Environmental chemistry is the scientific study of the chemical and

biochemical Biochemistry, or biological chemistry, is the study of chemical processes within and relating to living organisms. A sub-discipline of both chemistry and biology, biochemistry may be divided into three fields: structural biology, enzymology, ...

phenomena that occur in natural places. It should not be confused with green chemistry, which seeks to reduce potential pollution at its source. It can be defined as the study of the sources, reactions, transport, effects, and fates of chemical species in the air,

soil Soil, also commonly referred to as earth, is a mixture of organic matter, minerals, gases, water, and organisms that together support the life of plants and soil organisms. Some scientific definitions distinguish dirt from ''soil'' by re ...

, and

water Water is an inorganic compound with the chemical formula . It is a transparent, tasteless, odorless, and Color of water, nearly colorless chemical substance. It is the main constituent of Earth's hydrosphere and the fluids of all known liv ...

environments; and the effect of human activity and

biological activity In pharmacology, biological activity or pharmacological activity describes the beneficial or adverse effects of a drug on living matter. When a drug is a complex chemical mixture, this activity is exerted by the substance's active ingredient or ...

on these. Environmental chemistry is an

interdisciplinary Interdisciplinarity or interdisciplinary studies involves the combination of multiple academic disciplines into one activity (e.g., a research project). It draws knowledge from several fields such as sociology, anthropology, psychology, economi ...

science that includes atmospheric, aquatic and

soil chemistry Soil chemistry is the study of the Chemistry, chemical characteristics of soil. Soil chemistry is affected by mineral composition, organic matter and Environment (biophysical), environmental factors. In the early 1870s a consulting chemist to the R ...

, as well as heavily relying on analytical chemistry and being related to environmental and other areas of science. Environmental chemistry involves first understanding how the uncontaminated environment works, which chemicals in what concentrations are present naturally, and with what effects. Without this it would be impossible to accurately study the effects humans have on the environment through the release of chemicals. Environmental

chemist A chemist (from Greek ''chēm(ía)'' alchemy; replacing ''chymist'' from Medieval Latin ''alchemist'') is a graduated scientist trained in the study of chemistry, or an officially enrolled student in the field. Chemists study the composition of ...

s draw on a range of concepts from chemistry and various environmental sciences to assist in their study of what is happening to a chemical species in the environment. Important general concepts from chemistry include understanding

chemical reaction A chemical reaction is a process that leads to the chemistry, chemical transformation of one set of chemical substances to another. When chemical reactions occur, the atoms are rearranged and the reaction is accompanied by an Gibbs free energy, ...

s and equations, solutions, units, sampling, and analytical techniques.Williams, Ian. ''Environmental Chemistry, A Modular Approach''. Wiley. 2001.

Contaminant

contaminant Contamination is the presence of a constituent, impurity, or some other undesirable element that renders something unsuitable, unfit or harmful for the physical body, natural environment, wiktionary:Workplace, workplace, etc. Types of contamina ...

is a substance present in nature at a level higher than fixed levels or that would not otherwise be there. This may be due to human activity and bioactivity. The term contaminant is often used interchangeably with '' pollutant'', which is a substance that detrimentally impacts the surrounding environment. While a contaminant is sometimes a substance in the environment as a result of human activity, but without harmful effects, it sometimes the case that toxic or harmful effects from contamination only become apparent at a later date.Harrison, R.M (edited by). ''Understanding Our Environment, An Introduction to Environmental Chemistry and Pollution, Third Edition''. Royal Society of Chemistry. 1999. The "medium" such as soil or organism such as fish affected by the pollutant or contaminant is called a ''receptor'', whilst a ''sink'' is a chemical medium or species that retains and interacts with the pollutant such as

carbon sink A carbon sink is a natural or artificial carbon sequestration process that "removes a greenhouse gas, an aerosol or a precursor of a greenhouse gas from the atmosphere". These sinks form an important part of the natural carbon cycle. An overar ...

and its effects by microbes.

