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Fermi liquid theory (also known as Landau's Fermi-liquid theory) is a theoretical model of interacting
fermion In particle physics, a fermion is a subatomic particle that follows Fermi–Dirac statistics. Fermions have a half-integer spin (spin 1/2, spin , Spin (physics)#Higher spins, spin , etc.) and obey the Pauli exclusion principle. These particles i ...
s that describes the normal state of the conduction electrons in most
metal A metal () is a material that, when polished or fractured, shows a lustrous appearance, and conducts electrical resistivity and conductivity, electricity and thermal conductivity, heat relatively well. These properties are all associated wit ...
s at sufficiently low temperatures. The theory describes the behavior of many-body systems of particles in which the interactions between particles may be strong. The phenomenological theory of Fermi liquids was introduced by the Soviet physicist Lev Davidovich Landau in 1956, and later developed by Alexei Abrikosov and Isaak Khalatnikov using
diagrammatic A diagram is a symbolic Depiction, representation of information using Visualization (graphics), visualization techniques. Diagrams have been used since prehistoric times on Cave painting, walls of caves, but became more prevalent during the Age o ...
perturbation theory In mathematics and applied mathematics, perturbation theory comprises methods for finding an approximate solution to a problem, by starting from the exact solution of a related, simpler problem. A critical feature of the technique is a middle ...
. The theory explains why some of the properties of an interacting fermion system are very similar to those of the ideal Fermi gas (collection of non-interacting fermions), and why other properties differ. Fermi liquid theory applies most notably to conduction electrons in normal (non- superconducting) metals, and to liquid helium-3. Liquid helium-3 is a Fermi liquid at low temperatures (but not low enough to be in its
superfluid Superfluidity is the characteristic property of a fluid with zero viscosity which therefore flows without any loss of kinetic energy. When stirred, a superfluid forms vortex, vortices that continue to rotate indefinitely. Superfluidity occurs ...
phase). An atom of helium-3 has two
proton A proton is a stable subatomic particle, symbol , Hydron (chemistry), H+, or 1H+ with a positive electric charge of +1 ''e'' (elementary charge). Its mass is slightly less than the mass of a neutron and approximately times the mass of an e ...
s, one
neutron The neutron is a subatomic particle, symbol or , that has no electric charge, and a mass slightly greater than that of a proton. The Discovery of the neutron, neutron was discovered by James Chadwick in 1932, leading to the discovery of nucle ...
and two
electron The electron (, or in nuclear reactions) is a subatomic particle with a negative one elementary charge, elementary electric charge. It is a fundamental particle that comprises the ordinary matter that makes up the universe, along with up qua ...
s, giving an odd number of fermions, so the atom itself is a fermion. Fermi liquid theory also describes the low-temperature behavior of electrons in heavy fermion materials, which are metallic rare-earth alloys having partially filled f orbitals. The effective mass of electrons in these materials is much larger than the free-electron mass because of interactions with other electrons, so these systems are known as ''heavy Fermi liquids''. Strontium ruthenate displays some key properties of Fermi liquids, despite being a
strongly correlated material Strongly correlated materials are a wide class of compounds that include insulators and electronic materials, and show unusual (often technologically useful) electronic and magnetic properties, such as metal-insulator transitions, heavy fermi ...
that is similar to high temperature superconductors such as the cuprates. The low-momentum interactions of
nucleons In physics and chemistry, a nucleon is either a proton or a neutron, considered in its role as a component of an atomic nucleus. The number of nucleons in a nucleus defines the atom's mass number. Until the 1960s, nucleons were thought to be ele ...
(protons and neutrons) in
atomic nuclei The atomic nucleus is the small, dense region consisting of protons and neutrons at the center of an atom, discovered in 1911 by Ernest Rutherford at the University of Manchester based on the 1909 Geiger–Marsden gold foil experiment. Aft ...
are also described by Fermi liquid theory.


