 May 1829) was a British chemist and inventor who invented the Davy lamp and a very early form of arc lamp. He is also remembered for isolating, by using electricity, several Chemical element, e ...
in response to accidents such as the Felling mine disaster near
Newcastle upon Tyne Newcastle upon Tyne, or simply Newcastle ( , Received Pronunciation, RP: ), is a City status in the United Kingdom, cathedral city and metropolitan borough in Tyne and Wear, England. It is England's northernmost metropolitan borough, located o ...
, which killed 92 people on 25 May 1812. Davy experimented with brass
gauze Gauze is a thin, translucent Textile, fabric with a wikt:loose, loose open Weaving, weave. In technical terms, "gauze" is a weave structure in which the weft yarns are arranged in pairs and are crossed before and after each Warp (weaving), w ...
, determining the maximum size of the gaps and the optimum wire thickness to prevent a flame passing through the gauze. If a naked flame was thus enclosed totally by such a gauze, then methane could pass into the lamp and burn safely above the flame. Stephenson's lamp (the "Geordie lamp") worked on a different principle: the flame was enclosed by glass; air access to the flame was through tubes sufficiently narrow that the flame could not burn-back in incoming firedamp and the exiting gases were too low in oxygen to allow the enclosed flame to reach the surrounding atmosphere. Both principles were combined in later versions of safety lamps. Even after the widespread introduction of the safety lamp, explosions continued because the early lamps were fragile and easily damaged. For example the iron gauze on a Davy lamp needed to lose only one wire to become unsafe. The light was also very poor (compared with a naked flame) and there were continuous attempts to improve the basic design. The height of the cone of burning methane in a flame safety lamp can be used to estimate the concentration of the gas in the local atmosphere. It was not until the 1890s that safe and reliable electric lamps became available in collieries. The Firedamp whistle was developed by
Fritz Haber Fritz Jakob Haber (; 9 December 1868 – 29 January 1934) was a German chemist who received the Nobel Prize in Chemistry in 1918 for his invention of the Haber process, a method used in industry to synthesize ammonia from nitrogen gas and hydrog ...
in 1913, as a prophylactic indicator of firedamp, but calibration in a working colliery ultimately proved impractical. Margit Szöllösi-Janze: ''Fritz Haber 1868-1934: Eine Biographie'', Verlag C. H.Beck, 1998, , p. 240-242


See also

* Firedamp whistle * Whitedamp *
Blackdamp Blackdamp (also known as stythe or choke damp), sometimes found in enclosed environments such as mines, sewers, wells, tunnels and ships' holds, is an asphyxiant, reducing the available oxygen content of air to a level incapable of sustaining huma ...
*
Stinkdamp Hydrogen sulfide is a chemical compound with the formula . It is a colorless chalcogen-hydride gas, and is toxic, corrosive, and flammable. Trace amounts in ambient atmosphere have a characteristic foul odor of rotten eggs. Swedish chemist Car ...
*
Afterdamp Afterdamp is the toxic mixture of gases left in a mine following an explosion caused by methane-rich firedamp, which itself can initiate a much larger explosion of coal dust. The term is etymologically and practically related to other terms for ...
*
Glossary of coal mining terminology This is a partial glossary of coal mining terminology commonly used in the coalfields of the United Kingdom. Some words were in use throughout the coalfields, some are historic and some are local to the different British coalfields. A Adit :An ...
* Abercarn colliery disaster *
Coalbed methane ''Coalbed methane'' (CBM or coal-bed methane), coalbed gas, or coal seam gas (CSG) is a form of natural gas extracted from coal beds. In recent decades it has become an important source of energy in United States, Canada, Australia, and other co ...
* Darr Mine Disaster *
Gresford Disaster The Gresford disaster () occurred on 22 September 1934 at Gresford Colliery, near Wrexham, when an explosion and underground fire killed 261 men. Gresford is one of Britain's worst coal mining disasters: a controversial inquiry into the disaster ...
* Maypole Colliery disaster *
Mining accident A mining accident is an accident that occurs during the process of mining minerals or metals. Thousands of miners die from mining accidents each year, especially from underground mining (hard rock), underground coal mining, although accidents al ...
* Udston mining disaster


References

* "Experiments Show How Gas Explodes in a Mine", ''
Popular Science Popular science (also called pop-science or popsci) is an interpretation of science intended for a general audience. While science journalism focuses on recent scientific developments, popular science is more broad ranging. It may be written ...
'' monthly, February 1919, Unnumbered page, Scanned by Google Books: https://books.google.com/books?id=7igDAAAAMBAJ&pg=PT21 {{Authority control Coal mining Fuel gas Mine safety Natural gas safety