Environmental indicators

Chemical measures of water quality include dissolved oxygen (DO), chemical oxygen demand (COD), biochemical oxygen demand (BOD), total dissolved solids (TDS), pH, nutrients ( nitrates and

phosphorus Phosphorus is a chemical element; it has Chemical symbol, symbol P and atomic number 15. All elemental forms of phosphorus are highly Reactivity (chemistry), reactive and are therefore never found in nature. They can nevertheless be prepared ar ...

), heavy metals, soil chemicals (including

copper Copper is a chemical element; it has symbol Cu (from Latin ) and atomic number 29. It is a soft, malleable, and ductile metal with very high thermal and electrical conductivity. A freshly exposed surface of pure copper has a pinkish-orang ...

zinc Zinc is a chemical element; it has symbol Zn and atomic number 30. It is a slightly brittle metal at room temperature and has a shiny-greyish appearance when oxidation is removed. It is the first element in group 12 (IIB) of the periodic tabl ...

, cadmium,

lead Lead () is a chemical element; it has Chemical symbol, symbol Pb (from Latin ) and atomic number 82. It is a Heavy metal (elements), heavy metal that is density, denser than most common materials. Lead is Mohs scale, soft and Ductility, malleabl ...

and mercury), and

pesticide Pesticides are substances that are used to control pests. They include herbicides, insecticides, nematicides, fungicides, and many others (see table). The most common of these are herbicides, which account for approximately 50% of all p ...

Applications

Environmental chemistry is used by the Environment Agency in

England England is a Countries of the United Kingdom, country that is part of the United Kingdom. It is located on the island of Great Britain, of which it covers about 62%, and List of islands of England, more than 100 smaller adjacent islands. It ...

Natural Resources Wales Natural Resources Wales () is a Welsh Government sponsored body, which became operational from 1 April 2013, when it took over the management of the natural resources of Wales. It was formed from a merger of the Countryside Council for Wales, E ...

, the

United States Environmental Protection Agency The Environmental Protection Agency (EPA) is an independent agency of the United States government tasked with environmental protection matters. President Richard Nixon proposed the establishment of EPA on July 9, 1970; it began operation on De ...

, the Association of Public Analysts, and other environmental agencies and research bodies around the world to detect and identify the nature and source of pollutants. These can include: * Heavy metal contamination of land by industry. These can then be transported into water bodies and be taken up by living organisms such as animals and plants. * PAHs (Polycyclic Aromatic Hydrocarbon) in large bodies of water contaminated by

oil spill An oil spill is the release of a liquid petroleum hydrocarbon into the environment, especially the marine ecosystem, due to human activity, and is a form of pollution. The term is usually given to marine oil spills, where oil is released into th ...

s or leaks. Many of the PAHs are

carcinogen A carcinogen () is any agent that promotes the development of cancer. Carcinogens can include synthetic chemicals, naturally occurring substances, physical agents such as ionizing and non-ionizing radiation, and biologic agents such as viruse ...

s and are extremely toxic. They are regulated by concentration ( ppb) using environmental chemistry and

chromatography In chemical analysis, chromatography is a laboratory technique for the Separation process, separation of a mixture into its components. The mixture is dissolved in a fluid solvent (gas or liquid) called the ''mobile phase'', which carries it ...

laboratory testing. *Nutrients leaching from

agricultural Agriculture encompasses crop and livestock production, aquaculture, and forestry for food and non-food products. Agriculture was a key factor in the rise of sedentary human civilization, whereby farming of domesticated species created f ...

land into water courses, which can lead to algal blooms and eutrophication. *

Urban runoff Urban runoff is surface runoff of rainwater, landscape irrigation, and car washing created by urbanization. Impervious surfaces (roads, parking lots and sidewalks) are constructed during land development. During rain, storms, and other Precipitati ...

of pollutants washing off impervious surfaces ( roads, parking lots, and

roof A roof (: roofs or rooves) is the top covering of a building, including all materials and constructions necessary to support it on the walls of the building or on uprights, providing protection against rain, snow, sunlight, extremes of tempera ...

tops) during rain storms. Typical pollutants include

gasoline Gasoline ( North American English) or petrol ( Commonwealth English) is a petrochemical product characterized as a transparent, yellowish, and flammable liquid normally used as a fuel for spark-ignited internal combustion engines. When for ...

