Ferrokentbrooksite is a moderately rare mineral of the

eudialyte group Eudialyte group is a group of complex trigonal zircono- and, more rarely, titanosilicate minerals with general formula (1)N(2)N(3)N(4)N(5)sub>3 (1a)M(1b)sub>3M(2)3M(4)Z3 i24O72'4X2, where N(1) and N(2) and N(3) and N(5) = Na+ and more rarely H3 ...

,Mindat, Ferrokentbrooksite, http://www.mindat.org/min-7106.html with formula .Johnsen, O., Grice, J.D., and Gault, R.A., 2003: Ferrokentbrooksite, a new member of the eudialyte group from Mont Saint-Hilaire, Quebec, Canada. The Canadian Mineralogist 41(1), 55–60 The original formula was extended form to show the presence of cyclic silicate groups and presence of silicon at the M4 site, according to the nomenclature of eudialyte group. As suggested by its name, it is the (ferrous) iron analogue of

kentbrooksite Kentbrooksite is a moderately rare mineral of the eudialyte group,Mindat, Kentbrooksite, http://www.mindat.org/min-7132.html with chemical formula .Johnsen, O., Grice, J.D., and Gault, R.A., 1998. Kentbrooksite from the Kangerdlugssuaq intrusion, ...

. When compared to the latter, it is also chlorine-dominant instead of being fluorine-dominant. The original (holotype) material is also relatively enriched in

rare earth elements The rare-earth elements (REE), also called the rare-earth metals or rare earths, and sometimes the lanthanides or lanthanoids (although scandium and yttrium, which do not belong to this series, are usually included as rare earths), are a set of ...

, including

cerium Cerium is a chemical element; it has Chemical symbol, symbol Ce and atomic number 58. It is a hardness, soft, ductile, and silvery-white metal that tarnishes when exposed to air. Cerium is the second element in the lanthanide series, and while it ...

and

yttrium Yttrium is a chemical element; it has Symbol (chemistry), symbol Y and atomic number 39. It is a silvery-metallic transition metal chemically similar to the lanthanides and has often been classified as a "rare-earth element". Yttrium is almost a ...

Occurrence and association

Ferrokentbrooksite was discovered in

Mont Saint-Hilaire Mont Saint-Hilaire (; English: Mount Saint-Hilaire; ;, ; see for other names) is a mountain, high, in the Montérégie region of southern Quebec. It is about thirty kilometres east of Montreal, and immediately east of the Richelieu River. It ...

, Quebec, Canada – a site wealth in rare alkaline minerals. At the site ferrokentbrooksite coexists with

aegirine Aegirine is a member of the clinopyroxene group of inosilicate minerals. It is the sodium endmember of the aegirine– augite series. It has the chemical formula NaFeSi2O6, in which the iron is present as the ion Fe3+. In the aegirine–augite se ...

albite Albite is a plagioclase feldspar mineral. It is the sodium endmember of the plagioclase solid solution series. It represents a plagioclase with less than 10% anorthite content. The pure albite endmember has the formula . It is a tectosilicat ...

, ancylite-(Ce),

calcite Calcite is a Carbonate minerals, carbonate mineral and the most stable Polymorphism (materials science), polymorph of calcium carbonate (CaCO3). It is a very common mineral, particularly as a component of limestone. Calcite defines hardness 3 on ...

catapleiite Catapleiite (·2) is a dimorph of gaidonnayite rarely found by itself. Its name derives from the Greek words "κατα" (kata) and "πλειον" (pleion) meaning "with more" as it is mostly accompanied by a number of rare minerals. When pure it ...

fluorite Fluorite (also called fluorspar) is the mineral form of calcium fluoride, CaF2. It belongs to the halide minerals. It crystallizes in isometric cubic habit, although octahedral and more complex isometric forms are not uncommon. The Mohs scal ...

fluorapatite Fluorapatite, often with the alternate spelling of fluoroapatite, is a phosphate mineral with the formula Ca5(PO4)3F (calcium fluorophosphate). Fluorapatite is a hard crystalline solid. Although samples can have various color (green, brown, blu ...