Description

The key ideas behind Landau's theory are the notion of ''adiabaticity'' and the Pauli exclusion principle. (draft copy) Consider a non-interacting fermion system (a Fermi gas), and suppose we "turn on" the interaction slowly. Landau argued that in this situation, the ground state of the Fermi gas would adiabatically transform into the ground state of the interacting system. By Pauli's exclusion principle, the ground state \Psi_0 of a Fermi gas consists of fermions occupying all momentum states corresponding to momentum p with all higher momentum states unoccupied. As the interaction is turned on, the spin, charge and momentum of the fermions corresponding to the occupied states remain unchanged, while their dynamical properties, such as their mass, magnetic moment etc. are '' renormalized'' to new values. Thus, there is a one-to-one correspondence between the elementary excitations of a Fermi gas system and a Fermi liquid system. In the context of Fermi liquids, these excitations are called " quasiparticles". Landau quasiparticles are long-lived excitations with a lifetime \tau that satisfies /\ll\varepsilon_ where \varepsilon_ is the quasiparticle energy (measured from the Fermi energy). At finite temperature, \varepsilon_ is on the order of the thermal energy k_T, and the condition for Landau quasiparticles can be reformulated as /\ll k_T. For this system, the many-body Green's function can be written (near its poles) in the form :G(\omega,\mathbf)\approx\frac where \mu is the
chemical potential In thermodynamics, the chemical potential of a Chemical specie, species is the energy that can be absorbed or released due to a change of the particle number of the given species, e.g. in a chemical reaction or phase transition. The chemical potent ...
, \varepsilon(\mathbf) is the energy corresponding to the given momentum state and Z>0 is called the ''quasiparticle residue'' or ''renormalisation constant'' which is very characteristic of Fermi liquid theory. The spectral function for the system can be directly observed via angle-resolved photoemission spectroscopy (ARPES), and can be written (in the limit of low-lying excitations) in the form: :A(\mathbf,\omega)=Z\delta(\omega-v_k_) where v_ is the Fermi velocity. Physically, we can say that a propagating fermion interacts with its surrounding in such a way that the net effect of the interactions is to make the fermion behave as a "dressed" fermion, altering its effective mass and other dynamical properties. These "dressed" fermions are what we think of as "quasiparticles". Another important property of Fermi liquids is related to the scattering cross section for electrons. Suppose we have an electron with energy \varepsilon_1 above the Fermi surface, and suppose it scatters with a particle in the Fermi sea with energy \varepsilon_2. By Pauli's exclusion principle, both the particles after scattering have to lie above the Fermi surface, with energies \varepsilon_3,\varepsilon_4>\varepsilon_. Now, suppose the initial electron has energy very close to the Fermi surface \varepsilon\approx\varepsilon_ Then, we have that \varepsilon_2,\varepsilon_3,\varepsilon_4 also have to be very close to the Fermi surface. This reduces the
phase space The phase space of a physical system is the set of all possible physical states of the system when described by a given parameterization. Each possible state corresponds uniquely to a point in the phase space. For mechanical systems, the p ...
volume of the possible states after scattering, and hence, by
Fermi's golden rule In quantum physics, Fermi's golden rule is a formula that describes the transition rate (the probability of a transition per unit time) from one energy eigenstate of a quantum system to a group of energy eigenstates in a continuum, as a result of a ...
, the scattering cross section goes to zero. Thus we can say that the lifetime of particles at the Fermi surface goes to infinity.


Similarities to Fermi gas

The Fermi liquid is qualitatively analogous to the non-interacting Fermi gas, in the following sense: The system's dynamics and thermodynamics at low excitation energies and temperatures may be described by substituting the non-interacting fermions with interacting quasiparticles, each of which carries the same spin, charge and
momentum In Newtonian mechanics, momentum (: momenta or momentums; more specifically linear momentum or translational momentum) is the product of the mass and velocity of an object. It is a vector quantity, possessing a magnitude and a direction. ...
as the original particles. Physically these may be thought of as being particles whose motion is disturbed by the surrounding particles and which themselves perturb the particles in their vicinity. Each many-particle excited state of the interacting system may be described by listing all occupied momentum states, just as in the non-interacting system. As a consequence, quantities such as the heat capacity of the Fermi liquid behave qualitatively in the same way as in the Fermi gas (e.g. the heat capacity rises linearly with temperature).


Differences from Fermi gas

The following differences to the non-interacting Fermi gas arise:


Energy

The
energy Energy () is the physical quantity, quantitative physical property, property that is transferred to a physical body, body or to a physical system, recognizable in the performance of Work (thermodynamics), work and in the form of heat and l ...
of a many-particle state is not simply a sum of the single-particle energies of all occupied states. Instead, the change in energy for a given change \delta n_k in occupation of states k contains terms both linear and quadratic in \delta n_k (for the Fermi gas, it would only be linear, \delta n_k \varepsilon_k, where \varepsilon_k denotes the single-particle energies). The linear contribution corresponds to renormalized single-particle energies, which involve, e.g., a change in the effective mass of particles. The quadratic terms correspond to a sort of "mean-field" interaction between quasiparticles, which is parametrized by so-called Landau Fermi liquid parameters and determines the behaviour of density oscillations (and spin-density oscillations) in the Fermi liquid. Still, these mean-field interactions do not lead to a scattering of quasi-particles with a transfer of particles between different momentum states. The renormalization of the mass of a fluid of interacting fermions can be calculated from first principles using many-body computational techniques. For the two-dimensional homogeneous electron gas, GW calculations and
quantum Monte Carlo Quantum Monte Carlo encompasses a large family of computational methods whose common aim is the study of complex quantum systems. One of the major goals of these approaches is to provide a reliable solution (or an accurate approximation) of the ...
methods have been used to calculate renormalized quasiparticle effective masses.


Specific heat and compressibility

Specific heat In thermodynamics, the specific heat capacity (symbol ) of a substance is the amount of heat that must be added to one unit of mass of the substance in order to cause an increase of one unit in temperature. It is also referred to as massic heat ...
, compressibility, spin-susceptibility and other quantities show the same qualitative behaviour (e.g. dependence on temperature) as in the Fermi gas, but the magnitude is (sometimes strongly) changed.


