Electroplated Nickel Silver
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Nickel silver, maillechort, German silver, argentan, new silver, nickel brass, albata, or alpacca is a
cupronickel Cupronickel or copper–nickel (CuNi) is an alloy of copper with nickel, usually along with small quantities of other metals added for strength, such as iron and manganese. The copper content typically varies from 60 to 90 percent. ( Monel is a n ...
(
copper Copper is a chemical element; it has symbol Cu (from Latin ) and atomic number 29. It is a soft, malleable, and ductile metal with very high thermal and electrical conductivity. A freshly exposed surface of pure copper has a pinkish-orang ...
with
nickel Nickel is a chemical element; it has symbol Ni and atomic number 28. It is a silvery-white lustrous metal with a slight golden tinge. Nickel is a hard and ductile transition metal. Pure nickel is chemically reactive, but large pieces are slo ...
)
alloy An alloy is a mixture of chemical elements of which in most cases at least one is a metal, metallic element, although it is also sometimes used for mixtures of elements; herein only metallic alloys are described. Metallic alloys often have prop ...
with the addition of
zinc Zinc is a chemical element; it has symbol Zn and atomic number 30. It is a slightly brittle metal at room temperature and has a shiny-greyish appearance when oxidation is removed. It is the first element in group 12 (IIB) of the periodic tabl ...
. The usual formulation is 60% copper, 20% nickel and 20% zinc. Nickel silver does not contain the element
silver Silver is a chemical element; it has Symbol (chemistry), symbol Ag () and atomic number 47. A soft, whitish-gray, lustrous transition metal, it exhibits the highest electrical conductivity, thermal conductivity, and reflectivity of any metal. ...
. It is named for its silvery appearance, which can make it attractive as a cheaper and more durable substitute. It is also well suited for being
plated Plating is a finishing process in which a metal is deposited on a surface. Plating has been done for hundreds of years; it is also critical for modern technology. Plating is used to decorate objects, for corrosion inhibition, to improve solderab ...
with silver. A naturally occurring ore composition in China was smelted into the alloy known as or () ('white copper' or
cupronickel Cupronickel or copper–nickel (CuNi) is an alloy of copper with nickel, usually along with small quantities of other metals added for strength, such as iron and manganese. The copper content typically varies from 60 to 90 percent. ( Monel is a n ...
). The name ''German Silver'' refers to the artificial recreation of the natural ore composition by German metallurgists. All modern, commercially important, nickel silvers (such as those standardized under
ASTM ASTM International, formerly known as American Society for Testing and Materials, is a standards organization that develops and publishes voluntary consensus technical international standards for a wide range of materials, products, systems and s ...
B122) contain zinc and are sometimes considered a subset of
brass Brass is an alloy of copper and zinc, in proportions which can be varied to achieve different colours and mechanical, electrical, acoustic and chemical properties, but copper typically has the larger proportion, generally copper and zinc. I ...
.


