Fano Interference
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In
physics Physics is the scientific study of matter, its Elementary particle, fundamental constituents, its motion and behavior through space and time, and the related entities of energy and force. "Physical science is that department of knowledge whi ...
, a Fano resonance is a type of resonant
scattering In physics, scattering is a wide range of physical processes where moving particles or radiation of some form, such as light or sound, are forced to deviate from a straight trajectory by localized non-uniformities (including particles and radiat ...
phenomenon that gives rise to an asymmetric line-shape. Interference between a background and a resonant scattering process produces the asymmetric line-shape. It is named after Italian-American physicist
Ugo Fano Ugo Fano (July 28, 1912 – February 13, 2001) was an Italian American physicist, notable for contributions to theoretical physics. Biography Ugo Fano was born into a wealthy Jewish family in Turin, Italy. His father was Gino Fano, a professo ...
, who in 1961 gave a theoretical explanation for the scattering line-shape of inelastic scattering of electrons from helium; however,
Ettore Majorana Ettore Majorana ( ,, uploaded 19 April 2013, retrieved 14 December 2019 ; 5 August 1906 – disappeared 25 March 1938) was an Italian theoretical physicist who worked on neutrino masses. Majorana was a supporter of Italian Fascism and a member of ...
was the first to discover this phenomenon. Fano resonance is a weak coupling effect meaning that the decay rate is so high, that no hybridization occurs. The coupling modifies the resonance properties such as spectral position and
width Length is a measure of distance. In the International System of Quantities, length is a quantity with dimension distance. In most systems of measurement a base unit for length is chosen, from which all other units are derived. In the Intern ...
and its line-shape takes on the distinctive asymmetric Fano profile. Because it is a general
wave In physics, mathematics, engineering, and related fields, a wave is a propagating dynamic disturbance (change from List of types of equilibrium, equilibrium) of one or more quantities. ''Periodic waves'' oscillate repeatedly about an equilibrium ...
phenomenon, examples can be found across many areas of physics and engineering.


History

The explanation of the Fano line-shape first appeared in the context of inelastic
electron scattering Electron scattering occurs when electrons are displaced from their original trajectory. This is due to the electrostatic forces within matter interaction or, if an external magnetic field is present, the electron may be deflected by the Lorentz ...
by helium and
autoionization Autoionization is a process by which an atom or a molecule in an excited state spontaneously emits one of the outer-shell electrons, thus going from a state with charge  to a state with charge , for example from an electrically neutral sta ...
. The incident electron doubly excites the atom to the 2s2p state, a sort of
shape resonance In quantum mechanics, a shape resonance is a metastable state in which an electron is trapped due to the shape of a potential barrier. Altunata describes a state as being a shape resonance if, "the internal state of the system remains unchanged up ...
. The doubly excited atom spontaneously decays by ejecting one of the excited electrons. Fano showed that interference between the amplitude to simply scatter the incident electron and the amplitude to scatter via autoionization creates an asymmetric scattering line-shape around the autoionization energy with a line-width very close to the inverse of the autoionization lifetime.


Explanation

The Fano resonance line-shape is due to
interference Interference is the act of interfering, invading, or poaching. Interference may also refer to: Communications * Interference (communication), anything which alters, modifies, or disrupts a message * Adjacent-channel interference, caused by extra ...
between two scattering amplitudes, one due to scattering within a continuum of states (the background process) and the second due to an excitation of a discrete state (the resonant process). The energy of the resonant state must lie in the energy range of the continuum (background) states for the effect to occur. Near the resonant energy, the background
scattering amplitude In quantum physics, the scattering amplitude is the probability amplitude of the outgoing spherical wave relative to the incoming plane wave in a stationary-state scattering process. Formulation Scattering in quantum mechanics begins with a p ...
typically varies slowly with energy while the resonant scattering amplitude changes both in magnitude and phase quickly. It is this variation that creates the asymmetric profile. For energies far from the resonant energy E_\mathrm the background scattering process dominates. Within 2\Gamma_\mathrm of the resonant energy, the phase of the resonant scattering amplitude changes by \pi. It is this rapid variation in phase that creates the asymmetric line-shape. Fano showed that the total scattering cross-section \sigma assumes the following form, \sigma \approx \frac where \Gamma_\mathrm describes the line width of the resonant energy and , the Fano parameter, measures the ratio of resonant scattering to the direct (background) scattering amplitude. This is consistent with the interpretation within the
Feshbach–Fano partitioning In quantum mechanics, and in particular in scattering theory, the Feshbach–Fano method, named after Herman Feshbach and Ugo Fano, separates (partitions) the resonant and the background components of the wave function and therefore of the associat ...
theory. In case the direct scattering amplitude vanishes, the parameter becomes zero and the Fano formula becomes : \sigma(q=0) \approx \frac Looking at transmission shows that this last expression boils down to the expected Breit–Wigner ( Lorentzian) formula, as 1 - \sigma(q=0) \approx \frac = f(E;E_\mathrm,\Gamma_\mathrm/2,1), the three parameters
Lorentzian function The Cauchy distribution, named after Augustin-Louis Cauchy, is a continuous probability distribution. It is also known, especially among physicists, as the Lorentz distribution (after Hendrik Lorentz), Cauchy–Lorentz distribution, Lorentz(ian) ...
(note that it is not a density function and does not integrate to 1, as its amplitude I is 1 and not 2/\pi \Gamma_\mathrm).