Interactions

In addition to the mean-field interactions, some weak interactions between quasiparticles remain, which lead to scattering of quasiparticles off each other. Therefore, quasiparticles acquire a finite lifetime. However, at low enough energies above the Fermi surface, this lifetime becomes very long, such that the product of excitation energy (expressed in frequency) and lifetime is much larger than one. In this sense, the quasiparticle energy is still well-defined (in the opposite limit, Heisenberg's uncertainty relation would prevent an accurate definition of the energy).


Structure

The structure of the "bare" particles (as opposed to quasiparticle) many-body Green's function is similar to that in the Fermi gas (where, for a given momentum, the Green's function in frequency space is a delta peak at the respective single-particle energy). The delta peak in the density-of-states is broadened (with a width given by the quasiparticle lifetime). In addition (and in contrast to the quasiparticle Green's function), its weight (integral over frequency) is suppressed by a quasiparticle weight factor 0. The remainder of the total weight is in a broad "incoherent background", corresponding to the strong effects of interactions on the fermions at short time scales.


Distribution

The distribution of particles (as opposed to quasiparticles) over momentum states at zero temperature still shows a discontinuous jump at the Fermi surface (as in the Fermi gas), but it does not drop from 1 to 0: the step is only of size Z.


Electrical resistivity

In a metal the resistivity at low temperatures is dominated by electron–electron scattering in combination with umklapp scattering. For a Fermi liquid, the resistivity from this mechanism varies as T^2, which is often taken as an experimental check for Fermi liquid behaviour (in addition to the linear temperature-dependence of the specific heat), although it only arises in combination with the lattice. In certain cases, umklapp scattering is not required. For example, the resistivity of compensated semimetals scales as T^2 because of mutual scattering of electron and hole. This is known as the Baber mechanism.


Optical response

Fermi liquid theory predicts that the scattering rate, which governs the optical response of metals, not only depends quadratically on temperature (thus causing the T^2 dependence of the DC resistance), but it also depends quadratically on frequency. This is in contrast to the Drude prediction for non-interacting metallic electrons, where the scattering rate is a constant as a function of frequency. One material in which optical Fermi liquid behavior was experimentally observed is the low-temperature metallic phase of Sr2RuO4.


Instabilities

The experimental observation of exotic phases in strongly correlated systems has triggered an enormous effort from the theoretical community to try to understand their microscopic origin. One possible route to detect instabilities of a Fermi liquid is precisely the analysis done by Isaak Pomeranchuk. Due to that, the Pomeranchuk instability has been studied by several authors with different techniques in the last few years and in particular, the instability of the Fermi liquid towards the nematic phase was investigated for several models.


Non-Fermi liquids

Non-Fermi liquids are systems in which the Fermi-liquid behaviour breaks down. The simplest example is a system of interacting fermions in one dimension, called the Luttinger liquid. Although Luttinger liquids are physically similar to Fermi liquids, the restriction to one dimension gives rise to several qualitative differences such as the absence of a ''quasiparticle peak'' in the momentum dependent spectral function, and the presence of spin-charge separation and of spin-density waves. One cannot ignore the existence of interactions in one dimension and has to describe the problem with a non-Fermi theory, where Luttinger liquid is one of them. At small finite spin temperatures in one dimension the ground state of the system is described by spin-incoherent Luttinger liquid (SILL). Another example of non-Fermi-liquid behaviour is observed at quantum critical points of certain second-order
phase transition In physics, chemistry, and other related fields like biology, a phase transition (or phase change) is the physical process of transition between one state of a medium and another. Commonly the term is used to refer to changes among the basic Sta ...
s, such as heavy fermion criticality, Mott criticality and high-T_ cuprate phase transitions. The ground state of such transitions is characterized by the presence of a sharp Fermi surface, although there may not be well-defined quasiparticles. That is, on approaching the critical point, it is observed that the quasiparticle residue Z\to0. In optimally doped cuprates and iron-based superconductors, the normal state above the critical temperature shows signs of non-Fermi liquid behaviour, and is often called a strange metal. In this region of phase diagram, resistivity increases linearly in temperature and the Hall coefficient is found to depend on temperature. Understanding the behaviour of non-Fermi liquids is an important problem in condensed matter physics. Approaches towards explaining these phenomena include the treatment of ''marginal Fermi liquids''; attempts to understand critical points and derive scaling relations; and descriptions using ''emergent'' gauge theories with techniques of
holographic Holography is a technique that allows a wavefront to be recorded and later reconstructed. It is best known as a method of generating three-dimensional images, and has a wide range of other uses, including data storage, microscopy, and interfe ...
gauge/gravity duality.


See also

* Classical fluid * Fermionic condensate * Luttinger liquid * Luttinger's theorem * Strongly correlated quantum spin liquid


References


Further reading

* * * * {{DEFAULTSORT:Fermi Liquid Condensed matter physics Fermions Electronic band structures Lev Landau