Eugen Goldstein (; ; 5 September 1850 – 25 December 1930) was a German
physicist
A physicist is a scientist who specializes in the field of physics, which encompasses the interactions of matter and energy at all length and time scales in the physical universe. Physicists generally are interested in the root or ultimate cau ...
. He was an early investigator of
discharge tube
A gas-filled tube, also commonly known as a discharge tube or formerly as a Plücker tube, is an arrangement of electrodes in a gas within an insulating, temperature-resistant envelope. Gas-filled tubes exploit phenomena related to electri ...
s, and the discoverer of
anode rays or canal rays, later identified as positive
ions in the gas phase including the
hydrogen ion
A hydrogen ion is created when a hydrogen atom loses or gains an electron. A positively charged hydrogen ion (or proton) can readily combine with other particles and therefore is only seen isolated when it is in a gaseous state or a nearly particl ...
.
Life
Goldstein was born in 1850 in Gleiwitz (now known as
Gliwice
Gliwice (; , ) is a city in Upper Silesia, in southern Poland. The city is located in the Silesian Highlands, on the Kłodnica river (a tributary of the Oder River, Oder). It lies approximately 25 km west from Katowice, the regional capital ...
) to a
Jewish
Jews (, , ), or the Jewish people, are an ethnoreligious group and nation, originating from the Israelites of History of ancient Israel and Judah, ancient Israel and Judah. They also traditionally adhere to Judaism. Jewish ethnicity, rel ...
family. He studied in
Breslau and later in
Berlin
Berlin ( ; ) is the Capital of Germany, capital and largest city of Germany, by both area and List of cities in Germany by population, population. With 3.7 million inhabitants, it has the List of cities in the European Union by population withi ...
, under
Helmholtz. Goldstein worked at the
Berlin Observatory from 1878 to 1890, but spent most of his career at the
Potsdam Observatory, where he became head of the astrophysical section in 1927. He died in 1930 in Berlin and was buried in the
Weißensee Cemetery there. His great-nephews were
Boris and
Mikhail Goldstein.
Work
In the mid-nineteenth century,
Julius Plücker investigated the light emitted in
discharge tubes (
Crookes tube
A Crookes tube: light and dark. Electrons (cathode rays) travel in straight lines from the cathode ''(left)'', as shown by the shadow cast by the metal Maltese cross on the fluorescence of the righthand glass wall of the tube. The anode is the ...
s) and the influence of magnetic fields on the glow. Later, in 1869,
Johann Wilhelm Hittorf studied discharge tubes with energy rays extending from a negative
electrode
An electrode is an electrical conductor used to make contact with a nonmetallic part of a circuit (e.g. a semiconductor, an electrolyte, a vacuum or a gas). In electrochemical cells, electrodes are essential parts that can consist of a varie ...
, the cathode. These rays produced a
fluorescence
Fluorescence is one of two kinds of photoluminescence, the emission of light by a substance that has absorbed light or other electromagnetic radiation. When exposed to ultraviolet radiation, many substances will glow (fluoresce) with colore ...
when they hit a tube's glass walls, and when interrupted by a solid object they cast a shadow.
In the 1870s, Goldstein undertook his own investigations of discharge tubes and named the light emissions studied by others ''Kathodenstrahlen'', or
cathode ray
Cathode rays are streams of electrons observed in discharge tubes. If an evacuated glass tube is equipped with two electrodes and a voltage is applied, glass behind the positive electrode is observed to glow, due to electrons emitted from the c ...
s. He discovered several important properties of cathode rays, which contributed to their later identification as the first subatomic particle, the
electron
The electron (, or in nuclear reactions) is a subatomic particle with a negative one elementary charge, elementary electric charge. It is a fundamental particle that comprises the ordinary matter that makes up the universe, along with up qua ...
. He found that cathode rays were emitted perpendicularly from a metal surface, and carried energy. He attempted to measure their velocity by the
Doppler shift
The Doppler effect (also Doppler shift) is the change in the frequency of a wave in relation to an observer who is moving relative to the source of the wave. The ''Doppler effect'' is named after the physicist Christian Doppler, who described t ...
of spectral lines in the glow emitted by Crookes tubes. He was awarded the
Hughes Medal
The Hughes Medal is a silver-gilt medal awarded by the Royal Society
The Royal Society, formally The Royal Society of London for Improving Natural Knowledge, is a learned society and the United Kingdom's national academy of sciences. T ...
in 1908 for this work.
In 1886, he discovered that tubes with a perforated cathode also emit a glow at the cathode end. Goldstein concluded that in addition to the already-known cathode rays, later recognized as electrons moving from the negatively charged cathode toward the positively charged
anode
An anode usually is an electrode of a polarized electrical device through which conventional current enters the device. This contrasts with a cathode, which is usually an electrode of the device through which conventional current leaves the devic ...
, there is another ray that travels in the opposite direction. Because these latter rays passed through the holes, or channels, in the cathode, Goldstein called them ''Kanalstrahlen'', or
canal rays. They are composed of positive ions whose identity depends on the residual gas inside the tube. It was another of Helmholtz's students,
Wilhelm Wien, who later conducted extensive studies of canal rays, and in time this work would become part of the basis for
mass spectrometry
Mass spectrometry (MS) is an analytical technique that is used to measure the mass-to-charge ratio of ions. The results are presented as a ''mass spectrum'', a plot of intensity as a function of the mass-to-charge ratio. Mass spectrometry is used ...
.
The anode ray with the largest ''e/m'' ratio comes from hydrogen gas (H
2), and is made of H
+ ions. In other words, this ray is made of
protons
A proton is a stable subatomic particle, symbol , H+, or 1H+ with a positive electric charge of +1 ''e'' ( elementary charge). Its mass is slightly less than the mass of a neutron and approximately times the mass of an electron (the pro ...
. Goldstein's work with anode rays of H
+ was apparently the first observation of the proton, although strictly speaking it might be argued that it was Wien who measured the ''e/m'' ratio of the proton and should be credited with its discovery.
Goldstein also used discharge tubes to investigate comets. An object, such as a small ball of glass or iron, placed in the path of cathode rays produces secondary emissions to the sides, flaring outwards in a manner reminiscent of a comet's tail. See the work of Hedenus for pictures and additional information.
Notes and references
Further reading
* Hedenus, M.
Der Komet in der Entladungsröhre 2007, GNT-Verlag
* Brief obituary of Eugen Goldstein, ''Nature'', 1931, volume 127, page 171
* Goldstein, E., "Ueber eine noch nicht untersuchte Strahlungsform an der Kathode inducirter Entladungen" in ''Berlin Akd. Monatsber.'' II, 1886, page 691
*
* Goldstein, E., "Vorläufige Mittheilungen über elektrische Entladungen in verdünnten Gasen" in ''Berlin Akd. Monatsber.'', 1876, page 279
*
{{DEFAULTSORT:Goldstein, Eugen
19th-century German physicists
19th-century German inventors
19th-century German Jews
People from Gliwice
Scientists from the Province of Silesia
1850 births
1930 deaths
Jewish German physicists
20th-century German physicists