gonnardite Gonnardite is a comparatively rare, fibrous zeolite, natrolite subgroup. Older papers claim that a complete solid solution exists between tetranatrolite and gonnardite, but tetranatrolite was discredited as a separate species in 1999.American Mi ...

microcline Microcline (KAlSi3O8) is an important igneous rock-forming tectosilicate mineral. It is a potassium-rich alkali feldspar. Microcline typically contains minor amounts of sodium. It is common in granite and pegmatites. Microcline forms during s ...

natrolite Natrolite is a tectosilicate mineral species belonging to the zeolite group. It is a hydrated sodium and aluminium silicate with the formula . The type locality is Hohentwiel, Hegau, Germany. It was named natrolite by Martin Heinrich Klaprot ...

nepheline Nepheline, also called nephelite (), is a rock-forming mineral in the feldspathoid groupa silica-undersaturated aluminosilicate, Na3 K Al4 Si4 O16, that occurs in intrusive and volcanic rocks with low silica, and in their associated pegmatit ...

rhodochrosite Rhodochrosite is a manganese carbonate mineral with chemical composition Manganese(II) carbonate, MnCO3. In its pure form (rare), it is typically a rose-red colour, but it can also be shades of pink to pale brown. It Streak (mineralogy), streak ...

, and

serandite Serandite is a mineral with formula Na(Mn2+,Ca)2Si3O8(OH). The mineral was discovered in Guinea in 1931 and named for J. M. Sérand. Serandite is generally red, brown, black or colorless. The correct name lacks an accent. Description Serandite is ...

Notes on chemistry

Beside fluorine, ferrokentbrooksite has admixtures of

(including

lanthanum Lanthanum is a chemical element; it has symbol La and atomic number 57. It is a soft, ductile, silvery-white metal that tarnishes slowly when exposed to air. It is the eponym of the lanthanide series, a group of 15 similar elements bet ...

neodymium Neodymium is a chemical element; it has Symbol (chemistry), symbol Nd and atomic number 60. It is the fourth member of the lanthanide series and is considered to be one of the rare-earth element, rare-earth metals. It is a hard (physics), hard, sli ...

and some

gadolinium Gadolinium is a chemical element; it has Symbol (chemistry), symbol Gd and atomic number 64. It is a silvery-white metal when oxidation is removed. Gadolinium is a malleable and ductile rare-earth element. It reacts with atmospheric oxygen or moi ...

and

samarium Samarium is a chemical element; it has symbol Sm and atomic number 62. It is a moderately hard silvery metal that slowly oxidizes in air. Being a typical member of the lanthanide series, samarium usually has the oxidation state +3. Compounds of s ...

potassium Potassium is a chemical element; it has Symbol (chemistry), symbol K (from Neo-Latin ) and atomic number19. It is a silvery white metal that is soft enough to easily cut with a knife. Potassium metal reacts rapidly with atmospheric oxygen to ...

strontium Strontium is a chemical element; it has symbol Sr and atomic number 38. An alkaline earth metal, it is a soft silver-white yellowish metallic element that is highly chemically reactive. The metal forms a dark oxide layer when it is exposed to ...

, and contains minor admixtures of

titanium Titanium is a chemical element; it has symbol Ti and atomic number 22. Found in nature only as an oxide, it can be reduced to produce a lustrous transition metal with a silver color, low density, and high strength, resistant to corrosion in ...

hafnium Hafnium is a chemical element; it has symbol Hf and atomic number 72. A lustrous, silvery gray, tetravalent transition metal, hafnium chemically resembles zirconium and is found in many zirconium minerals. Its existence was predicted by Dm ...

, and

tantalum Tantalum is a chemical element; it has Symbol (chemistry), symbol Ta and atomic number 73. It is named after Tantalus, a figure in Greek mythology. Tantalum is a very hard, ductility, ductile, lustre (mineralogy), lustrous, blue-gray transition ...

Notes on structure

Iron in ferrokentbrooksite has coordination number 5.

References

Cyclosilicates Sodium minerals Calcium minerals Iron minerals Manganese minerals Zirconium minerals Niobium minerals Trigonal minerals Minerals in space group 160 Minerals described in 1999 {{silicate-mineral-stub