History

Nickel silver was first used in
China China, officially the People's Republic of China (PRC), is a country in East Asia. With population of China, a population exceeding 1.4 billion, it is the list of countries by population (United Nations), second-most populous country after ...
, where it was smelted from readily available unprocessed ore. During the
Qing dynasty The Qing dynasty ( ), officially the Great Qing, was a Manchu-led Dynasties of China, imperial dynasty of China and an early modern empire in East Asia. The last imperial dynasty in Chinese history, the Qing dynasty was preceded by the ...
, it was "smuggled into various parts of the
East Indies The East Indies (or simply the Indies) is a term used in historical narratives of the Age of Discovery. The ''Indies'' broadly referred to various lands in Eastern world, the East or the Eastern Hemisphere, particularly the islands and mainl ...
", despite a government ban on the export of nickel silver. It became known in the West from imported wares called (
Mandarin Mandarin or The Mandarin may refer to: Language * Mandarin Chinese, branch of Chinese originally spoken in northern parts of the country ** Standard Chinese or Modern Standard Mandarin, the official language of China ** Taiwanese Mandarin, Stand ...
) or (
Cantonese Cantonese is the traditional prestige variety of Yue Chinese, a Sinitic language belonging to the Sino-Tibetan language family. It originated in the city of Guangzhou (formerly known as Canton) and its surrounding Pearl River Delta. While th ...
) ( , literally "white copper"), for which the silvery metal colour was used to imitate
sterling silver Sterling silver is an alloy composed mass fraction (chemistry), by weight of 92.5% silver and 7.5% other metals, usually copper. The sterling silver silver standards, standard has a minimum millesimal fineness of 925. ''Fineness, Fine silver'' ...
. According to
Berthold Laufer Berthold Laufer (October 11, 1874 – September 13, 1934) was a German anthropologist and historical geographer with an expertise in East Asian languages. The American Museum of Natural History calls him "one of the most distinguished sinologists ...
, it was identical to ''khar sini'', one of the seven metals recognized by Jābir ibn Hayyān. In Europe, consequently, it was at first called , which is about the way is pronounced in the Cantonese dialect. The earliest European mention of occurs in the year 1597. From then until the end of the eighteenth century there are references to it as having been exported from Canton to Europe. German artificial recreation of the natural ore composition, however, began to appear from about 1750 onward. In 1770, the
Suhl Suhl () is a city in Thuringia, Germany, located SW of Erfurt, NE of Würzburg and N of Nuremberg. With its 37,000 inhabitants, it is the smallest of the six urban districts within Thuringia. Together with its northern neighbour-town Zella ...
metalworks were able to produce a similar alloy. In 1823, a German competition was held to perfect the production process: the goal was to develop an alloy that possessed the closest visual similarity to silver. The brothers Henniger in
Berlin Berlin ( ; ) is the Capital of Germany, capital and largest city of Germany, by both area and List of cities in Germany by population, population. With 3.7 million inhabitants, it has the List of cities in the European Union by population withi ...
and Ernst August Geitner in Schneeberg independently achieved this goal. The manufacturer Berndorf (founded in 1843) named the trademark brand ''Alpacca'', which became widely known in northern Europe for nickel silver. In 1830, the German process of manufacture was introduced into England, while exports of from China gradually stopped. In 1832, a form of German silver was also developed in Birmingham, England. After the modern process for the production of electroplated nickel silver was patented in 1840 by George Richards Elkington and his cousin Henry Elkington in Birmingham, the development of electroplating caused nickel silver to become widely used. It formed an ideal, strong and bright substrate for the plating process. It was also used unplated in applications such as cutlery.