Examples

Examples of Fano resonances can be found in
atomic physics Atomic physics is the field of physics that studies atoms as an isolated system of electrons and an atomic nucleus. Atomic physics typically refers to the study of atomic structure and the interaction between atoms. It is primarily concerned wit ...
,
nuclear physics Nuclear physics is the field of physics that studies atomic nuclei and their constituents and interactions, in addition to the study of other forms of nuclear matter. Nuclear physics should not be confused with atomic physics, which studies th ...
,
condensed matter physics Condensed matter physics is the field of physics that deals with the macroscopic and microscopic physical properties of matter, especially the solid and liquid State of matter, phases, that arise from electromagnetic forces between atoms and elec ...
,
electrical circuit An electrical network is an interconnection of electrical components (e.g., battery (electricity), batteries, resistors, inductors, capacitors, switches, transistors) or a model of such an interconnection, consisting of electrical elements (e. ...
s,
microwave engineering Microwave engineering pertains to the study and design of microwave circuits, components, and systems. Fundamental principles are applied to analysis, design and measurement techniques in this field. The short wavelengths involved distinguish this ...
,
nonlinear optics Nonlinear optics (NLO) is the branch of optics that describes the behaviour of light in Nonlinearity, nonlinear media, that is, media in which the polarization density P responds non-linearly to the electric field E of the light. The non-linearity ...
,
nanophotonics Nanophotonics or nano-optics is the study of the behavior of light on the nanometer scale, and of the interaction of nanometer-scale objects with light. It is a branch of optics, optical engineering, electrical engineering, and nanotechnology. I ...
, magnetic
metamaterial A metamaterial (from the Greek word μετά ''meta'', meaning "beyond" or "after", and the Latin word ''materia'', meaning "matter" or "material") is a type of material engineered to have a property, typically rarely observed in naturally occu ...
s, and in mechanical waves. Fano can be observed with
photoelectron spectroscopy Photoemission spectroscopy (PES), also known as photoelectron spectroscopy, refers to energy measurement of electrons emitted from solids, gases or liquids by the photoelectric effect, in order to determine the binding energies of electrons in t ...
and
Raman spectroscopy Raman spectroscopy () (named after physicist C. V. Raman) is a Spectroscopy, spectroscopic technique typically used to determine vibrational modes of molecules, although rotational and other low-frequency modes of systems may also be observed. Ra ...
. The phenomenon can be also observed at visible frequencies using simple
glass Glass is an amorphous (non-crystalline solid, non-crystalline) solid. Because it is often transparency and translucency, transparent and chemically inert, glass has found widespread practical, technological, and decorative use in window pane ...
microspheres Microparticles are particles between 0.1 and 100 μm in size. Commercially available microparticles are available in a wide variety of materials, including ceramics, glass, polymers, and metals. Microparticles encountered in daily life includ ...
, which may allow enhancing the
magnetic field A magnetic field (sometimes called B-field) is a physical field that describes the magnetic influence on moving electric charges, electric currents, and magnetic materials. A moving charge in a magnetic field experiences a force perpendicular ...
of light (which is typically small) by a few orders of magnitude.


See also

*
Resonance (particle physics) In particle physics, a resonance is the peak located around a certain energy found in differential cross sections of scattering experiments. These peaks are associated with subatomic particles, which include a variety of bosons, quarks and hadron ...
* Core-excited shape resonance *
Antiresonance In the physics of coupled oscillators, antiresonance, by analogy with resonance, is a pronounced minimum in the amplitude of an oscillator at a particular frequency, accompanied by a large, abrupt shift in its oscillation phase. Such frequencies a ...


References

{{Reflist Quantum mechanics Scattering