motor oil Motor oil, engine oil, or engine lubricant is any one of various substances used for the lubrication of internal combustion engines. They typically consist of base oils enhanced with various additives, particularly antiwear additives, deterge ...

and other

hydrocarbon In organic chemistry, a hydrocarbon is an organic compound consisting entirely of hydrogen and carbon. Hydrocarbons are examples of group 14 hydrides. Hydrocarbons are generally colourless and Hydrophobe, hydrophobic; their odor is usually fain ...

compounds, metals, nutrients and

sediment Sediment is a solid material that is transported to a new location where it is deposited. It occurs naturally and, through the processes of weathering and erosion, is broken down and subsequently sediment transport, transported by the action of ...

(soil). *

Organometallic Organometallic chemistry is the study of organometallic compounds, chemical compounds containing at least one chemical bond between a carbon atom of an organic molecule and a metal, including alkali, alkaline earth, and transition metals, and so ...

compounds.

Methods

Quantitative chemical

analysis Analysis (: analyses) is the process of breaking a complex topic or substance into smaller parts in order to gain a better understanding of it. The technique has been applied in the study of mathematics and logic since before Aristotle (38 ...

is a key part of environmental chemistry, since it provides the data that frame most environmental studies. Common analytical techniques used for quantitative determinations in environmental chemistry include classical wet chemistry, such as gravimetric, titrimetric and electrochemical methods. More sophisticated approaches are used in the determination of trace metals and organic compounds. Metals are commonly measured by atomic spectroscopy and mass spectrometry: Atomic Absorption Spectrophotometry (AAS) and Inductively Coupled Plasma Atomic Emission (ICP-AES) or Inductively Coupled Plasma Mass Spectrometric (ICP-MS) techniques. Organic compounds, including PAHs, are commonly measured also using mass spectrometric methods, such as Gas chromatography-mass spectrometry (GC/MS) and Liquid chromatography-mass spectrometry (LC/MS). Tandem Mass spectrometry MS/MS and High Resolution/Accurate Mass spectrometry HR/AM offer sub part per trillion detection. Non-MS methods using GCs and LCs having universal or specific detectors are still staples in the arsenal of available analytical tools. Other parameters often measured in environmental chemistry are radiochemicals. These are pollutants which emit radioactive materials, such as alpha and beta particles, posing danger to human health and the environment. Particle counters and Scintillation counters are most commonly used for these measurements. Bioassays and immunoassays are utilized for toxicity evaluations of chemical effects on various organisms. Polymerase Chain Reaction PCR is able to identify species of bacteria and other organisms through specific DNA and RNA gene isolation and amplification and is showing promise as a valuable technique for identifying environmental microbial contamination.

Published analytical methods

Peer-reviewed Peer review is the evaluation of work by one or more people with similar competencies as the producers of the work ( peers). It functions as a form of self-regulation by qualified members of a profession within the relevant field. Peer review ...

test methods have been published by government agencies and private research organizations. Approved published methods must be used when testing to demonstrate compliance with regulatory requirements.

Notable environmental chemists

Joan Berkowitz

Paul Crutzen Paul Jozef Crutzen (; 3 December 1933 – 28 January 2021) was a Dutch meteorologist and atmospheric chemistry, atmospheric chemist. In 1995, he was awarded the Nobel Prize in Chemistry alongside Mario Molina and F. Sherwood Rowland, Frank Sherw ...

( Nobel Prize in Chemistry, 1995)
Philip Gschwend
Alice Hamilton
John M. Hayes
Charles David Keeling
Ralph Keeling
Mario Molina ( Nobel Prize in Chemistry, 1995)
James J. Morgan
Clair Patterson
Roger Revelle
Sherry Roland ( Nobel Prize in Chemistry, 1995)
Robert Angus Smith
Susan Solomon
Werner Stumm
Ellen Swallow Richards
Hans Suess
John Tyndall

References

External links

List of links for Environmental Chemistry
- from the WWW Virtual Library
International Journal of Environmental Analytical Chemistry
{{DEFAULTSORT:Environmental Chemistry Biochemistry Chemistry Water pollution