Europium(II) fluoride is an
inorganic compound
An inorganic compound is typically a chemical compound that lacks carbon–hydrogen bondsthat is, a compound that is not an organic compound. The study of inorganic compounds is a subfield of chemistry known as ''inorganic chemistry''.
Inorgan ...
with a chemical formula EuF
2. It was first synthesized in 1937.
[Zhao Yongzhi, Ma Ying, Hou Shaochun, Zhang Wenjuan, Wang Jingjing, Ding Yanrong, Hao Yifan]
氟化亚铕研究现状
(''lit''. Research Progress of Europium(II) Fluoride). ''Chinese Rare Earths'', 2017. 38 (5): 134-140. (in Chinese)
Production
Europium(II) fluoride can be produced by reducing
europium(III) fluoride
Europium(III) fluoride is an inorganic compound with a chemical formula EuF3.
Production
Europium(III) fluoride can be produced by reacting europium(III) nitrate and ammonium fluoride:
: Eu(NO3)3 + 3 NH4F → EuF3 + 3 NH4NO3
Europium(III) fluor ...
with metallic
europium
Europium is a chemical element; it has symbol Eu and atomic number 63. It is a silvery-white metal of the lanthanide series that reacts readily with air to form a dark oxide coating. Europium is the most chemically reactive, least dense, and soft ...
or
hydrogen gas
Hydrogen is a chemical element; it has symbol H and atomic number 1. It is the lightest and most abundant chemical element in the universe, constituting about 75% of all normal matter. Under standard conditions, hydrogen is a gas of diatomi ...
.
[Georg Brauer: ''Handbuch der Präparativen Anorganischen Chemie''. 3., umgearb. Auflage. Band I. Enke, Stuttgart 1975, , S. 255.]
:
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Properties
Europium(II) fluoride is a bright yellowish solid with a
fluorite structure
The fluorite structure refers to a common motif for compounds with the formula MX2. The X ions occupy the eight tetrahedral interstitial sites whereas M ions occupy the regular sites of a face-centered cubic
In crystallography, the cubic (or is ...
.
EuF
2 can be used to dope a trivalent rare-earth fluoride, such as
LaF3, to create a vacancy-filled structure with increased conductivity over a pure crystal. Such a crystal can be used as a fluoride-specific
semipermeable membrane
Semipermeable membrane is a type of synthetic or biologic, polymeric membrane that allows certain molecules or ions to pass through it by osmosis. The rate of passage depends on the pressure, concentration, and temperature of the molecules o ...
in a
fluoride selective electrode A fluoride selective electrode is a type of ion selective electrode sensitive to the concentration of the fluoride ion. A common example is the lanthanum fluoride electrode.
Lanthanum fluoride electrode
In the lanthanum fluoride electrode, the s ...
to detect trace quantities of fluoride.
References
{{Lanthanide halides
Europium(II) compounds
Fluorides
Lanthanide halides
Substances discovered in the 1930s
Fluorite crystal structure