Uses

Nickel silver first became popular as a base metal for silver-plated
cutlery Cutlery (also referred to as silverware, flatware, or tableware) includes any hand implement used in preparing, serving, and especially eating food in Western culture. A person who makes or sells cutlery is called a cutler. While most cutlers ...
and other silverware, notably the electroplated wares called EPNS (electroplated nickel silver). It is used in zippers, costume
jewelry Jewellery (or jewelry in American English) consists of decorative items worn for personal adornment such as brooches, ring (jewellery), rings, necklaces, earrings, pendants, bracelets, and cufflinks. Jewellery may be attached to the body or the ...
, for making musical instruments (e.g.,
flutes The flute is a member of a family of musical instruments in the woodwind group. Like all woodwinds, flutes are aerophones, producing sound with a vibrating column of air. Flutes produce sound when the player's air flows across an opening. In th ...
,
clarinet The clarinet is a Single-reed instrument, single-reed musical instrument in the woodwind family, with a nearly cylindrical bore (wind instruments), bore and a flared bell. Clarinets comprise a Family (musical instruments), family of instrume ...
s), and is preferred for the track in electric model railway layouts, as its
oxide An oxide () is a chemical compound containing at least one oxygen atom and one other element in its chemical formula. "Oxide" itself is the dianion (anion bearing a net charge of −2) of oxygen, an O2− ion with oxygen in the oxidation st ...
is conductive. Better quality keys and lock cylinder pins are made of nickel silver for durability under heavy use. The alloy has been widely used in the production of
coin A coin is a small object, usually round and flat, used primarily as a medium of exchange or legal tender. They are standardized in weight, and produced in large quantities at a mint in order to facilitate trade. They are most often issued by ...
s (e.g.
Portuguese escudo The Portuguese escudo (, ) was the currency of Portugal replacing the ''real'' on 22 May 1911 and was in use until the introduction of the euro on 1 January 2002. The escudo was subdivided into 100 . The word literally means shield; like other ...
and the former GDR
marks Marks may refer to: Business * Mark's, a Canadian retail chain * Marks & Spencer, a British retail chain * Collective trade marks A collective trademark, collective trade mark, or collective mark is a trademark owned by an organization (such ...
). Its industrial and technical uses include marine fittings and plumbing fixtures for its corrosion resistance, and heating coils for its high electrical resistance. In the nineteenth century, particularly after 1868, North American
Plains Indian Plains Indians or Indigenous peoples of the Great Plains and Canadian Prairies are the Native American tribes and First Nations peoples who have historically lived on the Interior Plains (the Great Plains and Canadian Prairies) of North ...
metalsmiths were able to easily acquire sheets of German silver. They used them to cut, stamp, and cold hammer a wide range of accessories and also horse gear. Presently, Plains metalsmiths use German silver for pendants, pectorals, bracelets, armbands, hair plates, ''conchas'' (oval decorative plates for belts), earrings, belt buckles, necktie slides, stickpins, '' dush-tuhs'', and
tiara A tiara (, ) is a head ornament adorned with jewels. Its origins date back to ancient Greco-Roman world. In the late 18th century, the tiara came into fashion in Europe as a prestigious piece of jewelry to be worn by women at formal occasions ...
s. Nickel silver is the metal of choice among contemporary
Kiowa Kiowa ( ) or Cáuigú () people are a Native Americans in the United States, Native American tribe and an Indigenous people of the Great Plains of the United States. They migrated southward from western Montana into the Rocky Mountains in Colora ...
and Pawnee in
Oklahoma Oklahoma ( ; Choctaw language, Choctaw: , ) is a landlocked U.S. state, state in the South Central United States, South Central region of the United States. It borders Texas to the south and west, Kansas to the north, Missouri to the northea ...
. Many of the metal fittings on modern higher-end equine harness and
tack Thermoproteati is a kingdom of archaea. Its synonym, "TACK", is an acronym for Thaumarchaeota (now Nitrososphaerota), Aigarchaeota, Crenarchaeota (now Thermoproteota), and Korarchaeota (now Thermoproteota), the first groups discovered. They ...
are of nickel silver. Early in the twentieth century, German silver was used by automobile manufacturers before the advent of steel sheet metal. For example, the famous
Rolls-Royce Silver Ghost The Rolls-Royce Silver Ghost name refers both to a car model and one specific car from that series. Originally named the "Tax horsepower#Britain, 40/50 h.p." the chassis was first made at Royce's Manchester works, with production moving t ...
of 1907 used German silver. After about 1920, it became widely used for pocketknife bolsters, due to its machinability and corrosion resistance. Prior to this, the most common metal was
iron Iron is a chemical element; it has symbol Fe () and atomic number 26. It is a metal that belongs to the first transition series and group 8 of the periodic table. It is, by mass, the most common element on Earth, forming much of Earth's o ...
. Musical instruments, including the
flute The flute is a member of a family of musical instruments in the woodwind group. Like all woodwinds, flutes are aerophones, producing sound with a vibrating column of air. Flutes produce sound when the player's air flows across an opening. In th ...
, saxophone,
trumpet The trumpet is a brass instrument commonly used in classical and jazz musical ensemble, ensembles. The trumpet group ranges from the piccolo trumpet—with the highest Register (music), register in the brass family—to the bass trumpet, pitche ...
, and
French horn The French horn (since the 1930s known simply as the horn in professional music circles) is a brass instrument made of tubing wrapped into a coil with a flared bell. The double horn in F/B (technically a variety of German horn) is the horn most o ...
, string instrument frets, and electric guitar pickup parts, can be made of nickel silver. Many professional-level French horns are entirely made of nickel silver. Some saxophone manufacturers, such as
Keilwerth The Julius Keilwerth company is a German saxophone manufacturer, established in 1925. Company history Early history Julius Keilwerth first apprenticed for the Kohlert company in Graslitz, Czechoslovakia. After this apprenticeship, Julius Keilwe ...
, offer saxophones made of nickel silver (Shadow model); these are far rarer than traditional lacquered brass saxophones. Student-level flutes and piccolos are also made of silver-plated nickel silver, although upper-level models are likely to use
sterling silver Sterling silver is an alloy composed mass fraction (chemistry), by weight of 92.5% silver and 7.5% other metals, usually copper. The sterling silver silver standards, standard has a minimum millesimal fineness of 925. ''Fineness, Fine silver'' ...
. Nickel silver produces a bright and powerful sound quality; an additional benefit is that the metal is harder and more corrosion resistant than brass. Because of its hardness, it is used for most clarinet, flute, oboe and similar wind instrument keys, normally silver-plated. It is used to produce the tubes (called staples) onto which
oboe The oboe ( ) is a type of double-reed woodwind instrument. Oboes are usually made of wood, but may also be made of synthetic materials, such as plastic, resin, or hybrid composites. The most common type of oboe, the soprano oboe pitched in C, ...
reeds are tied. Many parts of brass instruments are made of nickel silver, such as tubes, braces or valve mechanism. Trombone slides of many manufacturers offer a lightweight nickel silver (LT slide) option for faster slide action and weight balance.Bach > Professional Bb Tenor Trombones > Viewing Model LT16M
. Bachbrass.com. Retrieved on 2013-12-19.
The material was used in the construction of the National tricone resophonic guitar. The
frets A fret is any of the thin strips of material, usually metal wire, inserted laterally at specific positions along the Neck (music), neck or Fingerboard, fretboard of a stringed instrument. Frets usually extend across the full width of the Neck ( ...
of guitar, mandolin, banjo, bass, and related string instruments are typically nickel silver. Nickel silver is sometimes used as ornamentation on the
great highland bagpipe The great Highland bagpipe ( 'the great pipe') is a type of bagpipe native to Scotland, and the Scottish analogue to the great Irish warpipes. It has acquired widespread recognition through its usage in the British Armed Forces, British mili ...
. Nickel silver is also used in artworks. The Dutch sculptor Willem Lenssinck has made several pieces from German silver. Outdoors art made from this material easily withstands all kinds of weather.


See also

* Argentium sterling silver *
Britannia silver Britannia silver is an alloy of silver containing 11 ozt 10 dwt (i.e. 11½ troy oz.) silver in the pound troy, equivalent to , or 95.833% by weight (mass) silver, the rest usually being copper. This standard was introduced in England by Act o ...
*
Britannia metal Britannia metal (also called britannium, Britannia ware, or Vickers White Metal (Cite
an
Cupronickel Cupronickel or copper–nickel (CuNi) is an alloy of copper with nickel, usually along with small quantities of other metals added for strength, such as iron and manganese. The copper content typically varies from 60 to 90 percent. ( Monel is a n ...
*
Sheffield plate Old Sheffield Plate (or OSP) is the material developed by Thomas Boulsover in the 1740s, a fusion of copper and sterling silver which could be made into a range of items normally made in solid silver. The material rapidly gained popularity as ...
* Nickel Directive * List of named alloys


References


External links

*
Silver's Sterling Qualities
{{DEFAULTSORT:Nickel Silver Chinese inventions Copper alloys Nickel alloys Economy of the Qing dynasty Silver